File name: Pandora101s1_Izana_20201021_L2Fit_fout2c15d20200721p1-8.txt File generation date: 20240504T135330.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v6d20170928.txt Instrument calibration file used: Pandora101s1_CF_v15d20200721.txt Level 1 file used: Pandora101s1_Izana_20201021_L1_smca1c15d20200721p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20201021 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 11 for vp 20200721 First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.0057 305.1465 305.2873 305.4282 305.5690 305.7098 305.8506 305.9914 306.1321 306.2729 306.4136 306.5544 306.6951 306.8358 306.9765 307.1172 307.2579 307.3986 307.5392 307.6799 307.8205 307.9611 308.1017 308.2423 308.3829 308.5235 308.6641 308.8046 308.9452 309.0857 309.2262 309.3667 309.5072 309.6477 309.7882 309.9286 310.0691 310.2095 310.3500 310.4904 310.6308 310.7712 310.9116 311.0519 311.1923 311.3326 311.4730 311.6133 311.7536 311.8939 312.0342 312.1745 312.3147 312.4550 312.5952 312.7355 312.8757 313.0159 313.1561 313.2963 313.4365 313.5766 313.7168 313.8569 313.9970 314.1371 314.2773 314.4173 314.5574 314.6975 314.8376 314.9776 315.1176 315.2577 315.3977 315.5377 315.6777 315.8176 315.9576 316.0976 316.2375 316.3774 316.5173 316.6573 316.7972 316.9370 317.0769 317.2168 317.3566 317.4965 317.6363 317.7761 317.9159 318.0557 318.1955 318.3352 318.4750 318.6147 318.7545 318.8942 319.0339 319.1736 319.3133 319.4529 319.5926 319.7323 319.8719 320.0115 320.1511 320.2907 320.4303 320.5699 320.7095 320.8490 320.9886 321.1281 321.2676 321.4072 321.5466 321.6861 321.8256 321.9651 322.1045 322.2440 322.3834 322.5228 322.6622 322.8016 322.9410 323.0803 323.2197 323.3591 323.4984 323.6377 323.7770 323.9163 324.0556 324.1949 324.3341 324.4734 324.6126 324.7519 324.8911 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20201021T074117.3Z 7599.320339 5 1 48.55 2 84.26 105.66 145.99 92.28 0.00 1 0.00 1 0 25 7.171e-01 1.484e-02 1.136e-01 2.689e-03 8.754840e-01 1.466983e-03 8.865732e-03 -6.000000e+00 3.988154e-01 225.27 -2.00 3.19 -2.00 321.79 0.00e+00 4.280009e-03 7.877265e-04 2.543093e-03 -6.000000e+00 1.733435e-02 278.04 -2.00 20.00 -2.00 321.36 0.00e+00 8.899 0.007 302.00 328.00 3 6.4459e-01 5.3301e-03 8.0194e-02 -6.0000e+00 9.8776e-01 3.9125e-01 8.0142e-03 4.5793e-02 -6.0000e+00 1.0733e+00 -5.8418e-01 8.6700e-03 2.6735e-02 -6.0000e+00 6.3873e-01 2.3945e-01 3.9957e-03 9.8109e-03 -6.0000e+00 2.7584e-01 1.4591e-04 -8.1741e-04 6.7716e-05 1.2944e-04 -6.0000e+00 1.7978e-02 9.4403e-06 0.0000e+00 12 8 8 10 0 0 76.24 16.70 0.26 0.00001 -0.00613 222 52 1 5 0 218.687 21.38 15.00 16.70 -189366 -247502 -208894 -207732 -186644 -215407 -233736 -130730 -252217 -184772 -248464 -178928 -217215 -76233 -156079 -101310 -104412 -78923 -87719 -42504 -37927 -86159 -36470 -84269 -31024 -96274 20932 -86275 -38112 -87814 -14419 -45405 2377 -6085 -15552 -27566 -18509 1600 -5197 38294 1675 26168 2726 24459 -1175 21628 4584 16290 7124 28917 15208 13965 20848 16047 23243 13147 21373 13031 19107 7275 11907 5299 11631 11532 12761 9495 8834 7718 6415 6808 6825 10721 5566 6540 1791 2289 -3612 -1270 -5063 1401 -1418 548 -290 -917 -210 -733 1228 -183 1531 455 821 -805 -1025 -2629 -2443 -2392 -1865 -451 -685 -431 -933 -936 -2498 -2024 -2866 -1658 -2227 -1126 -1264 -313 -53 394 655 184 -41 -724 346 80 141 -18 571 545 1340 1153 1133 785 916 539 459 611 584 574 -161 -61 -353 -167 2 391 76 -119 -419 -214 -1001 -1174 -3422 -2191 -2179 -1566 -2003 -2675 -651 -4329 -1938 -4679 -2018 -4194 -540 -2977 -1567 -1792 -1304 -1589 -568 -497 -1785 -459 -1856 -439 -2525 192 -2262 -600 -2395 -231 -1274 50 -161 -449 -839 -534 44 -187 1095 73 979 137 1026 -64 959 249 827 426 1510 1022 1095 1715 1530 2238 1473 2298 1534 2041 834 1294 663 1580 1847 2094 1650 1533 1407 1295 1601 1828 2942 1616 1778 463 521 -796 -275 -1271 403 -510 228 -139 -440 -106 -397 688 -108 896 262 444 -414 -552 -1363 -1428 -1668 -1542 -433 -703 -464 -971 -876 -2235 -1697 -2573 -1580 -2242 -1117 -1386 -392 -76 591 1027 289 -62 -1062 497 120 224 -30 945 855 1974 1654 1690 1142 1278 762 693 1089 1115 1204 -365 -139 -868 -439 4 1059 207 -316 -1041 -487 -2284 SS 20201021T075356.6Z 7599.329128 9 1 41.27 2 81.59 107.26 143.36 93.55 0.00 1 0.00 1 0 17 5.102e-01 9.209e-03 1.477e-01 3.128e-03 6.885939e-01 1.636531e-03 7.115190e-03 -6.000000e+00 2.837562e-01 225.27 -2.00 3.19 -2.00 320.97 0.00e+00 1.863758e-03 7.144911e-04 1.101750e-03 -6.000000e+00 1.233228e-02 278.04 -2.00 20.00 -2.00 320.48 0.00e+00 6.454 0.003 302.00 328.00 3 2.8150e+00 5.2206e-03 5.8763e-02 -6.0000e+00 7.0279e-01 5.2121e-02 7.1457e-03 3.3644e-02 -6.0000e+00 7.6367e-01 -8.0302e-02 7.5526e-03 1.8408e-02 -6.0000e+00 4.5444e-01 2.6972e-02 3.6840e-03 6.2914e-03 -6.0000e+00 1.9627e-01 1.1650e-04 -3.5562e-04 8.1339e-05 6.8981e-05 -6.0000e+00 1.2790e-02 -4.7960e-04 0.0000e+00 12 9 1 12 1 1 99.99 16.71 0.12 -0.00048 -0.00315 98 28 1 5 0 415.234 21.38 15.00 16.71 -171229 -203006 -117697 -191237 240788 -199081 -118554 -50999 -89456 -151063 -132544 -145316 -103106 -60993 -86394 -79274 -80765 -38383 -58866 15308 -31056 -18404 -43324 -18222 -10350 -25383 -26 -33992 -31733 -35838 -6478 -16151 1375 -6459 -4243 -19016 3970 -5646 14985 11738 8734 6120 336 5578 -2930 1438 5336 2426 1859 9850 -1600 4965 6612 8010 5558 5708 3682 4272 3241 1188 2345 1530 1562 3748 4430 2258 1596 1311 1331 938 1663 2002 1125 614 1336 -1588 -1315 -3304 -3555 -1217 -1121 -611 -1670 -1550 -1748 -174 -433 130 188 1191 -41 638 -1318 -570 -1971 -1035 -135 215 317 274 -149 -560 -1137 -1043 -423 -993 -969 -777 -146 382 832 688 803 352 -168 -98 -302 -138 -155 14 -474 313 755 606 82 46 182 715 202 132 299 95 -147 55 -477 -225 69 388 254 -223 -166 28 -576 -1471 -2878 -871 -2803 735 -2794 -839 -221 -639 -2111 -1667 -2208 -1310 -686 -1566 -1645 -1952 -710 -1426 205 -656 -350 -1060 -390 -229 -692 -1 -1023 -923 -1102 -178 -594 51 -290 -185 -912 163 -288 775 762 671 530 32 530 -307 147 542 262 213 1110 -220 729 1048 1376 1059 1123 774 906 677 245 479 340 390 1055 1348 704 486 406 444 360 710 910 522 274 553 -605 -461 -1159 -1354 -530 -573 -350 -1088 -1062 -1273 -132 -343 107 156 953 -32 462 -921 -394 -1495 -891 -130 236 382 344 -179 -628 -1153 -1027 -437 -1092 -1115 -936 -187 532 1269 1117 1334 575 -266 -149 -455 -213 -249 23 -805 514 1193 932 124 68 256 1009 310 225 554 186 -300 116 -1066 -524 166 928 613 -528 -378 60 -1200 SS 20201021T081148.3Z 7599.341531 18 1 48.52 2 77.87 109.61 139.65 95.25 0.00 1 0.00 1 0 25 1.301e-01 5.669e-03 1.524e-02 8.682e-04 5.203529e-01 4.364883e-04 5.548851e-03 -6.000000e+00 7.236294e-02 225.27 -2.00 3.19 -2.00 319.66 0.00e+00 9.595288e-04 1.270754e-04 2.930542e-04 -6.000000e+00 3.144671e-03 278.04 -2.00 20.00 -2.00 319.09 0.00e+00 4.624 0.001 302.00 328.00 3 2.2778e+00 1.2347e-03 4.2571e-02 -6.0000e+00 1.7922e-01 9.5858e-04 1.4813e-03 2.4457e-02 -6.0000e+00 1.9474e-01 4.7929e-03 1.2929e-03 1.2498e-02 -6.0000e+00 1.1589e-01 -9.8921e-03 6.8201e-04 3.9188e-03 -6.0000e+00 5.0056e-02 8.8400e-04 -2.1772e-04 2.2951e-05 3.7625e-05 -6.0000e+00 3.2616e-03 -9.9995e-04 0.0000e+00 10 0 0 10 0 0 99.96 16.74 0.16 -0.00100 -0.00264 345 81 1 5 0 140.633 21.38 15.01 16.74 -56061 -40007 -37649 -32976 -45760 -52729 -45485 -46256 -29194 -40603 -22582 -42509 -20599 -23901 -11749 -15390 -6756 -7628 -4456 -3726 -3917 -2969 -7266 -2673 -4289 -2424 -4004 -2438 -8973 -4572 -4024 30 -521 571 -3509 -4786 -3439 -1703 991 420 1254 -238 964 -285 1086 6 836 312 285 69 1252 1151 1487 2001 1375 1498 894 1111 120 642 405 1696 1312 2833 1687 746 67 -476 112 611 457 442 135 -131 213 -640 -759 -2090 -1152 -1139 -1018 -954 -1671 -1792 -1289 -634 -191 243 539 899 531 734 -40 -35 -243 -6 85 710 396 204 -217 -696 -650 -461 -531 -971 -744 -629 -299 323 582 474 580 347 3 43 -40 157 -97 -18 -368 -156 35 356 337 292 -92 623 262 329 272 53 -68 -145 -266 -182 -44 122 241 -155 -129 -225 -175 -897 -661 -669 -567 -814 -938 -789 -928 -576 -909 -484 -1057 -488 -736 -399 -654 -297 -369 -227 -200 -222 -167 -432 -165 -296 -177 -308 -181 -675 -329 -322 3 -50 61 -384 -500 -374 -212 148 77 264 -55 233 -66 273 1 217 76 71 18 345 355 501 727 536 608 379 476 51 263 167 741 599 1435 933 408 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