File name: Pandora246s1_IowaCityIA-WHS_20260124_L2Fit_fout2c2d20230109p1-8.txt File generation date: 20260125T062058.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Charles Stanier Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 246 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora246_OF_v2d20221122.txt Instrument calibration file used: Pandora246s1_CF_v2d20230109.txt Level 1 file used: Pandora246s1_IowaCityIA-WHS_20260124_L1_smca1c2d20230109p1-8.txt Full location name: West High School, Iowa City, IA Short location name: IowaCityIA-WHS Country of location: United States Location latitude [deg]: 41.6548 Location longitude [deg]: -91.5827 Location altitude [m]: 235 Local noon date: 20260124 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 198 339 Nominal wavelengths inside fitting window [nm]: 305.1105 305.2516 305.3926 305.5337 305.6748 305.8158 305.9568 306.0979 306.2389 306.3799 306.5209 306.6618 306.8028 306.9438 307.0847 307.2256 307.3666 307.5075 307.6484 307.7892 307.9301 308.0710 308.2118 308.3527 308.4935 308.6343 308.7751 308.9159 309.0567 309.1974 309.3382 309.4789 309.6197 309.7604 309.9011 310.0418 310.1825 310.3232 310.4638 310.6045 310.7451 310.8858 311.0264 311.1670 311.3076 311.4482 311.5887 311.7293 311.8699 312.0104 312.1509 312.2914 312.4319 312.5724 312.7129 312.8534 312.9938 313.1343 313.2747 313.4151 313.5555 313.6959 313.8363 313.9767 314.1171 314.2574 314.3977 314.5381 314.6784 314.8187 314.9590 315.0993 315.2395 315.3798 315.5200 315.6603 315.8005 315.9407 316.0809 316.2211 316.3613 316.5015 316.6416 316.7817 316.9219 317.0620 317.2021 317.3422 317.4823 317.6224 317.7624 317.9025 318.0425 318.1825 318.3225 318.4625 318.6025 318.7425 318.8825 319.0224 319.1624 319.3023 319.4422 319.5821 319.7220 319.8619 320.0018 320.1417 320.2815 320.4213 320.5612 320.7010 320.8408 320.9806 321.1204 321.2601 321.3999 321.5396 321.6794 321.8191 321.9588 322.0985 322.2382 322.3779 322.5175 322.6572 322.7968 322.9364 323.0761 323.2157 323.3552 323.4948 323.6344 323.7740 323.9135 324.0530 324.1926 324.3321 324.4716 324.6110 324.7505 324.8900 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260124T155703.0Z 9520.664618 126 1 53.85 2 69.00 144.15 93.23 76.24 0.00 1 0.00 1 0 17 8.529e-02 3.101e-02 1.042e-02 2.242e-03 3.763499e-01 1.126502e-03 4.730649e-03 -6.000000e+00 4.829445e-02 223.93 -2.00 3.52 -2.00 317.89 0.00e+00 -8.439392e-03 1.845257e-04 8.074500e-04 -6.000000e+00 2.070772e-03 273.26 -2.00 20.00 -2.00 317.35 0.00e+00 2.763 0.000 302.00 328.00 3 4.8463e+00 2.9858e-03 3.3568e-02 -6.0000e+00 1.1940e-01 5.1211e-02 3.3645e-03 2.3108e-02 -6.0000e+00 1.2971e-01 -1.1395e-02 2.2009e-03 1.0308e-02 -6.0000e+00 7.7030e-02 -1.3373e-02 1.1532e-03 7.8404e-03 -6.0000e+00 3.3418e-02 