File name: Pandora101s1_Izana_20210308_L2Fit_fout2c16d20210210p1-8.txt File generation date: 20240504T125758.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v7d20170928.txt Instrument calibration file used: Pandora101s1_CF_v16d20210210.txt Level 1 file used: Pandora101s1_Izana_20210308_L1_smca1c16d20210210p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20210308 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 11 for VP 20210210 First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.0133 305.1541 305.2949 305.4357 305.5766 305.7173 305.8581 305.9989 306.1397 306.2804 306.4211 306.5619 306.7026 306.8433 306.9840 307.1247 307.2653 307.4060 307.5466 307.6873 307.8279 307.9685 308.1091 308.2497 308.3903 308.5309 308.6714 308.8120 308.9525 309.0930 309.2335 309.3740 309.5145 309.6550 309.7954 309.9359 310.0763 310.2168 310.3572 310.4976 310.6380 310.7784 310.9187 311.0591 311.1994 311.3398 311.4801 311.6204 311.7607 311.9010 312.0413 312.1816 312.3218 312.4621 312.6023 312.7425 312.8827 313.0229 313.1631 313.3033 313.4435 313.5836 313.7238 313.8639 314.0040 314.1441 314.2842 314.4243 314.5644 314.7044 314.8445 314.9845 315.1246 315.2646 315.4046 315.5446 315.6845 315.8245 315.9645 316.1044 316.2443 316.3843 316.5242 316.6641 316.8040 316.9438 317.0837 317.2236 317.3634 317.5032 317.6430 317.7829 317.9226 318.0624 318.2022 318.3420 318.4817 318.6214 318.7612 318.9009 319.0406 319.1803 319.3200 319.4596 319.5993 319.7389 319.8785 320.0182 320.1578 320.2974 320.4370 320.5765 320.7161 320.8556 320.9952 321.1347 321.2742 321.4137 321.5532 321.6927 321.8322 321.9716 322.1111 322.2505 322.3899 322.5293 322.6687 322.8081 322.9475 323.0868 323.2262 323.3655 323.5048 323.6442 323.7835 323.9228 324.0620 324.2013 324.3406 324.4798 324.6190 324.7582 324.8975 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210308T124040.1Z 7737.528241 5 1 14.11 2 34.11 163.83 71.72 226.20 0.00 1 0.00 1 0 17 7.501e-03 6.140e-03 1.295e-04 1.007e-04 1.492044e-01 5.077443e-05 1.673639e-03 -6.000000e+00 4.157078e-03 225.23 -2.00 3.19 -2.00 314.17 0.00e+00 4.506390e-04 3.646013e-06 2.561767e-05 -6.000000e+00 1.777448e-04 273.46 -2.00 20.00 -2.00 313.78 0.00e+00 1.207 0.000 302.00 328.00 3 6.7616e-02 1.2883e-04 1.1423e-02 -6.0000e+00 1.0310e-02 3.9729e-03 1.4296e-04 6.8792e-03 -6.0000e+00 1.1225e-02 3.5811e-03 8.2101e-05 3.4042e-03 -6.0000e+00 6.6614e-03 -4.1168e-03 3.5934e-05 1.0168e-03 -6.0000e+00 2.8562e-03 1.7537e-01 2.4626e-04 2.6505e-06 1.2225e-05 -6.0000e+00 1.8820e-04 1.5095e-02 0.0000e+00 10 0 0 10 0 0 7.27 16.70 0.33 0.01510 0.01695 2692 636 1 5 0 5.227 21.38 15.00 16.70 -412 -405 -167 -1405 -2418 -2003 -816 463 1008 -75 -1344 -1451 -793 -220 232 86 -45 233 674 1177 920 488 912 845 452 