File name: Pandora101s1_Izana_20200703_L2Fit_fwvt1c14d20200331p1-8.txt File generation date: 20240504T150607.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v6d20170928.txt Instrument calibration file used: Pandora101s1_CF_v14d20200331.txt Level 1 file used: Pandora101s1_Izana_20200703_L1_smca1c14d20200331p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20200703 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 11 "Baseline" for new VP 20200331 First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0431 492.1641 492.2850 492.4059 492.5268 492.6477 492.7686 492.8894 493.0103 493.1311 493.2519 493.3727 493.4935 493.6142 493.7349 493.8557 493.9764 494.0971 494.2177 494.3384 494.4590 494.5797 494.7003 494.8209 494.9414 495.0620 495.1825 495.3031 495.4236 495.5441 495.6645 495.7850 495.9054 496.0259 496.1463 496.2667 496.3871 496.5074 496.6278 496.7481 496.8684 496.9887 497.1090 497.2292 497.3495 497.4697 497.5899 497.7101 497.8303 497.9505 498.0706 498.1908 498.3109 498.4310 498.5511 498.6711 498.7912 498.9112 499.0312 499.1512 499.2712 499.3912 499.5111 499.6310 499.7510 499.8709 499.9908 500.1106 500.2305 500.3503 500.4701 500.5899 500.7097 500.8295 500.9492 501.0690 501.1887 501.3084 501.4281 501.5477 501.6674 501.7870 501.9067 502.0263 502.1458 502.2654 502.3850 502.5045 502.6240 502.7435 502.8630 502.9825 503.1019 503.2214 503.3408 503.4602 503.5796 503.6990 503.8183 503.9377 504.0570 504.1763 504.2956 504.4148 504.5341 504.6533 504.7726 504.8918 505.0110 505.1301 505.2493 505.3684 505.4875 505.6067 505.7257 505.8448 505.9639 506.0829 506.2019 506.3209 506.4399 506.5589 506.6779 506.7968 506.9157 507.0346 507.1535 507.2724 507.3912 507.5101 507.6289 507.7477 507.8665 507.9853 508.1040 508.2228 508.3415 508.4602 508.5789 508.6976 508.8162 508.9349 509.0535 509.1721 509.2907 509.4093 509.5278 509.6464 509.7649 509.8834 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20200703T064210.4Z 7489.279287 165 1 48.78 2 85.11 66.56 117.56 258.50 0.00 1 0.00 1 0 22 2.877e-03 2.861e-03 3.067e-04 3.064e-04 6.310614e+03 2.050305e+01 3.432486e+02 -6.000000e+00 1.602565e+02 281.50 -2.00 20.00 -2.00 505.29 0.00e+00 9.321796e-04 8.456285e-06 5.739687e-05 -6.000000e+00 8.056891e-05 281.50 -2.00 20.00 -2.00 500.53 0.00e+00 7.703641e-01 6.081962e-03 4.034574e-02 -6.000000e+00 5.735180e-02 228.40 -2.00 3.19 -2.00 502.11 0.00e+00 10.046 0.010 489.00 513.00 1 4.7575e+00 4.6540e-04 1.1600e-02 -6.0000e+00 4.3907e-03 4.9088e-03 1.1941e-04 1.1520e-03 -6.0000e+00 1.1472e-03 5.2290e-03 1.6816e-03 2.9846e-05 5.2725e-05 -6.0000e+00 2.9380e-04 4.9886e-03 -5.1502e-06 10 0 0 10 0 0 95.13 16.93 1.30 0.00499 0.01665 78 18 1 4 0 625.322 21.58 15.01 16.93 -552 -482 -284 -13 202 351 524 528 545 395 164 74 -65 -142 -210 -190 -113 59 301 218 192 235 207 216 352 318 58 74 5 -357 -499 -353 -351 -12 160 33 -74 -30 -157 -204 -137 -75 91 228 293 341 245 102 -94 -179 -445 -557 -622 -473 -270 -129 58 62 148 228 267 327 282 313 363 187 71 -110 -134 -231 -285 -253 -234 -203 -117 -138 -267 -355 -335 -362 -425 -393 -406 -287 -290 -195 -167 -128 -191 -119 33 140 246 342 295 180 37 -223 -177 -482 -598 -540 -386 -171 -57 -108 -193 -241 -211 -77 -52 74 262 504 494 575 581 467 369 258 282 231 148 250 266 124 146 253 111 198 151 -102 -207 -191 -323 -103 71 39 216 279 163 174 231 244 100 40 -196 -354 -496 -467 -531 -460 -279 -13 205 355 539 549 566 406 167 74 -65 -142 -209 -191 -112 59 305 224 198 243 215 225 367 332 60 76 5 -358 -492 -348 -354 -12 167 34 -76 -31 -161 -208 -140 -77 94 234 302 353 252 104 -97 -179 -444 -543 -600 -459 -269 -129 59 62 149 230 270 331 287 