File name: Pandora101s1_Izana_20200606_L2Fit_fout2c14d20200331p1-8.txt File generation date: 20240504T150936.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v6d20170928.txt Instrument calibration file used: Pandora101s1_CF_v14d20200331.txt Level 1 file used: Pandora101s1_Izana_20200606_L1_smca1c14d20200331p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20200606 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 11 "Baseline" for new VP 20200331 First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.0143 305.1552 305.2960 305.4369 305.5777 305.7185 305.8593 306.0000 306.1408 306.2816 306.4223 306.5630 306.7038 306.8445 306.9852 307.1259 307.2665 307.4072 307.5478 307.6885 307.8291 307.9697 308.1103 308.2509 308.3915 308.5321 308.6727 308.8132 308.9537 309.0943 309.2348 309.3753 309.5158 309.6563 309.7967 309.9372 310.0776 310.2181 310.3585 310.4989 310.6393 310.7797 310.9201 311.0604 311.2008 311.3411 311.4815 311.6218 311.7621 311.9024 312.0427 312.1829 312.3232 312.4634 312.6037 312.7439 312.8841 313.0243 313.1645 313.3047 313.4449 313.5850 313.7252 313.8653 314.0054 314.1455 314.2856 314.4257 314.5658 314.7059 314.8459 314.9860 315.1260 315.2660 315.4060 315.5460 315.6860 315.8260 315.9659 316.1059 316.2458 316.3857 316.5256 316.6655 316.8054 316.9453 317.0852 317.2250 317.3649 317.5047 317.6445 317.7843 317.9241 318.0639 318.2037 318.3435 318.4832 318.6229 318.7627 318.9024 319.0421 319.1818 319.3215 319.4611 319.6008 319.7404 319.8801 320.0197 320.1593 320.2989 320.4385 320.5781 320.7176 320.8572 320.9967 321.1362 321.2757 321.4153 321.5547 321.6942 321.8337 321.9731 322.1126 322.2520 322.3914 322.5309 322.6703 322.8096 322.9490 323.0884 323.2277 323.3671 323.5064 323.6457 323.7850 323.9243 324.0636 324.2029 324.3421 324.4814 324.6206 324.7598 324.8990 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200606T063644.2Z 7462.275512 206 1 48.39 2 85.19 66.76 90.24 243.71 0.00 1 0.00 1 0 33 5.314e-01 1.835e-02 1.415e-01 4.616e-03 1.086519e+00 2.626398e-03 1.068594e-02 -6.000000e+00 2.994883e-01 229.00 -2.00 3.19 -2.00 322.27 0.00e+00 3.895175e-03 1.544333e-03 2.232352e-03 -6.000000e+00 1.295660e-02 280.07 -2.00 20.00 -2.00 321.86 0.00e+00 10.162 0.011 302.00 328.00 3 2.1540e-02 1.0499e-02 9.6385e-02 -6.0000e+00 7.4765e-01 1.1380e+00 1.5111e-02 6.2455e-02 -6.0000e+00 8.1019e-01 -1.5239e+00 1.4792e-02 3.1827e-02 -6.0000e+00 4.8128e-01 6.1133e-01 6.7748e-03 1.1588e-02 -6.0000e+00 2.0639e-01 7.6388e-05 -1.4897e-03 1.0813e-04 1.3615e-04 -6.0000e+00 1.3338e-02 -2.4525e-03 0.0000e+00 12 8 8 10 0 0 36.31 16.73 0.26 -0.00245 -0.01365 158 37 1 5 0 306.268 21.38 14.99 16.73 -134450 -117998 -129369 -49340 -144789 -157369 -197451 -131312 -166521 -174823 -168341 -173003 -140857 -113750 -47801 -103190 -21461 -53016 -17675 -27329 6750 -53773 -30148 -53121 -36687 -75489 -27168 -49801 -88487 -45333 -73213 -41593 -22748 25387 -24080 3083 -2293 -9152 13994 32358 40687 36010 24341 27354 26210 -4696 27200 6950 39218 32017 48008 31211 43752 41485 43903 30903 37237 30261 26369 29791 11958 16902 9124 21984 20259 29997 15486 22682 15709 16697 17382 23740 15391 11544 