File name: Pandora101s1_Izana_20200212_L2Fit_fout2c18d20191026p1-8.txt File generation date: 20240504T161537.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c18p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v5d20170928.txt Instrument calibration file used: Pandora101s1_CF_v18d20191026.txt Level 1 file used: Pandora101s1_Izana_20200212_L1_smca1c18d20191026p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20200212 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 11 baseline for VP20191026 First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.0349 305.1758 305.3166 305.4574 305.5982 305.7390 305.8798 306.0206 306.1614 306.3021 306.4428 306.5836 306.7243 306.8650 307.0057 307.1464 307.2870 307.4277 307.5683 307.7090 307.8496 307.9902 308.1308 308.2714 308.4120 308.5525 308.6931 308.8336 308.9742 309.1147 309.2552 309.3957 309.5362 309.6766 309.8171 309.9576 310.0980 310.2384 310.3788 310.5192 310.6596 310.8000 310.9404 311.0807 311.2211 311.3614 311.5018 311.6421 311.7824 311.9227 312.0629 312.2032 312.3435 312.4837 312.6239 312.7641 312.9044 313.0445 313.1847 313.3249 313.4651 313.6052 313.7454 313.8855 314.0256 314.1657 314.3058 314.4459 314.5859 314.7260 314.8660 315.0061 315.1461 315.2861 315.4261 315.5661 315.7061 315.8460 315.9860 316.1259 316.2659 316.4058 316.5457 316.6856 316.8255 316.9653 317.1052 317.2450 317.3849 317.5247 317.6645 317.8043 317.9441 318.0839 318.2236 318.3634 318.5031 318.6429 318.7826 318.9223 319.0620 319.2017 319.3413 319.4810 319.6206 319.7603 319.8999 320.0395 320.1791 320.3187 320.4583 320.5978 320.7374 320.8769 321.0165 321.1560 321.2955 321.4350 321.5745 321.7139 321.8534 321.9929 322.1323 322.2717 322.4111 322.5505 322.6899 322.8293 322.9687 323.1080 323.2474 323.3867 323.5260 323.6653 323.8046 323.9439 324.0832 324.2224 324.3617 324.5009 324.6401 324.7793 324.9185 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200212T080331.7Z 7347.335783 228 1 49.32 2 87.30 107.29 62.88 256.84 0.00 1 0.00 1 0 33 6.048e-01 9.981e-02 2.882e-01 4.282e-02 9.768738e-01 2.368051e-02 9.948816e-03 -6.000000e+00 3.389808e-01 223.78 -2.00 3.19 -2.00 320.84 0.00e+00 -2.295271e-02 5.000650e-03 9.298573e-03 -6.000000e+00 1.559027e-02 272.58 -2.00 20.00 -2.00 320.10 0.00e+00 14.471 0.031 302.00 328.00 3 -6.6643e-02 6.7528e-02 1.3429e-01 -6.0000e+00 8.3929e-01 2.6957e+00 7.8911e-02 1.0281e-01 -6.0000e+00 9.1885e-01 -2.1586e+00 4.4629e-02 2.4753e-02 -6.0000e+00 5.4029e-01 5.6427e-01 2.4177e-02 2.0399e-02 -6.0000e+00 2.3591e-01 2.7613e-06 7.0203e-03 1.0585e-03 2.1732e-04 -6.0000e+00 1.6103e-02 -1.7224e-03 0.0000e+00 12 8 8 10 0 0 -22.67 17.05 1.11 -0.00172 0.05103 14 3 1 5 0 3522.383 21.58 14.99 17.05 900000 -3514 900000 38471 900000 289553 -32592 900000 15522 