318 366 190 71 -109 -132 -229 -281 -250 -228 -201 -116 -137 -260 -348 -325 -350 -413 -383 -400 -279 -285 -193 -166 -126 -189 -118 33 138 246 340 290 177 36 -214 -166 -456 -565 -507 -375 -168 -57 -108 -192 -237 -206 -75 -52 75 260 503 497 581 591 478 376 260 279 230 147 249 266 125 144 253 112 198 150 -100 -201 -184 -311 -100 70 39 217 278 164 176 235 249 102 41 -196 -355 -489 -458 SQ 20200703T065606.2Z 7489.288961 169 1 48.43 2 82.28 68.09 120.44 259.76 0.00 1 0.00 1 0 15 2.606e-03 2.595e-03 3.609e-04 3.604e-04 4.594074e+03 2.338380e+01 2.516765e+02 -6.000000e+00 1.451549e+02 281.50 -2.00 20.00 -2.00 505.26 0.00e+00 7.740949e-04 9.899808e-06 4.808422e-05 -6.000000e+00 7.297777e-05 281.50 -2.00 20.00 -2.00 500.45 0.00e+00 5.571787e-01 7.163735e-03 3.051496e-02 -6.000000e+00 5.194986e-02 228.40 -2.00 3.19 -2.00 502.04 0.00e+00 6.953 0.003 489.00 513.00 1 5.4144e+00 5.4798e-04 8.0887e-03 -6.0000e+00 3.9771e-03 8.8075e-03 1.4148e-04 8.3973e-04 -6.0000e+00 1.0392e-03 3.8712e-03 1.2906e-03 3.5355e-05 3.9673e-05 -6.0000e+00 2.6611e-04 8.7565e-03 -3.1898e-05 10 0 0 10 0 0 99.48 16.93 1.37 0.00876 0.01771 116 27 1 4 0 417.474 21.58 15.00 16.93 -512 -426 -203 98 171 391 492 472 476 360 119 71 101 -99 -197 -121 -109 15 292 202 153 277 200 155 344 221 56 -2 77 -358 -462 -371 -321 -123 4 49 -127 -39 -201 -117 -7 -28 63 130 295 273 278 94 -40 -145 -384 -517 -630 -529 -343 -143 58 57 170 228 140 301 257 290 275 177 91 -88 -141 -220 -324 -223 -247 -170 -66 -73 -240 -372 -257 -338 -357 -447 -351 -223 -191 -206 -125 -47 -182 -59 44 88 148 296 162 212 -31 -221 -229 -350 -488 -454 -456 -98 -3 -104 -197 -171 -153 -88 -71 -4 215 339 565 518 460 439 340 228 168 173 101 202 225 139 205 209 39 178 182 -47 -124 -173 -184 -19 81 63 206 306 251 157 174 128 90 -70 -38 -321 -435 -452 -498 -420 -200 100 172 403 516 485 489 377 123 73 102 -99 -195 -120 -110 16 298 210 160 288 209 162 360 232 59 -2 78 -363 -460 -369 -327 -126 5 52 -134 -41 -206 -119 -8 -28 65 135 310 288 291 97 -41 -144 -384 -506 -609 -514 -342 -143 59 58 174 233 144 310 265 298 281 178 91 -87 -141 -217 -319 -219 -245 -166 -65 -71 -238 -364 -248 -325 -345 -435 -344 -221 -185 -201 -123 -47 -179 -58 43 88 150 300 162 208 -30 -214 -216 -325 -452 -427 -443 -95 -3 -102 -198 -169 -150 -87 -71 -4 214 339 568 523 468 449 346 229 166 168 97 196 219 136 200 204 38 173 176 -46 -120 -166 -177 -18 78 62 204 307 254 156 173 128 90 -70 -38 -317 -421 -436 SQ 20200703T070503.3Z 7489.295177 172 1 48.67 2 80.45 69.04 122.30 260.58 0.00 1 0.00 1 0 15 2.404e-03 2.393e-03 2.821e-04 2.817e-04 3.671196e+03 1.780870e+01 2.037066e+02 -6.000000e+00 1.339229e+02 281.50 -2.00 20.00 -2.00 505.27 0.00e+00 6.710873e-04 7.737829e-06 4.157181e-05 -6.000000e+00 6.731723e-05 281.50 -2.00 20.00 -2.00 500.46 0.00e+00 4.308096e-01 5.592656e-03 2.501826e-02 -6.000000e+00 4.790838e-02 228.40 -2.00 3.19 -2.00 502.05 0.00e+00 5.758 0.002 489.00 513.00 1 5.0848e+00 4.2805e-04 6.6923e-03 -6.0000e+00 3.6680e-03 6.9418e-03 1.1061e-04 6.8736e-04 -6.0000e+00 9.5791e-04 6.2044e-03 1.0953e-03 2.7839e-05 3.2918e-05 -6.0000e+00 2.4550e-04 4.9944e-03 2.1280e-05 10 0 0 10 0 0 99.94 16.93 1.46 0.00499 0.01259 134 32 1 4 0 363.175 21.58 14.99 16.93 -411 -255 -180 134 164 341 499 454 480 371 182 138 -4 -101 -207 -220 -122 13 210 141 164 235 180 153 333 266 11 5 64 -209 -367 -240 -268 -62 57 -74 -176 -43 -120 -208 -199 -60 86 181 269 238 200 18 -45 -117 -386 -489 -477 -527 -218 -128 55 47 39 160 133 218 268 246 260 154 39 -108 -108 -168 -314 -175 -163 -125 -93 -116 -317 -367 -279 -319 -340 -326 -253 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