File name: Pandora101s1_Izana_20231121_L2Fit_fout2c22d20230904p1-8.txt File generation date: 20240911T133701.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c22p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v3d20220624.txt Instrument calibration file used: Pandora101s1_CF_v22d20230904.txt Level 1 file used: Pandora101s1_Izana_20231121_L1_smca1c22d20230904p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20231121 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 fieldcal with sens applied First and last pixel inside fitting window: 222 363 Nominal wavelengths inside fitting window [nm]: 305.1209 305.2618 305.4026 305.5434 305.6843 305.8251 305.9659 306.1066 306.2474 306.3882 306.5289 306.6697 306.8104 306.9511 307.0918 307.2325 307.3732 307.5139 307.6545 307.7952 307.9358 308.0764 308.2170 308.3576 308.4982 308.6388 308.7794 308.9199 309.0605 309.2010 309.3415 309.4820 309.6225 309.7630 309.9035 310.0440 310.1844 310.3249 310.4653 310.6057 310.7461 310.8865 311.0269 311.1673 311.3076 311.4480 311.5883 311.7287 311.8690 312.0093 312.1496 312.2898 312.4301 312.5704 312.7106 312.8509 312.9911 313.1313 313.2715 313.4117 313.5519 313.6920 313.8322 313.9723 314.1125 314.2526 314.3927 314.5328 314.6729 314.8129 314.9530 315.0931 315.2331 315.3731 315.5131 315.6531 315.7931 315.9331 316.0731 316.2130 316.3530 316.4929 316.6329 316.7728 316.9127 317.0526 317.1924 317.3323 317.4722 317.6120 317.7518 317.8916 318.0315 318.1712 318.3110 318.4508 318.5906 318.7303 318.8701 319.0098 319.1495 319.2892 319.4289 319.5686 319.7082 319.8479 319.9875 320.1272 320.2668 320.4064 320.5460 320.6856 320.8252 320.9647 321.1043 321.2438 321.3833 321.5229 321.6624 321.8019 321.9413 322.0808 322.2203 322.3597 322.4991 322.6386 322.7780 322.9174 323.0568 323.1961 323.3355 323.4749 323.6142 323.7535 323.8928 324.0321 324.1714 324.3107 324.4500 324.5893 324.7285 324.8677 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231121T132650.8Z 8725.560310 262 1 48.31 2 48.97 190.93 104.82 93.57 0.00 1 0.00 1 0 17 1.261e-02 9.881e-03 3.077e-03 1.819e-03 2.057897e-01 9.113431e-04 2.291311e-03 -6.000000e+00 7.047728e-03 223.77 -2.00 3.19 -2.00 315.48 0.00e+00 8.797761e-04 8.524731e-05 3.283763e-05 -6.000000e+00 3.051360e-04 275.52 -2.00 20.00 -2.00 314.98 0.00e+00 1.521 0.000 302.00 328.00 3 7.8907e+00 2.3293e-03 1.4876e-02 -6.0000e+00 1.7411e-02 7.2761e-02 2.5958e-03 9.4092e-03 -6.0000e+00 1.8927e-02 -2.9395e-03 1.5000e-03 4.6818e-03 -6.0000e+00 1.1251e-02 -2.5604e-03 7.0108e-04 1.4487e-03 -6.0000e+00 4.9065e-03 4.8032e-05 -2.7562e-04 4.9200e-05 1.5952e-05 -6.0000e+00 3.2606e-04 -2.4228e-03 0.0000e+00 12 8 8 10 0 0 98.75 20.96 0.04 -0.00242 -0.00449 14 4 1 5 0 3450.410 20.96 15.00 14.41 12.16 0.1 901.91 554 2025 -1192 568 -3788 -1686 -1862 -75 -528 -2599 -2458 -2640 -643 -442 1784 417 1228 709 