149310 -13746 43012 37 900000 17776 94862 -17749 107184 -20758 127191 145984 52125 69288 29849 207828 -7148 900000 -30997 83584 -61731 900000 39999 900000 10255 73245 -31147 29742 50284 96696 900000 23350 177334 1772 900000 -37176 14931 33085 136864 5413 900000 21083 153298 25110 26066 900000 43154 102905 53831 88298 -14959 81215 -38302 12744 30897 25608 -30609 1928 16125 -5603 20080 -10775 186030 -11988 50511 17518 138993 -48832 19749 -67731 78868 35401 33784 43643 18 19756 8601 24328 -9864 13226 -33836 26847 -15062 22489 35425 -14455 -9897 16448 8255 7153 12405 9994 17972 -33337 21210 -25211 13997 -14828 14919 -3901 23731 9576 7788 6322 -8966 -9433 195 5750 7692 -1625 1900 7462 3571 8728 -8609 6590 -8693 4853 2172 1327 -89 -1073 -2469 -8144 1813 -3914 989 -2561 7895 408 -728 -1141 3215 17 900000 -918 900000 4835 900000 12063 -6856 900000 2651 7186 -3188 5831 8 900000 3741 9744 -5361 9558 -5996 8181 7168 5905 7039 5167 8658 -1948 900000 -7837 5783 -17116 900000 5148 900000 1829 6269 -6807 3898 6361 9449 900000 5768 9851 505 900000 -12499 2788 4937 7286 1074 900000 4168 9158 5554 6101 900000 9316 12544 9868 10286 -4226 8618 -13392 3031 6787 6052 -11910 551 4214 -2005 6403 -4874 12669 -5146 10678 4406 9243 -18790 4053 -36834 12461 9887 10999 14041 9 8649 4359 10743 -5981 6221 -23259 9569 -7598 7946 11998 -9054 -6950 10478 6430 6082 9820 7383 10823 -29439 11406 -22395 8938 -13083 10815 -3816 20585 10772 9660 8150 -13264 -13452 245 6956 9579 -2338 2673 9474 4416 10052 -11333 7388 -10995 5253 2664 1933 -155 -2085 -5308 -19697 4329 -10588 2678 -7315 20968 1137 -1938 -2856 7241 39 SS 20200212T081620.2Z 7347.344678 232 1 48.43 2 84.61 108.87 65.59 258.54 0.00 1 0.00 1 0 17 6.355e-01 1.674e-02 1.303e-01 3.651e-03 9.952151e-01 1.998181e-03 9.798447e-03 -6.000000e+00 3.501643e-01 223.78 -2.00 3.19 -2.00 322.03 0.00e+00 4.209849e-03 1.042021e-03 1.572278e-03 -6.000000e+00 1.500030e-02 272.58 -2.00 20.00 -2.00 321.63 0.00e+00 9.358 0.008 302.00 328.00 3 5.0396e-01 7.1075e-03 8.5671e-02 -6.0000e+00 8.6590e-01 7.5826e-01 1.0756e-02 5.0941e-02 -6.0000e+00 9.4399e-01 -1.0388e+00 1.1791e-02 2.9179e-02 -6.0000e+00 5.6055e-01 4.2138e-01 5.4671e-03 1.1363e-02 -6.0000e+00 2.4078e-01 1.0288e-04 -8.2577e-04 8.6950e-05 1.4506e-04 -6.0000e+00 1.5944e-02 -2.6255e-03 0.0000e+00 12 8 8 10 0 0 14.61 17.05 0.24 -0.00263 -0.00883 163 38 1 5 0 297.123 21.58 15.00 17.05 -135402 -226472 -147242 -170004 -144665 -195382 -216334 -183303 -152834 -211410 -183383 -232924 -123525 -119150 -102493 -137371 -73804 -75945 -76895 -5435 -49316 -24311 -53621 -39589 -78289 -41903 -49724 -93246 -59727 -75675 -14853 -24009 -18847 -16858 1780 -27842 -9905 -23444 59966 20665 33718 16417 25238 20749 24936 -3750 11490 15765 10858 36323 22768 43213 