File name: Pandora101s1_Izana_20210913_L2Fit_fout2c16d20210210p1-8.txt File generation date: 20240504T110602.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v8d20170928.txt Instrument calibration file used: Pandora101s1_CF_v16d20210210.txt Level 1 file used: Pandora101s1_Izana_20210913_L1_smca1c16d20210210p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20210913 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 11 for VP 20210210 First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.0133 305.1541 305.2949 305.4357 305.5766 305.7173 305.8581 305.9989 306.1397 306.2804 306.4211 306.5619 306.7026 306.8433 306.9840 307.1247 307.2653 307.4060 307.5466 307.6873 307.8279 307.9685 308.1091 308.2497 308.3903 308.5309 308.6714 308.8120 308.9525 309.0930 309.2335 309.3740 309.5145 309.6550 309.7954 309.9359 310.0763 310.2168 310.3572 310.4976 310.6380 310.7784 310.9187 311.0591 311.1994 311.3398 311.4801 311.6204 311.7607 311.9010 312.0413 312.1816 312.3218 312.4621 312.6023 312.7425 312.8827 313.0229 313.1631 313.3033 313.4435 313.5836 313.7238 313.8639 314.0040 314.1441 314.2842 314.4243 314.5644 314.7044 314.8445 314.9845 315.1246 315.2646 315.4046 315.5446 315.6845 315.8245 315.9645 316.1044 316.2443 316.3843 316.5242 316.6641 316.8040 316.9438 317.0837 317.2236 317.3634 317.5032 317.6430 317.7829 317.9226 318.0624 318.2022 318.3420 318.4817 318.6214 318.7612 318.9009 319.0406 319.1803 319.3200 319.4596 319.5993 319.7389 319.8785 320.0182 320.1578 320.2974 320.4370 320.5765 320.7161 320.8556 320.9952 321.1347 321.2742 321.4137 321.5532 321.6927 321.8322 321.9716 322.1111 322.2505 322.3899 322.5293 322.6687 322.8081 322.9475 323.0868 323.2262 323.3655 323.5048 323.6442 323.7835 323.9228 324.0620 324.2013 324.3406 324.4798 324.6190 324.7582 324.8975 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210913T071843.7Z 7926.304673 51 1 48.89 2 84.57 88.75 166.84 70.58 0.00 1 0.00 1 0 17 4.578e-01 2.718e-02 2.097e-01 6.381e-03 9.532249e-01 3.565225e-03 9.453174e-03 -6.000000e+00 2.588079e-01 226.94 -2.00 3.19 -2.00 321.95 0.00e+00 -1.808181e-02 1.897290e-03 4.830618e-03 -6.000000e+00 1.162560e-02 281.06 -2.00 20.00 -2.00 321.48 0.00e+00 9.279 0.008 302.00 328.00 3 1.7890e+00 1.3314e-02 9.4876e-02 -6.0000e+00 6.4278e-01 8.6679e-01 1.9146e-02 8.3717e-02 -6.0000e+00 6.9807e-01 -1.3113e+00 1.7982e-02 2.7981e-02 -6.0000e+00 4.1332e-01 5.4382e-01 8.2634e-03 1.8923e-02 -6.0000e+00 1.7773e-01 3.2174e-05 -1.0702e-03 1.5884e-04 1.7166e-04 -6.0000e+00 1.1846e-02 2.7801e-03 0.0000e+00 12 8 8 10 0 0 33.76 16.86 0.38 0.00278 -0.00526 50 12 1 5 0 977.827 21.58 15.00 16.86 69284 -60204 -120187 900000 -90884 900000 -129657 900000 -79104 -55144 -112892 -95908 -64364 900000 8943 -19357 -16425 -25002 3536 26708 93960 33585 83375 -35509 62673 -142896 193506 10347 17903 -35512 28916 27705 44653 70307 10634 60296 60575 57292 80405 165311 41206 86369 51092 104237 32487 20826 81105 20880 25380 53143 39485 5357 52958 27803 57411 29775 45030 37139 43579 27361 38880 24757 12088 30933 19044 21685 9908 19054 7164 17420 12068 22745 10917 16664 14039 5649 1070 -6243 -2563 581 33 -1940 2586 -2504 -112 21 5679 1464 3098 -1658 2302 -390 -120 -308 -4977 -2682 -4303 -2958 -4087 -1812 -4867 -2957 -6098 -3060 -2755 -2293 -2398 -1614 -2709 -711 33 -647 1327 -249 -30 752 1378 -514 337 -740 489 2306 1910 2284 2471 1842 1237 2458 45 -81 -135 418 -216 125 105 517 273 981 205 -244 -831 -1015 -2180 431 -953 -3465 900000 -1490 900000 -3005 900000 -1565 -966 -3702 -2765 -1528 900000 136 -449 -399 -693 76 453 876 543 830 -1225 1052 -17106 1203 263 401 -1164 611 706 1111 1487 355 1237 1281 1461 2050 2262 2073 3276 2542 3241 1763 1213 2774 1192 1449 2710 2344 512 3503 2609 4382 3215 4429 3989 4139 2784 3319 2519 1572 3847 2961 3310 1686 3102 1454 3742 3097 5568 2755 4060 3151 1204 216 -1362 -598 159 10 -710 1036 -1142 -53 11 2840 788 1637 -888 1108 -182 -54 -146 -2827 -1772 -3418 -2508 -3998 -1815 -4820 -2578 -5208 -2409 -2310 -1898 -2087 -1497 -2820 -843 45 -933 1981 -380 -45 1062 1919 -759 521 -1210 780 3412 2682 3352 3521 2571 1670 3335 67 -144 -274 868 -485 302 274 1347 730 2629 553 -637 -2150 -2401 -4848 SS 20210913T073117.2Z 7926.313393 55 1 48.53 2 81.81 90.24 164.36 75.10 0.00 1 0.00 1 0 25 5.411e-01 9.317e-03 5.638e-02 1.447e-03 7.414279e-01 7.594193e-04 7.662711e-03 -6.000000e+00 3.025484e-01 226.94 -2.00 3.19 -2.00 320.98 0.00e+00 1.897308e-03 3.428023e-04 1.440185e-03 -6.000000e+00 1.324720e-02 281.06 -2.00 20.00 -2.00 320.45 0.00e+00 6.598 0.003 302.00 328.00 3 1.4132e+00 2.4750e-03 6.1449e-02 -6.0000e+00 7.5139e-01 9.3469e-02 3.4355e-03 3.6723e-02 -6.0000e+00 8.1543e-01 -1.3827e-01 3.5852e-03 1.9941e-02 -6.0000e+00 4.8545e-01 4.9691e-02 1.7296e-03 6.5509e-03 -6.0000e+00 2.0922e-01 3.9697e-04 -5.2891e-04 3.6428e-05 7.3021e-05 -6.0000e+00 1.3578e-02 1.4258e-03 0.0000e+00 11 8 0 10 0 0 96.47 16.87 0.19 0.00143 -0.00255 251 59 1 5 0 193.346 21.58 14.99 16.87 -195770 -179764 -184232 -138083 -204547 -117056 -215540 -124557 -176267 -119868 -173417 -116622 -140674 -98117 -90797 -78980 -58325 -53065 -29674 -42661 -15398 -41316 -15321 -49332 -15808 -70510 -13419 -37007 -29404 -36025 -12874 -15674 -5775 -2429 -7444 -8843 -15306 68 -3277 9787 -1472 7243 1443 7230 2790 2260 3419 2667 2205 4580 3892 3956 8295 4846 7750 3836 6707 3000 4085 1741 5140 2874 4887 4996 4035 3324 1400 1864 508 2670 924 2179 -70 1085 -542 -965 -2252 -2950 -2785 -1299 -1078 -1620 -1557 -2041 -1019 -841 317 291 899 