343 314 164 -53 378 1002 1520 1644 287 -1573 -1702 -1511 -589 -200 22 -560 -622 -625 -662 12 -284 -328 -261 -600 -237 492 786 1158 933 797 841 838 550 552 508 707 1025 1265 1321 473 -240 -736 -781 -144 156 131 74 -120 111 6 -212 -739 -1336 -1121 -1163 -1281 -1515 -1874 -1590 -1109 -579 -271 12 448 522 335 52 -296 -170 -69 109 228 782 458 265 -94 -391 -405 62 -303 -609 -512 -439 -194 358 555 490 501 307 88 71 37 209 257 186 -33 48 292 336 647 606 257 764 434 450 201 29 -194 -141 -245 -170 -142 75 48 -207 -334 -491 -721 -172 -184 -77 -616 -997 -749 -309 193 436 -35 -608 -635 -370 -107 125 47 -25 132 389 694 557 292 539 519 293 217 198 103 -31 217 580 867 997 183 -948 -1023 -900 -377 -144 17 -470 -542 -557 -595 11 -252 -283 -227 -501 -192 405 687 1005 846 741 790 762 501 517 470 666 974 1236 1370 497 -243 -703 -698 -131 153 137 78 -127 120 6 -204 -667 -1167 -974 -1063 -1252 -1557 -1975 -1731 -1278 -687 -327 16 564 640 399 58 -313 -174 -73 119 261 939 569 329 -115 -459 -444 69 -356 -736 -643 -552 -252 469 760 681 670 395 107 82 44 246 311 236 -44 64 377 434 788 731 305 875 523 554 249 37 -247 -184 -324 -230 -198 107 67 -297 -465 -662 -983 SS 20210308T124055.1Z 7737.528415 5 2 14.12 2 34.09 163.94 71.76 226.24 0.00 1 0.00 1 0 17 7.487e-03 6.142e-03 1.295e-04 1.008e-04 1.487836e-01 5.072866e-05 1.669128e-03 -6.000000e+00 4.149812e-03 225.23 -2.00 3.19 -2.00 314.17 0.00e+00 4.527363e-04 3.652101e-06 2.518344e-05 -6.000000e+00 1.774342e-04 273.46 -2.00 20.00 -2.00 313.79 0.00e+00 1.207 0.000 302.00 328.00 3 6.7052e-02 1.2871e-04 1.1409e-02 -6.0000e+00 1.0292e-02 2.7830e-03 1.4284e-04 6.8604e-03 -6.0000e+00 1.1205e-02 4.2901e-03 8.2014e-05 3.3949e-03 -6.0000e+00 6.6498e-03 -4.3676e-03 3.5911e-05 1.0146e-03 -6.0000e+00 2.8512e-03 1.7569e-01 2.5355e-04 2.6551e-06 1.2093e-05 -6.0000e+00 1.8787e-04 1.5104e-02 0.0000e+00 10 0 0 10 0 0 3.11 16.70 0.33 0.01510 0.01701 2692 636 1 5 0 5.227 21.38 15.00 16.70 -387 -420 -174 -1383 -2429 -1964 -749 486 1042 -77 -1366 -1475 -811 -219 261 74 -74 236 665 1141 881 504 906 859 484 345 317 157 -41 358 1008 1510 1618 264 -1591 -1663 -1513 -579 -202 25 -578 -610 -606 -623 20 -298 -326 -261 -574 -245 467 775 1156 935 764 830 857 542 569 498 700 1041 1255 1333 482 -244 -756 -807 -123 163 120 100 -111 70 -10 -223 -765 -1357 -1154 -1194 -1273 -1481 -1896 -1594 -1125 -573 -293 0 455 520 330 64 -277 -152 -69 131 225 795 454 266 -100 -399 -383 76 -308 -569 -509 -438 -199 350 551 501 513 314 79 50 20 224 248 197 -26 59 302 334 634 581 252 755 423 431 187 30 -201 -127 -233 -161 -147 84 58 -212 -331 -484 -718 -162 -192 -80 -608 -1004 -736 -284 203 452 -35 -619 -647 -379 -106 141 41 -41 134 385 674 535 302 537 529 295 218 200 99 -24 206 585 863 983 169 -961 -1001 -904 -371 -146 20 -486 -533 -542 -562 18 -265 -282 -216 -480 -199 385 679 1005 849 712 781 781 495 534 462 661 992 1228 1385 507 -237 -688 -723 -113 161 125 105 -118 73 -10 -216 -692 -1188 -1005 -1095 -1247 -1525 -2002 -1739 -1299 -681 -354 0 574 639 393 73 -293 -156 -69 143 257 957 567 331 -122 -469 -420 85 -363 -689 -642 -552 -259 460 756 698 687 405 96 58 24 264 301 250 -35 79 391 433 774 703 299 867 490 532 232 38 -256 -166 -310 -218 -206 121 81 -305 -461 -655 -981 SS 20210308T124109.1Z 7737.528578 5 3 14.22 2 34.08 164.04 71.79 226.28 0.00 1 0.00 1 0 17 7.519e-03 6.160e-03 1.295e-04 1.007e-04 1.488774e-01 5.071706e-05 1.671040e-03 -6.000000e+00 4.167324e-03 225.23 -2.00 3.19 -2.00 314.17 0.00e+00 4.591712e-04 3.651778e-06 2.540654e-05 -6.000000e+00 1.781830e-04 273.46 -2.00 20.00 -2.00 313.79 0.00e+00 1.207 0.000 302.00 328.00 3 6.6659e-02 1.2868e-04 1.1412e-02 -6.0000e+00 1.0335e-02 2.8647e-03 1.4281e-04 6.8678e-03 -6.0000e+00 1.1252e-02 4.2157e-03 8.1995e-05 3.3983e-03 -6.0000e+00 6.6779e-03 -4.2389e-03 3.5905e-05 1.0168e-03 -6.0000e+00 2.8633e-03 1.7573e-01 2.4574e-04 2.6540e-06 1.2113e-05 -6.0000e+00 1.8866e-04 1.5108e-02 0.0000e+00 10 0 0 10 0 0 12.12 16.70 0.33 0.01511 0.01695 2692 636 1 5 0 5.227 21.38 15.00 16.70 -412 -336 -159 -1426 -2462 -1999 -815 455 1036 -55 -1357 -1461 -764 -193 265 85 -40 228 646 1177 913 487 905 841 438 298 324 135 -60 371 984 1497 1666 258 -1606 -1698 -1502 -576 -197 34 -553 -622 -581 -640 21 -278 -290 -270 -616 -271 485 761 1136 956 784 859 830 558 569 510 712 1038 1278 1329 471 -242 -765 -800 -153 178 127 81 -108 53 -8 -241 -768 -1365 -1168 -1185 -1263 -1491 -1883 -1580 -1120 -597 -289 -24 453 516 326 78 -285 -137 -57 105 247 797 466 264 -87 -401 -384 77 -316 -586 -512 -440 -185 362 566 521 529 328 69 44 4 203 234 173 -27 57 298 341 640 591 252 762 425 427 163 27 -196 -128 -240 -147 -135 74 50 -211 -336 -474 -713 -172 -153 -73 -627 -1018 -749 -309 190 449 -25 -615 -640 -356 -94 143 47 -23 129 374 695 554 291 536 517 267 189 205 85 -35 214 571 855 1012 165 -970 -1022 -896 -370 -142 27 -464 -544 -519 -577 18 -247 -251 -223 -515 -219 400 667 988 868 731 808 757 509 534 473 672 988 1251 1381 496 -234 -696 -717 -139 175 133 85 -115 54 -8 -233 -695 -1195 -1018 -1086 -1237 -1535 -1988 -1724 -1293 -710 -350 -30 571 634 389 88 -302 -141 -57 115 283 959 581 329 -107 -472 -423 86 -372 -710 -644 -554 -241 475 778 726 708 423 84 51 5 239 284 220 -36 75 386 442 781 716 300 875 492 526 202 34 -250 -167 -319 -200 -189 105 70 -303 -469 -641 -974 SS 20210308T124123.1Z 7737.528739 5 4 14.13 2 34.07 164.14 71.83 226.32 0.00 1 0.00 1 0 17 7.501e-03 6.129e-03 1.294e-04 1.006e-04 1.490079e-01 5.064765e-05 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