22228 35464 28804 27210 20432 28532 18323 11577 11375 10963 12730 20079 19979 11302 11801 9595 14772 10606 13627 12073 10391 6482 7438 14 -2544 -4418 -2533 3473 2446 2744 846 886 -393 1267 1606 1574 -459 1821 -320 1658 -3255 -2164 -3964 -3010 -2459 -1066 -813 -1059 -1067 -1757 -2711 -2717 -2461 -3066 -2137 -1991 -1597 -450 -87 -368 43 -425 -866 -279 23 178 10 831 842 1592 1645 1602 909 1150 1059 1216 571 550 587 368 82 -264 -254 -206 253 551 349 -233 -144 -933 -1373 -920 -4544 -1430 -1981 -1236 -2276 -3151 -2076 -1523 -3626 -2433 -5654 -1451 -1824 -1751 -3779 -1366 -1450 -1593 -62 -860 -312 -916 -634 -1979 -761 -974 -2689 -1191 -1913 -259 -590 -530 -516 43 -843 -261 -818 1110 684 1116 696 1024 894 1021 -188 509 709 555 1733 1282 2280 1611 2479 2312 2316 1918 2438 1637 1042 1016 1072 1430 2482 2774 1741 1826 1605 2610 2099 2927 2758 2374 1423 1570 3 -481 -885 -529 849 736 973 347 388 -185 620 820 828 -245 919 -154 737 -1497 -1045 -2272 -1912 -1865 -945 -820 -1111 -1062 -1557 -2101 -2009 -1938 -2587 -1880 -1895 -1703 -517 -117 -554 67 -673 -1334 -412 34 275 16 1395 1376 2413 2354 2233 1240 1523 1354 1617 900 969 1184 822 184 -645 -671 -575 673 1474 993 -637 -361 -2141 -3152 SS 20200212T082910.3Z 7347.353591 236 1 48.60 2 81.95 110.50 68.31 260.19 0.00 1 0.00 1 0 17 6.186e-01 9.749e-03 3.157e-02 9.192e-04 7.836826e-01 4.760006e-04 7.987498e-03 -6.000000e+00 3.408924e-01 223.78 -2.00 3.19 -2.00 321.07 0.00e+00 2.692346e-03 2.074250e-04 1.364260e-03 -6.000000e+00 1.460304e-02 272.58 -2.00 20.00 -2.00 320.64 0.00e+00 6.710 0.003 302.00 328.00 3 3.4377e-01 1.4953e-03 6.2631e-02 -6.0000e+00 8.4297e-01 1.4377e-01 2.1078e-03 3.7993e-02 -6.0000e+00 9.1896e-01 -1.8784e-01 2.3583e-03 2.1720e-02 -6.0000e+00 5.4569e-01 7.0315e-02 1.1465e-03 8.1825e-03 -6.0000e+00 2.3443e-01 1.0378e-03 -2.8157e-04 2.2555e-05 8.9669e-05 -6.0000e+00 1.5520e-02 -3.3206e-03 0.0000e+00 12 8 8 10 0 0 -1.92 17.05 0.20 -0.00332 -0.00544 600 142 1 5 0 80.859 21.69 15.00 17.05 -230323 -192295 -201426 -181374 -204349 -203238 -207551 -185695 -172868 -190799 -158187 -181710 -122346 -122792 -76151 -95206 -50524 -59705 -41605 -37833 -43635 -42032 -45588 -35768 -43120 -30041 -37006 -28270 -47349 -32271 -34109 -12336 -10881 -1926 -10334 -10183 -10713 -6405 140 5037 5438 2340 8250 3774 5430 1814 6573 2518 5269 4616 7179 6686 7100 7704 6589 5890 5047 5713 2491 2511 1416 4666 4405 5917 4587 3803 2340 2202 1942 1983 2295 1825 1472 160 468 -1186 -1517 -3822 -1952 -1708 -983 -1512 -1655 -1810 -1398 -478 25 462 566 661 118 -104 -1204 -981 -1328 -517 -391 405 246 67 -497 -903 -898 -688 -876 -1206 -909 -865 -212 215 529 310 395 136 -56 -63 66 235 50 145 39 413 654 579 486 414 -24 707 127 331 229 132 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