File name: Pandora219s1_Ilocos_20250908_L2Fit_fwvt1c3d20240215p1-8.txt File generation date: 20250908T160222.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Ellison Castro Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 219 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora219_OF_v2d20220124.txt Instrument calibration file used: Pandora219s1_CF_v3d20240215.txt Level 1 file used: Pandora219s1_Ilocos_20250908_L1_smca1c3d20240215p1-8.txt Full location name: Mariano Marcos State University Short location name: Ilocos Country of location: Philippines Location latitude [deg]: 18.0582 Location longitude [deg]: 120.5451 Location altitude [m]: 34 Local noon date: 20250908 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on lab session 101 First and last pixel inside fitting window: 1602 1751 Nominal wavelengths inside fitting window [nm]: 492.0264 492.1479 492.2694 492.3909 492.5123 492.6338 492.7552 492.8766 492.9980 493.1193 493.2407 493.3620 493.4833 493.6046 493.7259 493.8472 493.9684 494.0897 494.2109 494.3321 494.4533 494.5744 494.6956 494.8167 494.9378 495.0589 495.1800 495.3011 495.4221 495.5432 495.6642 495.7852 495.9062 496.0271 496.1481 496.2690 496.3899 496.5108 496.6317 496.7526 496.8734 496.9942 497.1150 497.2358 497.3566 497.4774 497.5981 497.7188 497.8396 497.9603 498.0809 498.2016 498.3222 498.4429 498.5635 498.6841 498.8046 498.9252 499.0457 499.1662 499.2868 499.4072 499.5277 499.6482 499.7686 499.8890 500.0094 500.1298 500.2502 500.3705 500.4909 500.6112 500.7315 500.8518 500.9720 501.0923 501.2125 501.3327 501.4529 501.5731 501.6933 501.8134 501.9336 502.0537 502.1738 502.2939 502.4139 502.5340 502.6540 502.7740 502.8940 503.0140 503.1339 503.2539 503.3738 503.4937 503.6136 503.7335 503.8533 503.9732 504.0930 504.2128 504.3326 504.4523 504.5721 504.6918 504.8115 504.9312 505.0509 505.1706 505.2902 505.4099 505.5295 505.6491 505.7687 505.8882 506.0078 506.1273 506.2468 506.3663 506.4858 506.6052 506.7247 506.8441 506.9635 507.0829 507.2023 507.3216 507.4410 507.5603 507.6796 507.7989 507.9181 508.0374 508.1566 508.2758 508.3950 508.5142 508.6334 508.7525 508.8717 508.9908 509.1099 509.2290 509.3480 509.4671 509.5861 509.7051 509.8241 509.9431 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250907T225650.6Z 9381.956141 252 1 20.13 2 73.71 89.24 104.64 269.50 0.00 1 0.00 1 0 22 4.162e-03 4.133e-03 1.187e-04 1.185e-04 1.028774e+04 8.801250e+00 6.786496e+02 -6.000000e+00 2.524968e+02 295.07 -2.00 20.00 -2.00 505.29 0.00e+00 4.902566e-04 3.437883e-06 4.332390e-05 -6.000000e+00 1.228573e-04 295.07 -2.00 20.00 -2.00 500.45 0.00e+00 3.211817e-01 2.386787e-03 5.560395e-02 -6.000000e+00 8.405166e-02 227.29 -2.00 3.11 -2.00 502.04 0.00e+00 3.506 0.000 489.00 513.00 1 1.6903e+00 1.8394e-04 6.9694e-03 -6.0000e+00 6.4860e-03 5.9460e-04 4.6444e-05 1.4049e-03 -6.0000e+00 1.6667e-03 2.0993e-01 1.7417e-03 1.2677e-05 5.3192e-05 -6.0000e+00 4.8213e-04 7.0718e-02 -4.1145e-05 12 9 1 12 1 1 37.96 23.20 0.32 0.07072 0.08280 536 154 1 4 0 37.400 26.21 20.00 23.20 33.70 0.0 994.65 -699 -486 -242 -248 4 563 632 535 412 273 177 -128 -303 -310 -429 -465 -145 210 81 -93 149 297 434 705 574 360 276 -112 -698 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-106 -25 109 213 488 799 793 456 210 90 -53 148 472 341 194 320 212 186 386 77 -341 -361 -501 -529 -122 -27 -255 -89 158 153 227 402 375 334 179 -129 -447 -533 -481 900000 SQ 20250907T230840.6Z 9381.964359 256 1 11.66 2 70.90 90.15 107.33 270.45 0.00 1 0.00 1 0 22 3.920e-03 3.896e-03 1.299e-04 1.297e-04 9.067839e+03 9.488863e+00 6.009154e+02 -6.000000e+00 2.378130e+02 295.07 -2.00 20.00 -2.00 505.28 0.00e+00 