File name: Pandora101s1_Izana_20200821_L2Fit_fout2c15d20200721p1-8.txt File generation date: 20240504T142137.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v6d20170928.txt Instrument calibration file used: Pandora101s1_CF_v15d20200721.txt Level 1 file used: Pandora101s1_Izana_20200821_L1_smca1c15d20200721p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20200821 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 11 for vp 20200721 First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.0057 305.1465 305.2873 305.4282 305.5690 305.7098 305.8506 305.9914 306.1321 306.2729 306.4136 306.5544 306.6951 306.8358 306.9765 307.1172 307.2579 307.3986 307.5392 307.6799 307.8205 307.9611 308.1017 308.2423 308.3829 308.5235 308.6641 308.8046 308.9452 309.0857 309.2262 309.3667 309.5072 309.6477 309.7882 309.9286 310.0691 310.2095 310.3500 310.4904 310.6308 310.7712 310.9116 311.0519 311.1923 311.3326 311.4730 311.6133 311.7536 311.8939 312.0342 312.1745 312.3147 312.4550 312.5952 312.7355 312.8757 313.0159 313.1561 313.2963 313.4365 313.5766 313.7168 313.8569 313.9970 314.1371 314.2773 314.4173 314.5574 314.6975 314.8376 314.9776 315.1176 315.2577 315.3977 315.5377 315.6777 315.8176 315.9576 316.0976 316.2375 316.3774 316.5173 316.6573 316.7972 316.9370 317.0769 317.2168 317.3566 317.4965 317.6363 317.7761 317.9159 318.0557 318.1955 318.3352 318.4750 318.6147 318.7545 318.8942 319.0339 319.1736 319.3133 319.4529 319.5926 319.7323 319.8719 320.0115 320.1511 320.2907 320.4303 320.5699 320.7095 320.8490 320.9886 321.1281 321.2676 321.4072 321.5466 321.6861 321.8256 321.9651 322.1045 322.2440 322.3834 322.5228 322.6622 322.8016 322.9410 323.0803 323.2197 323.3591 323.4984 323.6377 323.7770 323.9163 324.0556 324.1949 324.3341 324.4734 324.6126 324.7519 324.8911 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200821T070746.0Z 7538.297061 44 1 48.06 2 84.67 79.31 114.47 69.74 0.00 1 0.00 1 0 25 5.327e-01 1.892e-02 2.612e-01 6.615e-03 9.311622e-01 3.719172e-03 9.482096e-03 -6.000000e+00 2.989918e-01 227.48 -2.00 3.19 -2.00 321.94 0.00e+00 3.788557e-03 2.085023e-03 3.553516e-03 -6.000000e+00 1.345804e-02 281.83 -2.00 20.00 -2.00 321.48 0.00e+00 9.410 0.009 302.00 328.00 3 1.7053e+00 1.4109e-02 8.6265e-02 -6.0000e+00 7.4289e-01 7.6610e-01 2.0479e-02 5.1370e-02 -6.0000e+00 8.0598e-01 -1.0127e+00 2.0428e-02 2.8657e-02 -6.0000e+00 4.7954e-01 4.0524e-01 9.3596e-03 9.3653e-03 -6.0000e+00 2.0877e-01 2.9684e-05 -1.2033e-03 1.6461e-04 1.3370e-04 -6.0000e+00 1.3736e-02 1.5777e-03 0.0000e+00 12 9 8 11 8 0 74.15 16.91 0.41 0.00158 -0.00746 48 11 1 5 0 1001.192 21.58 15.00 16.91 900000 -200015 -18121 -147678 900000 -82690 -193217 -85576 -45052 -230250 -187998 -194709 -114194 -76270 -71144 -81594 -55204 -54285 -91891 40812 -35004 900000 -5140 -72652 -38095 -42502 73218 -58911 -54271 -97080 -20913 -55396 106760 25882 61286 -18464 27814 -1789 123665 16136 26997 30390 13006 61553 -3934 -5378 38658 26582 14110 49774 21093 23427 24284 49430 28593 23643 24640 33593 16336 18495 36587 8898 -3353 12748 15684 16898 16415 12508 16059 -163 9930 13273 4852 6400 11224 3538 -182 -3357 -3693 2795 1376 1567 -906 -970 -4497 2627 778 3194 2078 -1631 105 -461 -2364 796 -4829 -900 -2084 -654 -1352 -279 -1557 -2027 -3757 -4547 -2664 -3713 -3269 -2569 -854 -817 -427 112 1213 162 -1361 493 -591 710 52 613 604 1866 1489 1029 1542 1273 1471 1764 509 322 -33 499 -4 -275 145 -340 110 354 136 154 -596 -520 -1261 900000 -4690 -117 -2164 900000 -533 -3398 -552 -290 -7288 -3967 -4680 -1540 -939 -1084 -1722 -1036 -1114 -2963 395 -657 900000 -73 -1959 -782 -947 567 -1485 -1365 -3528 -472 -2046 1033 634 1027 -631 610 -60 1435 605 1044 1229 656 2143 -238 -331 1720 1262 811 2375 1360 1689 1936 3361 2581 2342 2499 3111 1714 1789 2895 991 -485 1846 2491 2714 2627 2163 2928 -37 2332 3195 1270 1547 2540 759 -37 -704 -872 757 422 567 -384 -443 -2250 1301 413 1716 1134 -899 53 -221 -1115 375 -2735 -588 -1520 -556 -1332 -287 -1562 -1834 -3010 -3726 -2093 -3165 -2914 -2443 -884 -980 -595 162 1827 248 -2048 699 -840 1038 82 997 975 2811 2124 1432 2232 1797 1993 2412 751 568 -68 1037 -9 -663 375 -890 294 954 368 405 -1560 -1245 -2823 SS 20200821T072007.3Z 7538.305640 48 1 48.56 2 81.99 80.73 112.04 71.56 0.00 1 0.00 1 0 25 5.267e-01 8.970e-03 4.479e-02 1.289e-03 7.246644e-01 6.766703e-04 7.493719e-03 -6.000000e+00 2.953699e-01 227.48 -2.00 3.19 -2.00 320.92 0.00e+00 1.039658e-03 2.987539e-04 1.756870e-03 -6.000000e+00 1.293581e-02 281.83 -2.00 20.00 -2.00 320.38 0.00e+00 6.731 0.003 302.00 328.00 3 1.2040e+00 2.1762e-03 6.2015e-02 -6.0000e+00 7.3431e-01 7.9522e-02 2.9830e-03 3.6442e-02 -6.0000e+00 7.9619e-01 -1.2567e-01 3.0863e-03 1.9278e-02 -6.0000e+00 4.7405e-01 4.6067e-02 1.4999e-03 5.9105e-03 -6.0000e+00 2.0443e-01 4.5538e-04 -2.4080e-04 3.2379e-05 6.7622e-05 -6.0000e+00 1.3212e-02 1.1013e-03 0.0000e+00 11 8 0 10 0 0 0.95 16.91 0.17 0.00110 -0.00071 275 65 1 5 0 176.563 21.58 15.00 16.91 -163939 -183469 -126064 -172158 -142220 -183776 -185056 -169040 -156192 -150315 -156948 -142772 -141355 -91889 -88264 -64714 -61323 -40580 -53278 -32420 -42343 -34590 -29017 -41555 -27045 -31953 -18736 -37091 -29159 -38249 -14712 -16582 -424 -7620 -1007 -12856 -5562 -6281 -1955 4887 1462 5609 3851 5067 681 4963 1587 5177 1719 4552 3098 4907 5282 6278 6420 4881 5283 4348 3090 2143 3444 2244 4411 4311 3963 2828 1751 539 1091 1828 1384 2047 279 198 -145 -648 -2368 -2276 -2982 -1447 -1875 -1073 -1758 -1607 -1103 -376 145 296 