File name: Pandora101s1_Izana_20201004_L2Fit_fout2c15d20200721p1-8.txt File generation date: 20240504T140631.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v6d20170928.txt Instrument calibration file used: Pandora101s1_CF_v15d20200721.txt Level 1 file used: Pandora101s1_Izana_20201004_L1_smca1c15d20200721p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20201004 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 11 for vp 20200721 First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.0057 305.1465 305.2873 305.4282 305.5690 305.7098 305.8506 305.9914 306.1321 306.2729 306.4136 306.5544 306.6951 306.8358 306.9765 307.1172 307.2579 307.3986 307.5392 307.6799 307.8205 307.9611 308.1017 308.2423 308.3829 308.5235 308.6641 308.8046 308.9452 309.0857 309.2262 309.3667 309.5072 309.6477 309.7882 309.9286 310.0691 310.2095 310.3500 310.4904 310.6308 310.7712 310.9116 311.0519 311.1923 311.3326 311.4730 311.6133 311.7536 311.8939 312.0342 312.1745 312.3147 312.4550 312.5952 312.7355 312.8757 313.0159 313.1561 313.2963 313.4365 313.5766 313.7168 313.8569 313.9970 314.1371 314.2773 314.4173 314.5574 314.6975 314.8376 314.9776 315.1176 315.2577 315.3977 315.5377 315.6777 315.8176 315.9576 316.0976 316.2375 316.3774 316.5173 316.6573 316.7972 316.9370 317.0769 317.2168 317.3566 317.4965 317.6363 317.7761 317.9159 318.0557 318.1955 318.3352 318.4750 318.6147 318.7545 318.8942 319.0339 319.1736 319.3133 319.4529 319.5926 319.7323 319.8719 320.0115 320.1511 320.2907 320.4303 320.5699 320.7095 320.8490 320.9886 321.1281 321.2676 321.4072 321.5466 321.6861 321.8256 321.9651 322.1045 322.2440 322.3834 322.5228 322.6622 322.8016 322.9410 323.0803 323.2197 323.3591 323.4984 323.6377 323.7770 323.9163 324.0556 324.1949 324.3341 324.4734 324.6126 324.7519 324.8911 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20201004T071648.6Z 7582.303341 230 1 49.30 2 87.31 96.65 67.68 270.09 0.00 1 0.00 1 0 17 6.472e-01 6.874e-02 3.906e-01 4.239e-02 1.014115e+00 2.441157e-02 9.881276e-03 -6.000000e+00 3.694718e-01 226.06 -2.00 3.19 -2.00 321.84 0.00e+00 -2.444771e-02 8.083358e-03 1.236232e-02 -6.000000e+00 1.743058e-02 279.43 -2.00 20.00 -2.00 321.22 0.00e+00 14.448 0.031 302.00 328.00 3 1.8306e-01 7.8917e-02 1.4796e-01 -6.0000e+00 9.1601e-01 2.3806e+00 9.4189e-02 1.3353e-01 -6.0000e+00 9.9883e-01 -2.3095e+00 5.6121e-02 3.5649e-02 -6.0000e+00 5.9496e-01 7.3713e-01 2.9825e-02 1.9108e-02 -6.0000e+00 2.6088e-01 2.4545e-06 5.7448e-03 1.0754e-03 9.5829e-05 -6.0000e+00 1.7490e-02 1.8259e-03 0.0000e+00 12 9 9 12 1 1 52.80 16.70 1.24 0.00183 0.04499 16 4 1 5 0 2899.949 21.38 15.00 16.70 900000 -14470 900000 89959 900000 66197 21060 -57591 195122 20946 12437 11902 79830 46416 -3588 900000 73817 98552 45227 900000 353977 900000 166098 120550 101926 1330 900000 -20301 -4547 -60849 900000 20455 900000 53216 78569 15918 71821 135495 900000 900000 62431 129314 66191 100601 -29088 -36054 281340 71568 21290 900000 66207 -6861 61427 -6396 900000 37894 52 192418 56001 76265 900000 -13569 -38480 4613 14156 4865 -17441 31547 10754 -26748 -5769 -29547 11143 8605 43171 120551 -40465 -19008 -53252 13652 -22407 26194 34304 -15598 12473 25614 30949 -3678 32589 -10625 16245 24392 191 32702 -17226 7195 20115 15212 7672 14434 -1312 -5083 -28429 -12699 -10018 -6041 -2471 3456 7909 166 12455 -760 7675 -3254 -3105 288 6083 6979 -9564 3561 2278 7558 235 6100 -7452 -7660 544 4473 -6792 1980 3607 -1267 -1659 -576 -2847 -1533 612 2959 898 -1780 -796 1963 1519 900000 -2933 900000 4635 900000 3225 1592 -11079 8043 2159 1491 1427 5086 4349 -542 900000 5809 5909 4407 900000 14592 900000 6847 4969 5730 