4.689522e-04 3.762914e-06 3.973026e-05 -6.000000e+00 1.157041e-04 295.07 -2.00 20.00 -2.00 500.43 0.00e+00 2.848694e-01 2.612346e-03 5.014153e-02 -6.000000e+00 7.913735e-02 227.29 -2.00 3.11 -2.00 502.02 0.00e+00 3.020 0.000 489.00 513.00 1 1.3400e+00 2.0143e-04 6.1402e-03 -6.0000e+00 6.1072e-03 1.0625e-03 5.0905e-05 1.2549e-03 -6.0000e+00 1.5686e-03 3.2087e-01 1.3986e-03 1.3997e-05 4.7102e-05 -6.0000e+00 4.5405e-04 7.1690e-02 -2.1387e-05 11 8 0 10 0 0 -26.08 23.20 0.30 0.07169 0.08139 539 114 1 4 0 21.350 26.21 20.00 23.20 34.48 0.0 999.10 -616 -427 -215 -273 -50 490 576 464 357 263 185 -149 -352 -357 -496 -516 -202 206 8 -95 147 309 450 682 594 404 307 -91 -602 -580 -472 -388 267 533 -51 -235 -3 -3 -145 -54 62 126 276 467 517 503 385 302 -57 -494 -672 -863 -792 -392 -116 -155 -215 -192 20 289 519 473 396 426 232 101 56 -50 -221 -298 -204 -125 90 288 -47 -463 -458 -314 -320 -362 -415 -590 -347 -59 -184 -321 -118 8 122 368 684 937 740 543 437 218 -78 -265 -697 -924 -791 -314 143 16 -395 -471 -566 -431 -21 59 -56 -23 125 188 459 735 746 418 220 80 -29 170 444 316 178 310 190 215 381 66 -368 -436 -571 -598 -138 -1 -280 -133 145 111 239 374 411 334 174 -134 -456 -514 -418 900000 -605 -428 -212 -277 -52 517 592 480 368 268 193 -154 -361 -363 -503 -528 -210 209 9 -100 154 324 472 717 625 424 320 -93 -607 -595 -480 -399 269 549 -54 -249 -3 -3 -149 -55 64 130 287 489 544 528 400 309 -57 -487 -673 -852 -782 -391 -114 -156 -219 -198 20 296 532 486 407 436 235 101 55 -48 -222 -297 -202 -125 87 281 -46 -448 -454 -307 -310 -352 -405 -581 -344 -56 -178 -314 -115 8 119 359 671 923 730 530 416 211 -74 -245 -639 -845 -733 -299 135 16 -394 -469 -560 -423 -21 58 -56 -23 127 192 469 726 740 415 216 80 -29 167 434 310 176 305 187 211 372 64 -355 -415 -540 -567 -132 -1 -278 -134 141 109 238 373 411 333 173 -131 -440 -508 -412 900000 SQ 20250907T230852.4Z 9381.964495 256 2 11.53 2 70.86 90.17 107.37 270.46 0.00 1 0.00 1 0 22 3.910e-03 3.888e-03 1.273e-04 1.270e-04 9.045068e+03 9.250747e+00 6.021598e+02 -6.000000e+00 2.372042e+02 295.07 -2.00 20.00 -2.00 505.29 0.00e+00 4.786345e-04 3.673667e-06 3.907644e-05 -6.000000e+00 1.154087e-04 295.07 -2.00 20.00 -2.00 500.45 0.00e+00 2.817491e-01 2.554900e-03 4.954250e-02 -6.000000e+00 7.893666e-02 227.29 -2.00 3.11 -2.00 502.05 0.00e+00 3.013 0.000 489.00 513.00 1 1.3082e+00 1.9663e-04 6.0955e-03 -6.0000e+00 6.0917e-03 1.1579e-03 4.9861e-05 1.2490e-03 -6.0000e+00 1.5647e-03 3.3162e-01 1.4249e-03 1.3714e-05 4.8655e-05 -6.0000e+00 4.5288e-04 7.1598e-02 -2.2576e-05 11 8 0 10 0 0 -14.47 23.20 0.30 0.07160 0.08148 539 114 1 4 0 21.350 26.21 20.00 23.20 34.48 0.0 999.10 -630 -403 -236 -306 -48 494 565 449 383 279 187 -129 -327 -349 -503 -522 -201 174 32 -123 135 289 428 688 586 363 292 -45 -587 -553 -464 -388 258 552 -50 -239 -18 -27 -172 -63 40 97 273 444 538 479 415 278 -94 -509 -686 -832 -821 -374 -127 -135 -198 -182 -10 284 492 487 376 404 250 70 29 -75 -266 -311 -196 -134 84 280 -51 -473 -452 -321 -337 -344 -425 -576 -350 -60 -179 -317 -153 22 132 356 678 930 727 545 466 222 -98 -269 -709 -923 -806 -312 157 38 -399 -477 -586 -404 -56 41 -100 -21 105 186 469 755 729 443 207 77 -26 161 457 318 181 299 179 248 421 78 -361 -413 -564 -590 -134 -12 -261 -124 133 114 214 381 364 338 146 -139 -423 -530 -440 900000 -602 -392 -236 -315 -49 507 587 469 399 287 190 -129 -325 -358 -516 -520 -203 179 34 -130 143 306 454 731 623 386 308 -46 -599 -551 -458 -387 263 575 -51 -246 -18 -28 -179 -65 42 101 287 453 551 489 437 288 -96 -507 -668 -830 -820 -363 -127 -137 -205 -189 -10 294 510 506 391 418 256 71 29 -74 -259 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