File name: Pandora101s1_Izana_20210727_L2Fit_fout2c16d20210210p1-8.txt File generation date: 20240504T113146.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v7d20170928.txt Instrument calibration file used: Pandora101s1_CF_v16d20210210.txt Level 1 file used: Pandora101s1_Izana_20210727_L1_smca1c16d20210210p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20210727 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 11 for VP 20210210 First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.0133 305.1541 305.2949 305.4357 305.5766 305.7173 305.8581 305.9989 306.1397 306.2804 306.4211 306.5619 306.7026 306.8433 306.9840 307.1247 307.2653 307.4060 307.5466 307.6873 307.8279 307.9685 308.1091 308.2497 308.3903 308.5309 308.6714 308.8120 308.9525 309.0930 309.2335 309.3740 309.5145 309.6550 309.7954 309.9359 310.0763 310.2168 310.3572 310.4976 310.6380 310.7784 310.9187 311.0591 311.1994 311.3398 311.4801 311.6204 311.7607 311.9010 312.0413 312.1816 312.3218 312.4621 312.6023 312.7425 312.8827 313.0229 313.1631 313.3033 313.4435 313.5836 313.7238 313.8639 314.0040 314.1441 314.2842 314.4243 314.5644 314.7044 314.8445 314.9845 315.1246 315.2646 315.4046 315.5446 315.6845 315.8245 315.9645 316.1044 316.2443 316.3843 316.5242 316.6641 316.8040 316.9438 317.0837 317.2236 317.3634 317.5032 317.6430 317.7829 317.9226 318.0624 318.2022 318.3420 318.4817 318.6214 318.7612 318.9009 319.0406 319.1803 319.3200 319.4596 319.5993 319.7389 319.8785 320.0182 320.1578 320.2974 320.4370 320.5765 320.7161 320.8556 320.9952 321.1347 321.2742 321.4137 321.5532 321.6927 321.8322 321.9716 322.1111 322.2505 322.3899 322.5293 322.6687 322.8081 322.9475 323.0868 323.2262 323.3655 323.5048 323.6442 323.7835 323.9228 324.0620 324.2013 324.3406 324.4798 324.6190 324.7582 324.8975 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210727T065517.1Z 7878.288392 213 1 49.01 2 84.68 71.11 58.30 234.05 0.00 1 0.00 1 0 25 5.869e-01 2.641e-02 2.807e-01 1.036e-02 9.707852e-01 5.987985e-03 9.775274e-03 -6.000000e+00 3.358027e-01 227.92 -2.00 3.19 -2.00 322.07 0.00e+00 -4.500297e-03 3.268560e-03 4.842975e-03 -6.000000e+00 1.583684e-02 282.01 -2.00 20.00 -2.00 321.61 0.00e+00 9.422 0.009 302.00 328.00 3 2.3429e+00 2.2754e-02 9.1474e-02 -6.0000e+00 8.3588e-01 1.1225e+00 3.0670e-02 6.5972e-02 -6.0000e+00 9.1047e-01 -1.5612e+00 2.6546e-02 2.8891e-02 -6.0000e+00 5.3596e-01 6.2731e-01 1.2445e-02 9.1921e-03 -6.0000e+00 2.3052e-01 1.4579e-05 -1.5936e-03 2.6285e-04 1.0360e-04 -6.0000e+00 1.5687e-02 -2.1611e-03 0.0000e+00 12 8 8 10 0 0 89.35 16.88 0.35 -0.00216 -0.01414 27 6 1 5 0 1815.162 21.58 15.00 16.88 900000 -77993 78950 -13402 900000 900000 -89239 900000 -95127 27663 -135595 -97581 -117946 900000 -60073 27692 -58012 18979 -71743 900000 18336 92133 423704 -39775 67667 15342 900000 -57094 7452 -95997 53548 16031 900000 114861 131555 41230 137839 21240 120955 900000 44078 127250 28933 97566 5314 39921 56970 38269 10978 112930 23240 42820 51043 33086 61480 30453 41842 34514 46203 36175 61279 11422 7580 20586 49864 25474 17108 8322 5595 6167 7013 31162 5233 23020 11885 12827 -10026 -4139 -6217 8522 -796 5163 4686 -1083 432 -343 8405 3290 -876 -5121 3507 -1159 441 1305 -7383 -5047 -1702 -2676 -3262 -1357 -2807 -1436 -7894 -2926 -5472 -3348 -5322 -2919 -3723 -80 22 -231 973 -644 -1120 42 1327 783 -490 648 1319 1766 2916 1952 2709 508 2821 1313 558 515 1925 250 -639 -112 -140 -405 -696 1303 468 131 -473 -592 -2487 900000 -2599 796 -226 900000 900000 -2182 900000 -2889 279 -6302 -3259 -5593 900000 -2415 566 -2917 483 -4446 900000 468 1065 4272 -1680 1119 432 900000 -2900 185 -6230 957 504 900000 1768 1653 1120 1486 783 2071 900000 2130 2965 1743 3030 381 1991 2403 1975 761 3169 1676 2915 3535 2909 4484 3086 3914 3453 3918 3119 4024 1239 955 2646 5422 3544 2555 1392 1038 1321 1662 6199 1326 4611 2377 2242 -1988 -775 -1310 1884 -232 1651 1703 -450 187 -157 3691 1571 -436 -2580 1536 -498 181 552 -3835 -3035 -1169 -2167 -2990 -1289 -2605 -1208 -6162 -2059 -4184 -2663 -4537 -2582 -3649 -87 27 -322 1408 -957 -1645 58 1836 1123 -746 1022 2047 2603 4048 2660 3604 673 3555 1684 814 879 3660 525 -1429 -266 -352 -1085 -1903 3551 1288 350 -1198 -1394 -5576 SS 20210727T070748.2Z 7878.297086 217 1 48.42 2 82.06 72.50 60.48 236.46 0.00 1 0.00 1 0 25 6.272e-01 1.152e-02 8.085e-02 2.010e-03 7.876283e-01 1.073651e-03 8.134670e-03 -6.000000e+00 3.522204e-01 227.92 -2.00 3.19 -2.00 321.22 0.00e+00 3.947620e-04 5.160802e-04 2.132997e-03 -6.000000e+00 1.541575e-02 282.01 -2.00 20.00 -2.00 320.70 0.00e+00 6.782 0.003 302.00 328.00 3 1.8111e+00 3.6216e-03 6.4803e-02 -6.0000e+00 8.7650e-01 1.1274e-01 5.1935e-03 4.1177e-02 -6.0000e+00 9.5011e-01 -2.1538e-01 5.4932e-03 2.1359e-02 -6.0000e+00 5.6554e-01 8.4778e-02 2.5988e-03 6.2923e-03 -6.0000e+00 2.4363e-01 2.2497e-04 -7.5694e-04 5.0040e-05 7.5144e-05 -6.0000e+00 1.5736e-02 -3.6594e-03 0.0000e+00 12 8 8 10 0 0 64.10 16.88 0.19 -0.00366 -0.00935 163 38 1 5 0 297.013 21.58 15.00 16.88 -174097 -200459 -186035 -176119 -212802 -212677 -236759 -168622 -182492 -175661 -184997 -167716 -139117 -105064 -86446 -113386 -64482 -47913 -65531 -34409 -29678 -46099 -46983 -54352 -33496 -132062 -26487 -32823 -40671 -41660 -20276 -6083 -11173 -3984 -16324 -9576 -10034 -8307 2259 12918 6821 11933 6810 7980 5649 2162 6759 5352 6672 5943 7703 7490 8241 7765 10458 9285 8309 8041 7520 5978 5964 5822 4661 7012 5907 4826 2700 2739 740 3019 2273 3064 2134 1853 1201 -586 -1263 -3321 -1743 -1670 -1401 -1181 -1340 -1588 -1488 -1011 -204 57 622 682 490 417 -1008 -890 -1434 -341 -544 279 -362 -146 -711 -1046 -1636 -1128 -1174 -1519 -1483 -1137 -296 248 748 471 694 469 278 63 125 61 -71 31 -156 350 677 609 683 563 186 817 37 313 161 213 -164 -104 -242 -132 -45 300 97 -212 -169 -318 -332 -922 -1729 -1568 -1381 -2211 -2085 -3156 -1322 -1932 -1963 -2430 -2039 -1609 -1153 -1034 -2245 -923 -658 -1195 -492 -425 -777 -820 -1140 -644 -6731 -540 -701 -909 -980 -461 -151 -355 -135 -624 -325 -362 -347 97 619 408 749 479 576 421 170 524 439 576 557 795 892 1094 1147 1502 1429 1357 1339 1222 947 942 992 923 1580 1503 1257 706 737 222 1034 894 1180 837 752 449 -198 -392 -1045 -593 -684 -636 -626 -807 -1030 -1024 -741 -146 42 462 493 360 286 -669 -597 -1077 -277 -520 288 -428 -179 -843 -1118 -1661 -1085 -1206 -1568 -1603 -1308 -368 327 1123 780 1119 748 451 98 190 96 -119 52 -260 589 1079 942 1020 813 258 1129 59 538 312 425 -347 -222 -558 -324 -107 726 238 -504 -397 -692 -715 SS 20210727T072316.1Z 7878.307825 222 1 48.53 2 78.80 74.17 63.26 239.26 0.00 1 0.00 1 0 25 2.548e-01 6.649e-03 1.647e-02 6.706e-04 6.045281e-01 3.437259e-04 6.341333e-03 -6.000000e+00 1.430922e-01 227.92 -2.00 3.19 -2.00 320.10 0.00e+00 1.039473e-03 1.175768e-04 4.858542e-04 -6.000000e+00 6.262507e-03 282.01 -2.00 20.00 -2.00 319.49 0.00e+00 4.978 0.001 302.00 328.00 3 1.3508e+00 1.0090e-03 4.7474e-02 -6.0000e+00 3.5608e-01 1.4963e-03 1.2580e-03 2.8806e-02 -6.0000e+00 3.8598e-01 -2.8599e-02 1.1754e-03 1.4705e-02 -6.0000e+00 2.2975e-01 4.2317e-03 6.0451e-04 4.5158e-03 -6.0000e+00 9.8981e-02 1.5593e-03 -5.3851e-04 1.7318e-05 4.4940e-05 -6.0000e+00 6.3923e-03 -3.9775e-03 0.0000e+00 11 8 0 10 0 0 36.72 16.89 0.23 -0.00398 -0.00802 524 124 1 5 0 92.608 21.58 15.00 16.89 -87657 -94244 -67304 -89007 -81407 -99713 -84894 -89913 -65594 -72210 -66769 -63422 -58631 -38681 -29863 -22426 -22737 -11581 -17616 -5746 -15421 -10908 -15841 -8873 -10486 -21240 -7445 -10598 -11424 -14270 -7069 -6412 727 -2714 -3378 -8235 -3932 -4316 699 1396 1116 1182 1840 1510 1463 2101 1383 1935 178 1625 1740 2669 2000 2360 1986 2107 1616 1670 935 476 960 1420 2226 2694 2402 1189 283 -703 284 714 871 803 347 122 13 -703 -1734 -2450 -2061 -1331 -1224 -1109 -1887 -1414 -1345 -467 -112 248 584 890 728 529 -173 -425 -287 -170 -81 522 411 126 -176 -672 -732 -456 -673 -1122 -787 -540 -239 438 536 529 564 458 7 26 -22 228 19 -83 -291 -193 198 166 394 352 100 562 379 266 239 18 -210 -243 -317 -188 -72 272 236 -84 -153 -136 -273 -883 -1245 -757 -1269 -985 -1363 -1060 -1364 -914 -1204 -1109 -1087 -1166 -809 -726 -622 -726 -366 -591 -201 -568 -424 -601 -344 -459 -1120 -356 -513 -535 -700 -369 -402 50 -218 -269 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