File name: Pandora101s1_Izana_20201209_L2Fit_fwvt1c15d20200721p1-8.txt File generation date: 20240504T134038.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c15p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v6d20170928.txt Instrument calibration file used: Pandora101s1_CF_v15d20200721.txt Level 1 file used: Pandora101s1_Izana_20201209_L1_smca1c15d20200721p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20201209 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 11 for vp 20200721 First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0538 492.1747 492.2957 492.4166 492.5375 492.6584 492.7793 492.9002 493.0210 493.1419 493.2627 493.3835 493.5043 493.6250 493.7458 493.8665 493.9873 494.1080 494.2286 494.3493 494.4700 494.5906 494.7112 494.8318 494.9524 495.0730 495.1936 495.3141 495.4346 495.5551 495.6756 495.7961 495.9166 496.0370 496.1574 496.2778 496.3982 496.5186 496.6390 496.7593 496.8796 496.9999 497.1202 497.2405 497.3608 497.4810 497.6012 497.7215 497.8416 497.9618 498.0820 498.2021 498.3223 498.4424 498.5625 498.6826 498.8026 498.9227 499.0427 499.1627 499.2827 499.4027 499.5227 499.6426 499.7625 499.8824 500.0023 500.1222 500.2421 500.3619 500.4818 500.6016 500.7214 500.8412 500.9609 501.0807 501.2004 501.3201 501.4398 501.5595 501.6792 501.7988 501.9185 502.0381 502.1577 502.2773 502.3968 502.5164 502.6359 502.7554 502.8749 502.9944 503.1139 503.2333 503.3528 503.4722 503.5916 503.7110 503.8304 503.9497 504.0690 504.1884 504.3077 504.4269 504.5462 504.6655 504.7847 504.9039 505.0231 505.1423 505.2615 505.3806 505.4998 505.6189 505.7380 505.8571 505.9762 506.0952 506.2142 506.3333 506.4523 506.5712 506.6902 506.8092 506.9281 507.0470 507.1659 507.2848 507.4037 507.5225 507.6414 507.7602 507.8790 507.9978 508.1166 508.2353 508.3540 508.4728 508.5915 508.7102 508.8288 508.9475 509.0661 509.1847 509.3033 509.4219 509.5405 509.6590 509.7776 509.8961 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20201209T075244.3Z 7648.328290 209 1 48.52 2 89.66 116.40 26.56 166.13 0.00 1 0.00 1 0 22 5.227e-03 5.176e-03 2.254e-04 2.249e-04 2.382120e+03 1.309110e+01 1.253395e+02 -6.000000e+00 2.845776e+02 274.27 -2.00 20.00 -2.00 505.36 0.00e+00 1.334941e-03 6.097811e-06 7.532884e-05 -6.000000e+00 1.438309e-04 274.27 -2.00 20.00 -2.00 500.97 0.00e+00 1.068770e+00 4.329572e-03 2.470513e-02 -6.000000e+00 1.038710e-01 223.26 -2.00 3.19 -2.00 502.48 0.00e+00 20.436 0.088 489.00 513.00 1 3.1125e+00 3.3007e-04 2.4283e-02 -6.0000e+00 7.9377e-03 -3.0429e-02 8.4955e-05 1.4040e-03 -6.0000e+00 2.0739e-03 8.7418e-03 1.5663e-03 2.2536e-05 3.5797e-05 -6.0000e+00 5.3347e-04 3.7876e-03 -1.9462e-05 12 8 8 10 0 0 94.35 16.77 1.52 0.00379 0.01465 220 52 1 4 0 220.538 21.48 15.00 16.77 -1090 -820 -409 145 426 754 1018 978 1004 738 336 191 -70 -273 -437 -397 -221 65 388 408 343 429 417 445 585 539 284 133 -51 -734 -933 -752 -586 -131 213 132 17 -54 -203 -266 -176 -54 167 398 528 562 472 253 -67 -266 -752 -1046 -1167 -985 -544 -104 95 275 363 402 448 512 543 535 503 340 55 -226 -277 -423 -589 -536 -419 -286 -138 -266 -558 -702 -707 -751 -778 -684 -617 -511 -409 -393 -336 -309 -299 -246 -111 137 382 453 475 313 24 -327 -513 -936 -1092 -895 -645 -195 -28 -123 -291 -365 -404 -218 49 225 591 805 978 1033 990 950 773 506 395 288 257 354 414 316 444 390 347 350 302 -106 -302 -433 -510 -325 -68 50 265 348 388 325 372 345 226 40 -185 -559 -862 -875 -975 -745 -373 136 399 721 990 936 961 702 325 183 -66 -257 -410 -375 -212 62 379 404 333 418 408 438 578 535 281 130 -49 -709 -889 -719 -573 -129 215 131 17 -53 -203 -264 -176 -53 165 399 534 570 477 254 -66 -264 -730 -997 -1104 -941 -532 -102 96 278 