1.8284e-04 -6.6058e-04 6.2508e-05 6.4960e-05 -6.0000e+00 2.2727e-03 -3.6392e-02 6.4280e-05 12 9 8 11 8 0 96.79 22.57 0.61 -0.03639 -0.04136 16 2 1 5 0 3365.080 31.50 20.00 22.57 -4.49 2.9 721.98 -38609 -19980 -33698 -29549 -17303 -32919 -15319 17662 -1550 1181 18693 20577 4668 14947 -5208 2880 8772 1203 8007 -18234 1520 5663 -9310 8984 515 7737 11440 5215 9539 4708 -3247 3696 -2574 -8323 -871 -6476 -23 -2774 1502 6190 5518 8041 6697 4535 2879 377 -356 -3925 171 1436 -1255 2856 340 1495 5444 4210 3713 -36531 5370 3927 3232 1150 1962 934 107 -633 945 126 383 3181 1520 1411 1191 2251 1310 2016 1626 1213 80 -1189 8 -1150 -1982 -1351 -1602 923 -12 1563 -198 -73 762 1943 1584 1548 1578 139 -222 -229 -732 -872 -726 -226 -1061 -868 -1353 -939 -1312 -1204 -195 40 172 424 1268 757 893 1053 808 83 -193 -729 -520 -48 -383 451 991 -467 728 738 -300 -762 -653 37 -126 366 454 -278 754 716 -265 -319 -495 -493 -3207 -1507 -2983 -2351 -1097 -2432 -1072 1062 -132 108 1459 1642 487 1594 -703 396 1194 185 1204 -3710 260 936 -1913 1730 120 1783 2535 1133 1810 921 -738 859 -701 -2479 -226 -1775 -7 -902 579 2721 2497 3724 3211 2204 1397 185 -172 -1935 80 689 -669 1593 209 902 3317 2706 2475 -31691 3391 2462 2085 815 1511 728 83 -463 694 94 290 2680 1332 1286 1077 2045 1103 1504 1192 869 62 -1004 7 -1149 -2012 -1434 -1834 1039 -14 1876 -240 -85 850 1969 1599 1567 1633 163 -276 -300 -1013 -1174 -907 -271 -1214 -1041 -1771 -1217 -1790 -1642 -280 60 271 675 1933 1138 1237 1459 1134 117 -293 -1110 -791 -74 -579 646 1415 -646 952 1000 -426 -1176 -1017 59 -207 602 796 -491 1346 1305 -484 -562 -872 -833 SS 20260124T160259.2Z 9520.668741 129 1 55.89 2 68.36 145.49 92.17 77.18 0.00 1 0.00 1 0 17 6.811e-02 2.507e-02 7.876e-03 1.908e-03 3.641026e-01 9.601624e-04 4.539998e-03 -6.000000e+00 3.856295e-02 223.93 -2.00 3.52 -2.00 317.64 0.00e+00 -5.770396e-03 1.464182e-04 5.874116e-04 -6.000000e+00 1.653528e-03 273.26 -2.00 20.00 -2.00 317.09 0.00e+00 2.687 0.000 302.00 328.00 3 4.6764e+00 2.5312e-03 3.2271e-02 -6.0000e+00 9.5344e-02 5.3740e-02 2.8446e-03 2.0625e-02 -6.0000e+00 1.0358e-01 -1.3054e-02 1.8210e-03 9.6133e-03 -6.0000e+00 6.1510e-02 -1.1221e-02 9.4630e-04 5.6401e-03 -6.0000e+00 2.6683e-02 2.3438e-04 -9.0465e-04 5.2990e-05 4.8334e-05 -6.0000e+00 1.8150e-03 -3.6247e-02 4.0651e-05 12 8 8 10 0 0 96.90 22.59 0.68 -0.03625 -0.04304 21 2 1 5 0 2661.000 31.50 20.00 22.59 -4.28 2.9 723.56 -29354 -16817 -22780 -27003 -14477 -29168 -12989 17684 -5989 3053 9002 17075 4849 11601 -6502 1609 5599 183 2048 -13496 881 4948 -6566 6620 -110 4044 10506 3356 7272 3798 -2790 1670 -576 -4588 -1932 -5877 -24 -2735 620 3867 4152 5534 4544 3352 2829 -65 142 -3184 163 2058 -283 1526 371 1133 3807 3502 3115 -29207 3623 2489 2354 846 1820 1303 379 -485 882 215 901 