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1562 400 1509 323 -192 -247 -220 -163 1722 1269 -187 -921 -2667 -3581 SS 20200606T064859.3Z 7462.284019 210 1 48.54 2 82.70 68.10 92.59 245.08 0.00 1 0.00 1 0 17 7.589e-01 1.175e-02 3.958e-02 1.084e-03 8.560456e-01 5.829051e-04 8.857057e-03 -6.000000e+00 4.277746e-01 229.00 -2.00 3.19 -2.00 321.36 0.00e+00 3.868260e-03 2.871743e-04 2.862036e-03 -6.000000e+00 1.850339e-02 280.07 -2.00 20.00 -2.00 320.87 0.00e+00 7.290 0.004 302.00 328.00 3 3.1932e-02 1.9937e-03 7.0145e-02 -6.0000e+00 1.0679e+00 2.4070e-01 2.9203e-03 4.4807e-02 -6.0000e+00 1.1572e+00 -3.2038e-01 3.1602e-03 2.5724e-02 -6.0000e+00 6.8740e-01 1.2629e-01 1.4823e-03 9.2174e-03 -6.0000e+00 2.9485e-01 8.2094e-04 -6.3713e-04 2.6124e-05 1.1753e-04 -6.0000e+00 1.9046e-02 -3.7457e-03 0.0000e+00 12 8 8 10 0 0 1.05 16.76 0.21 -0.00375 -0.00853 591 140 1 5 0 82.126 21.38 15.00 16.76 -273337 -239546 -234050 -222919 -232809 -245358 -233915 -233213 -207136 -216035 -196714 -219294 -168248 -163683 -121328 -121474 -74396 -81951 -73368 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1699 1556 1267 716 502 -284 -507 -1108 -626 -426 -114 -377 -894 -1072 -910 -418 -192 275 402 483 -5 -224 -1043 -1172 -1285 -1015 -794 -51 62 -86 -714 -1235 -1235 -872 -1297 -1875 -1312 -1097 -572 187 651 662 699 308 -161 -236 12 584 378 291 332 1105 1433 1199 1036 808 97 922 498 476 562 259 -224 -563 -798 -390 -168 709 634 -42 -372 -912 -1259 SS 20200606T065848.3Z 7462.290837 213 1 48.58 2 80.68 69.15 94.48 246.15 0.00 1 0.00 1 0 17 4.689e-01 8.078e-03 1.751e-02 5.523e-04 7.185044e-01 2.886573e-04 7.444211e-03 -6.000000e+00 2.643106e-01 229.00 -2.00 3.19 -2.00 320.65 0.00e+00 2.552625e-03 1.167075e-04 1.286609e-03 -6.000000e+00 1.143207e-02 280.07 -2.00 20.00 -2.00 320.12 0.00e+00 5.888 0.002 302.00 328.00 3 1.3954e-02 8.8975e-04 5.6561e-02 -6.0000e+00 6.5984e-01 9.2019e-02 1.1820e-03 3.5078e-02 -6.0000e+00 7.1497e-01 -1.0340e-01 1.2103e-03 1.9083e-02 -6.0000e+00 4.2472e-01 3.3251e-02 6.0006e-04 6.7241e-03 -6.0000e+00 1.8219e-01 2.6463e-03 -4.5246e-04 1.3697e-05 6.9907e-05 -6.0000e+00 1.1767e-02 -4.2348e-03 0.0000e+00 11 8 0 10 0 0 23.46 16.78 0.23 -0.00423 -0.00763 1080 255 1 5 0 44.897 21.38 15.00 16.78 -177446 -151607 -155069 -135338 -156065 -162181 -164853 -142031 -136368 -126853 -124093 -122793 -102201 -84285 -63160 -58348 -43802 -43119 -32925 -35131 -25100 -32358 -29663 -28251 -20810 -24617 -19355 -24111 -28892 -25372 -19782 -9949 -7311 -3590 -8114 -8486 -10377 -3407 -2009 2945 2585 2985 2953 2648 2970 2272 2440 1480 2021 1669 3923 4096 4966 4602 4595 3770 3538 2462 1932 1017 1646 2644 3345 3981 3120 2103 672 291 374 1470 1379 1351 656 275 -190 -1148 -2212 -3231 -2279 -1579 -1178 -1133 -1570 -1718 -1261 -570 58 280 734 901 566 246 -603 -782 -888 -446 -315 591 291 162 -380 -709 -855 -396 -817 -1132 -951 -677 -254 297 547 461 505 240 -12 -83 24 299 254 54 -26 184 464 398 456 337 -109 528 267 216 117 9 -257 -227 -356 -206 -78 291 287 -46 -87 -233 -287 -1739 -1437 -1721 -1268 -1656 -1730 -1918 -1515 -1601 -1517 -1531 -1634 -1398 -1285 -1021 -1131 -861 -950 -729 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