368 407 444 510 544 537 501 344 55 -224 -272 -411 -570 -520 -411 -285 -139 -266 -551 -684 -684 -726 -756 -670 -610 -498 -403 -391 -336 -309 -300 -247 -113 137 388 462 481 313 24 -322 -496 -918 -1071 -870 -646 -197 -29 -125 -300 -372 -411 -223 49 231 616 846 1012 1077 1039 1000 810 525 405 299 267 369 424 326 459 402 358 362 310 -108 -312 -443 -524 -331 -70 53 279 370 416 351 396 370 242 42 -199 -592 -900 -913 SQ 20201209T075617.2Z 7648.330755 214 1 48.50 2 88.96 116.82 26.40 168.05 0.00 1 0.00 1 0 15 4.688e-03 4.648e-03 4.446e-04 4.437e-04 1.920958e+03 2.552373e+01 9.828937e+01 -6.000000e+00 2.552112e+02 274.27 -2.00 20.00 -2.00 505.36 0.00e+00 1.206243e-03 1.201541e-05 6.723535e-05 -6.000000e+00 1.289918e-04 274.27 -2.00 20.00 -2.00 500.91 0.00e+00 1.073028e+00 8.559776e-03 2.131339e-02 -6.000000e+00 9.315813e-02 223.26 -2.00 3.19 -2.00 502.44 0.00e+00 18.985 0.071 489.00 513.00 1 4.6136e+00 6.5289e-04 2.2090e-02 -6.0000e+00 7.1189e-03 -2.2538e-02 1.6831e-04 1.2655e-03 -6.0000e+00 1.8601e-03 2.2812e-03 1.6475e-03 4.4476e-05 3.0257e-05 -6.0000e+00 4.7839e-04 -6.0046e-03 3.4132e-05 12 8 8 10 0 0 90.37 16.78 1.35 -0.00600 0.00542 68 16 1 4 0 713.160 21.48 14.99 16.78 -1098 -754 -461 138 369 679 899 774 865 627 238 96 -107 -272 -397 -338 -237 38 293 392 314 336 343 447 534 509 191 62 -41 -599 -801 -631 -517 -93 156 173 22 86 -223 -276 -85 26 186 369 471 509 516 224 -27 -147 -685 -878 -1056 -898 -405 -65 210 162 335 340 398 526 574 496 514 290 34 -183 -295 -437 -604 -463 -394 -251 -144 -182 -380 -636 -613 -692 -631 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28.58 2 88.30 117.23 26.27 169.89 0.00 1 0.00 1 0 15 3.654e-03 3.630e-03 6.270e-04 6.264e-04 1.408526e+03 3.536988e+01 7.519380e+01 -6.000000e+00 1.989418e+02 274.27 -2.00 20.00 -2.00 505.32 0.00e+00 9.848326e-04 1.693942e-05 5.390235e-05 -6.000000e+00 1.005442e-04 274.27 -2.00 20.00 -2.00 500.75 0.00e+00 1.087660e+00 1.216374e-02 1.589603e-02 -6.000000e+00 7.259053e-02 223.26 -2.00 3.19 -2.00 502.30 0.00e+00 17.206 0.053 489.00 513.00 1 4.9263e+00 9.2846e-04 1.9588e-02 -6.0000e+00 5.5477e-03 9.6234e-05 2.4038e-04 1.1054e-03 -6.0000e+00 1.4487e-03 2.0246e-03 1.0352e-03 6.2644e-05 2.3766e-05 -6.0000e+00 3.7294e-04 -4.1114e-03 5.6296e-05 12 1 1 12 1 1 99.82 16.78 1.15 -0.00411 0.00307 22 9 1 4 0 1235.471 21.48 15.00 16.78 -771 -681 -446 -42 228 453 653 583 652 443 164 122 -120 -223 -373 -363 -115 56 279 334 250 466 180 314 605 324 146 52 -100 -465 -529 -543 -402 -29 232 100 -25 -30 -145 -314 -5 105 79 200 319 414 285 383 -60 -83 -558 -712 -838 -600 -229 -9 41 -162 374 308 305 458 373 450 376 339 -32 -112 -176 -172 -448 -289 -261 -296 -206 -125 -284 -481 -423 -502 -561 -425 -486 -403 -212 -265 -202 -218 -173 -92 -12 210 330 415 268 277 23 -231 -264 -622 -829 -551 -469 -81 -149 -19 -203 -296 -243 -155 19 109 440 526 669 708 587 585 546 305 271 287 186 266 253 210 131 245 208 174 82 -116 -235 -295 -335 -45 -69 -20 302 386 279 239 272 197 95 -35 -35 -494 -738 -731 -717 -644 -424 -40 223 452 646 583 651 439 161 121 -118 -216 -361 -354 -114 55 282 333 250 467 181 318 613 330 148 52 -101 -457 -511 -527 -399 -29 237 101 -25 -31 -147 -315 -5 106 81 202 324 423 289 384 -61 -82 -541 -692 -808 -584 -223 -9 41 -164 376 310 308 463 380 457 379 337 -31 -111 -174 -168 -436 -282 -257 -296 -203 -122 -280 -468 -408 -484 -544 -415 -479 -392 -208 -262 -201 -217 -172 -92 -12 209 333 420 270 275 23 -226 -259 -603 -803 -528 -463 -81 -152 -19 -205 -296 -241 -154 19 109 448 541 693 737 601 600 569 314 276 289 186 268 257 214 134 249 212 177 83 -116 -232 -296 -336 -44 -70 -20 309 399 291 252 281 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