468 833 -257 -389 -821 -838 -692 -641 455 62 200 -603 -714 -1222 -378 -1127 -1263 -1179 -609 -250 263 512 523 725 331 -34 120 170 111 189 -223 -49 73 663 290 489 373 65 504 206 380 161 252 -196 19 -534 -119 -234 321 217 -85 -183 -153 -292 -1741 -1700 -2054 -994 -2388 -595 -2848 -844 -2338 -1015 -2668 -1119 -2184 -1329 -1499 -1460 -1029 -1003 -494 -867 -250 -869 -255 -1165 -328 -2488 -307 -959 -755 -943 -352 -503 -202 -94 -299 -343 -674 3 -188 612 -120 595 134 658 268 224 346 283 229 498 476 554 1244 830 1396 757 1347 633 829 349 1000 620 1186 1404 1170 975 409 556 167 1005 402 996 -33 480 -223 -356 -767 -1004 -1039 -573 -569 -929 -1005 -1415 -743 -655 258 246 761 388 644 -187 -270 -578 -656 -591 -641 489 76 253 -733 -780 -1264 -373 -1199 -1442 -1320 -724 -322 360 793 834 1187 533 -55 185 259 175 299 -373 -82 116 1063 452 733 542 91 701 324 653 294 496 -409 40 -1211 -273 -551 764 522 -198 -421 -328 -621 SS 20210913T074513.9Z 7926.323077 60 1 48.53 2 78.74 91.91 161.54 78.90 0.00 1 0.00 1 0 25 2.061e-01 6.255e-03 1.276e-02 5.924e-04 5.821996e-01 3.013533e-04 6.132441e-03 -6.000000e+00 1.152623e-01 226.94 -2.00 3.19 -2.00 319.91 0.00e+00 9.831184e-04 9.719976e-05 5.338018e-04 -6.000000e+00 5.046928e-03 281.06 -2.00 20.00 -2.00 319.30 0.00e+00 4.953 0.001 302.00 328.00 3 1.1918e+00 8.7064e-04 4.6510e-02 -6.0000e+00 2.8626e-01 2.1333e-02 1.0631e-03 2.7586e-02 -6.0000e+00 3.1066e-01 -2.8962e-02 9.6640e-04 1.4071e-02 -6.0000e+00 1.8495e-01 2.5403e-03 5.0308e-04 4.3219e-03 -6.0000e+00 7.9704e-02 1.9061e-03 -3.5102e-04 1.5326e-05 4.1915e-05 -6.0000e+00 5.1730e-03 1.6293e-03 0.0000e+00 10 0 0 10 0 0 84.42 16.87 0.21 0.00163 -0.00101 581 137 1 5 0 83.521 21.58 14.99 16.87 -83684 -69798 -67781 -56960 -73747 -73472 -77813 -62964 -55937 -56372 -53474 -54534 -39240 -34696 -23007 -18908 -11851 -12384 -9876 -8845 -6805 -8331 -9693 -8353 -6842 -9592 -6476 -8034 -12178 -9324 -6398 -2000 -1292 -622 -4784 -4716 -5797 -2576 -171 1478 1029 1359 1873 1095 1759 801 1053 324 335 470 1400 1724 2217 1772 1767 1932 1423 1186 691 296 528 1496 1975 2764 1934 1017 -15 -176 52 881 748 835 351 159 11 -757 -1624 -2550 -1896 -1367 -1056 -1328 -1557 -1631 -1227 -559 -76 315 680 783 570 505 -237 -300 -362 -176 -104 728 405 220 -287 -735 -779 -245 -577 -1013 -724 -520 -204 314 578 549 563 331 18 -21 9 114 105 -109 -274 20 244 235 364 344 -23 522 325 248 87 30 -212 -137 -310 -192 -85 286 226 -32 -192 -146 -265 -1088 -960 -1010 -770 -1074 -1006 -1182 -953 -921 -1039 -1001 -1099 -825 -890 -662 -636 -422 -444 -378 -357 -282 -351 -423 -394 -352 -547 -371 -457 -690 -522 -398 -143 -107 -57 -451 -421 -556 -281 -23 236 174 249 361 220 353 165 221 70 75 109 352 487 686 600 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