773 477 713 -60 -401 -949 -739 -784 -358 194 244 84 -380 -933 -1043 -676 -1055 -1134 -1132 -789 -539 287 550 588 558 435 64 -50 -37 320 22 40 -35 140 588 380 595 189 48 619 329 316 291 25 -66 -170 -422 -223 -73 276 99 -44 -236 -146 -282 -1154 -1960 -856 -1904 -1072 -1986 -2163 -1954 -1865 -1908 -2268 -1956 -2398 -1259 -1520 -1106 -1187 -719 -1192 -632 -958 -726 -591 -1065 -673 -908 -487 -1142 -803 -1197 -431 -561 -15 -324 -40 -543 -232 -311 -116 336 122 492 367 495 70 502 171 558 203 559 394 701 841 1092 1210 986 1114 940 659 445 707 503 1108 1254 1282 930 567 180 364 706 611 959 134 91 -62 -247 -834 -790 -1136 -649 -1010 -620 -1154 -1128 -818 -297 121 238 625 405 567 -45 -285 -681 -585 -676 -360 211 300 108 -466 -1038 -1096 -679 -1139 -1232 -1288 -953 -707 396 858 947 923 707 100 -78 -56 508 35 67 -59 228 905 601 905 280 68 870 519 545 532 49 -131 -358 -913 -512 -172 659 240 -103 -524 -317 -575 SS 20200821T073515.3Z 7538.316149 53 1 48.55 2 78.70 82.44 109.03 73.69 0.00 1 0.00 1 0 25 1.735e-01 6.096e-03 9.321e-03 4.772e-04 5.597254e-01 2.418512e-04 5.908901e-03 -6.000000e+00 9.731232e-02 227.48 -2.00 3.19 -2.00 319.77 0.00e+00 1.302546e-03 7.460764e-05 3.998556e-04 -6.000000e+00 4.261648e-03 281.83 -2.00 20.00 -2.00 319.15 0.00e+00 4.936 0.001 302.00 328.00 3 8.6478e-01 6.9276e-04 4.5811e-02 -6.0000e+00 2.4193e-01 1.8612e-02 8.3848e-04 2.6510e-02 -6.0000e+00 2.6231e-01 -2.4118e-02 7.3855e-04 1.3475e-02 -6.0000e+00 1.5618e-01 2.2240e-03 3.8753e-04 4.2811e-03 -6.0000e+00 6.7352e-02 2.7352e-03 -1.8823e-04 1.2353e-05 4.1111e-05 -6.0000e+00 4.3526e-03 8.6601e-04 0.0000e+00 10 0 0 10 0 0 38.95 16.91 0.20 0.00087 -0.00055 799 189 1 5 0 60.684 21.58 15.01 16.91 -63924 -60537 -53034 -51858 -62852 -59508 -70429 -53838 -51313 -41241 -50138 -40632 -40771 -24626 -21099 -11698 -12713 -8896 -7673 -6355 -4121 -8638 -5099 -8288 -3538 -7187 -3473 -7817 -6866 -9883 -4602 -3561 561 -576 -4152 -4811 -5047 -2245 -853 1766 277 1287 462 800 920 1235 762 628 -230 276 1180 1609 2241 1585 1886 1394 1787 876 742 163 783 1246 2066 2530 1986 1123 251 -166 249 865 778 800 100 313 -201 -448 -1482 -1998 -1778 -1308 -1241 -1258 -1741 -1619 -1235 -660 -18 177 708 743 767 342 36 -329 -204 -62 12 665 351 121 -321 -579 -673 -135 -680 -906 -854 -548 -403 376 448 399 454 280 52 54 209 170 172 -156 -314 -138 268 197 419 341 37 634 363 357 230 102 -128 -88 -337 -229 -147 222 188 -83 -202 -151 -253 -839 -935 -842 -825 -1018 -872 -1213 -902 -977 -791 -1097 -853 -1030 -673 -699 -429 -487 -360 -335 -291 -194 -426 -247 -452 -203 -460 -222 -511 -425 -637 -318 -291 51 -60 -439 -483 -537 -271 -125 285 52 262 100 179 207 282 178 149 -57 71 325 495 696 539 683 530 703 352 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