1894 1589 1184 1044 1960 925 1229 855 811 -257 -1209 -69 -1041 -2173 -764 -1870 267 -208 1242 -256 50 424 1319 1373 1674 1023 267 -357 143 -582 -529 -385 -57 -625 -351 -1273 -764 -1195 -912 -187 158 91 211 667 309 722 944 567 393 -37 -258 -441 -37 -319 620 832 -555 969 421 -318 -582 -424 211 -24 36 142 -47 699 479 -282 -166 -398 -618 -2408 -1470 -1972 -2517 -1069 -2463 -1037 1220 -606 306 862 1575 569 1326 -1020 258 909 33 379 -3031 175 947 -1492 1461 -28 1061 2580 821 1574 843 -713 448 -159 -1363 -572 -1650 -7 -988 246 1764 2084 2874 2443 1818 1523 -35 77 -1742 86 1093 -154 887 234 756 2414 2309 2119 -25577 2365 1615 1570 617 1442 1044 305 -366 663 162 693 1650 1425 1107 967 1714 798 944 642 593 -204 -1042 -63 -1061 -2262 -825 -2078 311 -255 1459 -304 60 460 1377 1414 1717 1083 301 -431 192 -784 -693 -491 -69 -728 -427 -1616 -1013 -1588 -1273 -264 241 141 329 1001 454 1020 1266 771 562 -54 -400 -686 -56 -470 907 1155 -746 1287 582 -460 -871 -671 327 -39 60 243 -81 1220 856 -505 -287 -686 -1021 SS 20260124T162327.9Z 9520.682962 135 1 52.03 2 66.32 150.24 88.48 80.40 0.00 1 0.00 1 0 17 5.431e-02 2.439e-02 6.838e-03 2.000e-03 3.343658e-01 1.004359e-03 4.194524e-03 -6.000000e+00 3.075691e-02 223.93 -2.00 3.52 -2.00 317.31 0.00e+00 -4.706686e-03 1.415609e-04 4.824963e-04 -6.000000e+00 1.318770e-03 273.26 -2.00 20.00 -2.00 316.77 0.00e+00 2.472 0.000 302.00 328.00 3 4.8911e+00 2.6338e-03 2.9595e-02 -6.0000e+00 7.6044e-02 4.9448e-02 2.9528e-03 1.8497e-02 -6.0000e+00 8.2607e-02 -1.2358e-02 1.8269e-03 8.7686e-03 -6.0000e+00 4.9056e-02 -9.0160e-03 9.3243e-04 4.6567e-03 -6.0000e+00 2.1284e-02 2.4117e-04 -7.4463e-04 5.5677e-05 4.2184e-05 -6.0000e+00 1.4473e-03 -3.6891e-02 5.8552e-05 12 9 9 12 9 1 98.95 22.68 0.57 -0.03689 -0.04249 15 2 1 5 0 3251.470 31.50 20.01 22.68 -3.23 2.9 733.58 -25984 -12553 -18652 -15874 -10630 -21404 -10129 9783 -3670 1900 8570 12733 861 9044 -4761 1368 5362 1503 4034 -10389 -462 3106 -6393 7472 155 3804 6715 2453 6070 3281 -3848 2357 -792 -4131 -1675 -3635 13 -2358 806 2967 3153 4650 3802 1724 2132 -572 346 -3576 732 714 -642 1618 392 1242 4182 2878 2789 -28112 3331 2611 2288 1103 2253 1399 422 -530 945 33 853 1946 896 1007 1116 1718 888 1035 1229 273 -350 -1257 -266 -1356 -2187 -1075 -1373 399 -348 1092 56 -78 206 1187 1063 1383 1305 203 -103 308 -400 -614 -619 90 -475 -384 -1337 -976 -1178 -733 -166 -203 41 270 1193 229 791 719 642 131 -91 -315 -500 -268 -164 536 894 -477 989 765 -191 -199 -461 185 -60 232 14 -273 632 476 -268 -76 -599 -538 -2801 -1295 -2093 -1621 -1014 -2026 -1037 956 -428 226 959 1418 121 1339 -923 275 1087 331 905 -2561 -115 744 -1623 1976 44 1095 1870 661 1585 870 -1076 676 -257 -1424 -527 -1157 4 -902 366 1445 1685 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