File name: Pandora101s1_Izana_20200506_L2Fit_fout2c14d20200331p1-8.txt File generation date: 20240504T153653.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v6d20170928.txt Instrument calibration file used: Pandora101s1_CF_v14d20200331.txt Level 1 file used: Pandora101s1_Izana_20200506_L1_smca1c14d20200331p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20200506 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 11 "Baseline" for new VP 20200331 First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.0143 305.1552 305.2960 305.4369 305.5777 305.7185 305.8593 306.0000 306.1408 306.2816 306.4223 306.5630 306.7038 306.8445 306.9852 307.1259 307.2665 307.4072 307.5478 307.6885 307.8291 307.9697 308.1103 308.2509 308.3915 308.5321 308.6727 308.8132 308.9537 309.0943 309.2348 309.3753 309.5158 309.6563 309.7967 309.9372 310.0776 310.2181 310.3585 310.4989 310.6393 310.7797 310.9201 311.0604 311.2008 311.3411 311.4815 311.6218 311.7621 311.9024 312.0427 312.1829 312.3232 312.4634 312.6037 312.7439 312.8841 313.0243 313.1645 313.3047 313.4449 313.5850 313.7252 313.8653 314.0054 314.1455 314.2856 314.4257 314.5658 314.7059 314.8459 314.9860 315.1260 315.2660 315.4060 315.5460 315.6860 315.8260 315.9659 316.1059 316.2458 316.3857 316.5256 316.6655 316.8054 316.9453 317.0852 317.2250 317.3649 317.5047 317.6445 317.7843 317.9241 318.0639 318.2037 318.3435 318.4832 318.6229 318.7627 318.9024 319.0421 319.1818 319.3215 319.4611 319.6008 319.7404 319.8801 320.0197 320.1593 320.2989 320.4385 320.5781 320.7176 320.8572 320.9967 321.1362 321.2757 321.4153 321.5547 321.6942 321.8337 321.9731 322.1126 322.2520 322.3914 322.5309 322.6703 322.8096 322.9490 323.0884 323.2277 323.3671 323.5064 323.6457 323.7850 323.9243 324.0636 324.2029 324.3421 324.4814 324.6206 324.7598 324.8990 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200506T071048.6Z 7431.299174 234 1 47.30 2 80.43 76.11 108.72 271.16 0.00 1 0.00 1 0 25 5.090e-01 1.642e-02 2.131e-01 6.103e-03 6.782080e-01 3.293657e-03 7.045534e-03 -6.000000e+00 2.902207e-01 228.84 -2.00 3.19 -2.00 320.78 0.00e+00 4.642506e-03 1.338601e-03 1.637130e-03 -6.000000e+00 1.381468e-02 277.59 -2.00 20.00 -2.00 320.27 0.00e+00 5.748 0.002 302.00 328.00 3 4.6527e+00 1.0213e-02 5.4503e-02 -6.0000e+00 7.2671e-01 1.7846e-01 1.3541e-02 3.3206e-02 -6.0000e+00 7.9078e-01 -2.1025e-01 1.3810e-02 1.9654e-02 -6.0000e+00 4.6504e-01 8.6719e-02 6.8175e-03 8.4964e-03 -6.0000e+00 2.0084e-01 2.8785e-05 -2.6953e-04 1.6218e-04 8.8451e-05 -6.0000e+00 1.3442e-02 2.3762e-03 0.0000e+00 12 8 8 10 0 0 99.26 16.81 0.36 0.00238 0.00035 13 3 1 5 0 3638.141 21.48 15.00 16.81 900000 -227179 900000 170468 900000 -89876 -197922 900000 -93215 900000 -158514 -30727 -142763 900000 -102496 249298 -69910 110126 -57609 900000 19974 900000 -15051 -3943 108110 -47939 900000 -44540 4582 -33483 112541 -8939 109945 5579 31214 -15136 61052 -1507 41343 23088 702 14549 2196 11586 -6618 10521 1382 20656 8640 32771 1564 404 6420 14087 13071 6490 -560 6889 2932 -664 18366 -1751 1342 3663 6344 2503 -488 -1790 -2399 1256 -1738 5641 -2406 581 2384 3841 -5259 -697 -7840 -1646 229 548 -1232 -3867 -2322 -669 -790 801 1841 -1006 959 989 677 -392 -2184 -1729 966 -554 -290 875 -197 -765 -2187 -236 -1551 -1549 -1173 -821 -354 1627 817 -88 894 480 -1707 -203 503 383 -1130 1287 414 225 1501 -143 1468 129 -214 635 500 5 -209 -279 -147 -260 -38 179 12 849 112 348 -662 -178 -1304 900000 -7331 900000 1013 900000 -756 -4824 900000 -1072 900000 -3792 -237 -3937 900000 -3213 1481 -2271 721 -2012 900000 371 900000 -390 -99 1021 -2075 900000 -1896 120 -1301 1304 -396 1877 282 1214 -865 1808 -93 2064 1650 70 1381 246 1232 -846 1172 172 2224 1083 3468 243 71 1178 2612 2606 1432 -136 1575 676 -154 3604 -445 375 1138 2087 848 -165 -619 -892 519 -820 2630 -1209 272 1019 1460 -1993 -250 -3239 -755 121 327 -820 -2784 -1738 -523 -648 668 1535 -840 744 721 472 -276 -1694 -1520 938 -616 -353 1080 -235 -844 -2219 -230 -1613 -1701 -1337 -980 -447 2220 1230 -141 1443 762 -2649 -299 728 573 -1785 2077 673 356 2276 -214 2108 182 -293 862 741 8 -373 -525 -286 -524 -80 394 28 1914 255 775 -1421 -363 -2572 SS 20200506T071859.6Z 7431.304857 239 1 49.21 2 78.68 77.01 110.46 272.08 0.00 1 0.00 1 0 17 2.709e-01 8.971e-03 1.183e-01 3.347e-03 5.952111e-01 1.717570e-03 6.181718e-03 -6.000000e+00 1.524644e-01 228.84 -2.00 3.19 -2.00 320.13 0.00e+00 2.223302e-03 5.814799e-04 5.078769e-04 -6.000000e+00 6.557621e-03 277.59 -2.00 20.00 -2.00 319.59 0.00e+00 4.929 0.001 302.00 328.00 3 4.4218e+00 5.0142e-03 4.6908e-02 -6.0000e+00 3.8078e-01 4.6306e-02 6.2371e-03 2.8455e-02 -6.0000e+00 4.1317e-01 -3.7948e-02 5.9409e-03 1.4990e-02 -6.0000e+00 2.4496e-01 1.0498e-02 3.0565e-03 5.4819e-03 -6.0000e+00 1.0547e-01 7.3849e-05 -8.6059e-05 8.7281e-05 5.0218e-05 -6.0000e+00 6.8654e-03 2.7041e-03 0.0000e+00 11 8 0 10 0 0 94.53 16.80 0.31 0.00270 0.00206 19 4 1 5 0 2589.933 21.38 15.00 16.80 900000 -107502 79657 -88076 -18425 -98753 -111358 -60597 -60709 -108553 -82930 -113328 -42784 36284 -26236 -13156 -41486 6390 -35267 22085 -29797 26505 -22800 5681 862 -12930 16017 -12360 -11502 -16502 9406 -12541 26817 994 396 -4552 6801 -6698 8715 2902 942 -417 1090 1561 -488 322 2286 2716 -868 9145 -902 -1007 3107 4197 1270 3952 -1403 4366 1906 201 3234 350 -792 1950 2838 -112 826 -557 -163 -873 3 2127 592 -288 754 134 -2127 -2873 -2730 -950 -293 77 -2582 -1767 -1510 -161 -324 571 986 814 1311 589 114 -256 -882 -500 -686 448 448 530 -386 -637 -1194 -554 -603 -995 -962 -609 -150 740 883 804 771 -102 -308 -502 -465 404 -470 472 -205 -17 521 294 415 437 -386 708 103 44 181 -438 -318 -29 126 73 101 467 147 -61 89 -428 -721 900000 -1702 260 -1304 -129 -1398 -1881 -725 -842 -2585 -1618 -3161 -748 383 -625 -336 -1554 169 -1503 583 -1341 706 -984 205 36 -645 634 -625 -555 -860 441 -862 1482 78 30 -350 503 -651 899 382 143 -69 187 276 -89 59 422 511 -174 1753 -206 -258 835 1207 399 1252 -484 1444 629 66 1043 124 -317 851 1309 -52 369 -252 -78 -477 2 1315 374 -177 431 70 -1041 -1388 -1395 -551 -194 56 -2107 -1497 -1340 -150 -313 566 980 794 1211 518 96 -213 -789 -495 -759 543 585 705 -499 -767 -1329 -605 -695 -1206 -1205 -794 -205 1081 1384 1320 1276 -166 -480 -757 -693 613 -747 774 -340 -28 821 453 621 638 -548 996 155 72 317 -803 -597 -56 255 153 216 1005 320 -131 182 -849 -1388 SS 20200506T072606.3Z 7431.309795 243 1 48.58 2 77.15 77.77 111.97 272.89 0.00 1 0.00 1 0 17 1.608e-01 6.752e-03 3.700e-02 2.039e-03 5.421334e-01 1.032034e-03 5.693803e-03 -6.000000e+00 9.048080e-02 228.84 -2.00 3.19 -2.00 319.67 0.00e+00 1.577856e-03 3.010259e-04 4.270834e-04 -6.000000e+00 3.879401e-03 277.59 -2.00 20.00 -2.00 319.11 0.00e+00 4.383 0.001 302.00 328.00 3 3.9667e+00 2.9235e-03 4.2054e-02 -6.0000e+00 2.2598e-01 2.7116e-02 3.4966e-03 2.5717e-02 -6.0000e+00 2.4508e-01 -2.2235e-02 3.0547e-03 1.3179e-02 -6.0000e+00 1.4539e-01 2.6761e-03 1.6083e-03 4.3809e-03 -6.0000e+00 6.2183e-02 1.8471e-04 -6.7054e-05 5.3427e-05 4.0784e-05 -6.0000e+00 4.0359e-03 2.4222e-03 0.0000e+00 11 8 0 10 0 0 98.84 16.80 0.12 0.00242 0.00192 42 10 1 5 0 1156.564 21.38 15.00 16.80 -26770 -60890 -27915 -43422 -61095 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