209 900000 -2967 -460 -10033 900000 1840 900000 3789 3828 1312 3499 5585 900000 900000 6317 6785 6201 6032 -5668 -6891 11598 4291 2154 900000 4962 -1183 5755 -1270 900000 5396 11 7932 5876 6288 900000 -2390 -9662 847 2493 912 -4052 4729 2217 -9222 -1751 -11627 2798 1999 6763 7454 -10463 -4060 -18160 2865 -7977 6675 8999 -7131 4534 8543 10090 -1709 10259 -4858 5236 6856 68 9976 -9167 3559 10252 9463 5721 10169 -1008 -3562 -22160 -8328 -6908 -4233 -1760 2513 6224 166 12836 -991 9606 -4549 -4200 365 7340 8761 -14982 5031 3150 9291 297 7133 -9746 -9788 622 5263 -10690 3399 6961 -2831 -3693 -1383 -7629 -4307 1718 8224 2539 -4917 -2003 4396 3559 SS 20201004T072845.3Z 7582.311635 234 1 48.53 2 84.70 98.09 70.23 271.49 0.00 1 0.00 1 0 25 7.379e-01 1.481e-02 1.315e-01 3.258e-03 9.527087e-01 1.805121e-03 9.606319e-03 -6.000000e+00 4.115654e-01 226.06 -2.00 3.19 -2.00 321.96 0.00e+00 5.672782e-03 1.008924e-03 1.582168e-03 -6.000000e+00 1.794197e-02 279.43 -2.00 20.00 -2.00 321.53 0.00e+00 9.462 0.009 302.00 328.00 3 4.0130e-01 6.8094e-03 8.5959e-02 -6.0000e+00 1.0207e+00 5.7582e-01 1.0447e-02 5.0141e-02 -6.0000e+00 1.1083e+00 -8.1874e-01 1.1232e-02 2.8562e-02 -6.0000e+00 6.5966e-01 3.3210e-01 5.1003e-03 1.1669e-02 -6.0000e+00 2.8469e-01 1.1112e-04 -9.2955e-04 7.9298e-05 1.4508e-04 -6.0000e+00 1.8503e-02 1.3307e-03 0.0000e+00 12 8 8 10 0 0 -1.32 16.70 0.26 0.00133 -0.00565 205 48 1 5 0 236.709 21.38 15.00 16.70 -201860 -236780 -211950 -231048 -200460 -237158 -164537 -217400 -151830 -240447 -205789 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921 1219 1359 2014 1872 2107 1731 2045 1179 970 1123 861 1100 1802 2068 1617 1825 1237 2163 1904 2471 2456 2252 1282 1690 528 -184 -24 -861 510 -549 604 405 347 -333 655 430 771 557 673 -3 -56 -601 -1343 -1825 -1781 -1639 -1474 -603 -469 -1174 -1593 -1847 -1592 -1969 -2159 -1818 -1787 -1684 -249 -116 398 826 81 -937 -232 -106 100 -596 1000 526 1724 1949 2179 1182 727 1239 1366 336 793 1497 707 529 -230 -435 -661 35 645 561 160 -776 -862 -2924 SS 20201004T074039.3Z 7582.319899 238 1 48.59 2 82.11 99.55 72.77 272.86 0.00 1 0.00 1 0 17 5.858e-01 9.564e-03 2.965e-02 8.876e-04 7.514543e-01 4.652494e-04 7.799681e-03 -6.000000e+00 3.267299e-01 226.06 -2.00 3.19 -2.00 321.03 0.00e+00 2.603926e-03 2.107193e-04 1.790656e-03 -6.000000e+00 1.424180e-02 279.43 -2.00 20.00 -2.00 320.53 0.00e+00 6.825 0.003 302.00 328.00 3 3.5996e-01 1.5083e-03 6.3121e-02 -6.0000e+00 8.1029e-01 1.0709e-01 2.0892e-03 3.7342e-02 -6.0000e+00 8.7982e-01 -1.6761e-01 2.2177e-03 2.0691e-02 -6.0000e+00 5.2367e-01 6.3220e-02 1.0731e-03 7.1453e-03 -6.0000e+00 2.2603e-01 9.6612e-04 -3.1485e-04 2.2296e-05 8.4501e-05 -6.0000e+00 1.4687e-02 5.8739e-04 0.0000e+00 12 8 8 10 0 0 2.85 16.71 0.21 0.00059 -0.00178 663 157 1 5 0 73.165 21.38 15.01 16.71 -207368 -193388 -185951 -174610 -192246 -204470 -188533 -172193 -164514 -152384 -154755 -156736 -141589 -112685 -96876 -79384 -67292 -57286 -52372 -43636 -39763 -48812 -43065 -37735 -30511 -37202 -29169 -38479 -40155 -39681 -26569 -19695 -10968 -7980 -7886 -12405 -12534 -6488 -99 5030 4760 5711 4254 5560 5233 4047 3710 4268 2657 4523 6007 6753 6813 7052 6888 5772 5026 4753 3377 2382 3023 2608 4610 5495 5356 3919 2464 1659 1719 2259 2342 2136 1388 1073 39 -819 -2239 -2931 -2579 -1653 -1696 -1494 -1649 -1695 -1449 -636 -1 103 581 640 514 26 -784 -1324 -1243 -730 -467 269 275 95 -508 -806 -1027 -859 -1140 -1274 -974 -704 -408 223 519 589 628 387 60 -30 41 223 40 -34 -167 102 551 525 571 418 57 589 334 361 278 156 9 -143 -399 -276 -187 253 230 -101 -151 -217 -314 -1939 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