1794 1929 68 1157 -56 1121 453 1003 -637 -32 -1288 664 176 1835 -166 -1324 -4499 -3340 -2553 -1271 82 -143 515 468 62 211 135 -583 -496 -1721 -637 -522 358 740 964 1305 793 1119 199 107 -310 337 365 1474 2233 2072 160 -149 -1314 -986 225 479 825 850 1115 899 103 -1660 -2565 -3549 -2264 -2215 -1419 -1652 -1377 -938 -181 320 874 1587 1033 1145 -79 -748 -1385 -1187 -1426 72 792 1403 882 399 -529 -1238 -1027 -1207 -493 -517 -218 -226 959 825 1630 1064 634 -396 -769 -1506 -1244 -665 236 306 608 839 428 726 177 -455 -596 -328 -115 222 -297 -6 -259 52 468 230 350 491 299 -279 -519 -1011 144 547 -326 140 -863 -378 -443 -20 -148 -749 -701 -769 -207 -158 680 171 509 304 765 846 31 514 -25 526 223 501 -312 -15 -560 289 80 879 -85 -665 -2193 -1624 -1349 -753 55 -104 393 360 49 165 105 -454 -381 -1291 -469 -388 275 587 800 1098 681 974 172 93 -265 288 320 1354 2152 2078 156 -136 -1144 -849 208 478 862 893 1168 916 99 -1493 -2195 -2968 -1977 -2100 -1428 -1776 -1517 -1060 -214 389 1090 2003 1294 1401 -92 -822 -1425 -1236 -1544 81 954 1776 1156 511 -640 -1435 -1182 -1438 -621 -669 -288 -306 1326 1173 2380 1538 894 -532 -980 -1873 -1543 -853 319 422 845 1157 584 952 225 -560 -712 -401 -145 292 -399 -8 -358 74 680 343 532 748 455 -420 -765 -1465 SS 20231121T135810.9Z 8725.582070 277 1 47.77 2 50.84 200.25 98.13 96.93 0.00 1 0.00 1 0 17 7.737e-03 5.782e-03 1.043e-03 6.543e-04 1.965123e-01 3.295290e-04 2.213469e-03 -6.000000e+00 4.324809e-03 223.77 -2.00 3.19 -2.00 315.29 0.00e+00 3.911924e-04 2.964149e-05 2.227558e-05 -6.000000e+00 1.872483e-04 275.52 -2.00 20.00 -2.00 314.81 0.00e+00 1.580 0.000 302.00 328.00 3 5.9470e+00 8.4053e-04 1.4975e-02 -6.0000e+00 1.0684e-02 2.1002e-02 9.3515e-04 9.0128e-03 -6.0000e+00 1.1615e-02 1.9703e-04 5.3928e-04 4.4972e-03 -6.0000e+00 6.9045e-03 -2.9145e-03 2.4928e-04 1.3170e-03 -6.0000e+00 3.0108e-03 3.3503e-04 -1.4401e-04 1.7726e-05 1.5574e-05 -6.0000e+00 2.0010e-04 -2.1313e-03 0.0000e+00 10 0 0 10 0 0 99.91 20.96 0.22 -0.00213 -0.00321 107 27 1 5 0 446.400 20.96 15.00 14.41 12.77 0.1 906.62 -749 5 -1409 -2539 -2503 -1474 176 425 53 -986 -1319 -946 -144 169 555 24 620 797 1240 924 293 930 1106 878 322 284 -527 -323 -282 1018 856 1843 240 -1480 -2035 -1888 -1150 -637 -195 -639 -366 -505 -473 -308 -101 -677 -408 -809 -404 260 545 776 1019 877 654 908 383 461 284 665 772 1342 1305 847 -72 -315 -618 29 647 247 364 179 490 166 108 -529 -818 -1175 -994 -1419 -1183 -1713 -1689 -1156 -827 -211 153 396 396 463 217 86 -85 103 -131 213 722 657 264 -62 -485 -758 -156 -443 -701 -654 -335 -347 389 457 777 486 354 -70 -47 39 -180 11 171 -18 13 235 169 422 216 97 338 607 239 226 -108 -183 -155 -136 56 -100 287 108 -7 -186 -373 -672 -216 1 -420 -683 -652 -374 48 120 16 -308 -400 -298 -51 67 226 10 271 358 571 440 141 436 533 447 160 144 -260 -157 -128 454 406 928 131 -799 -1015 -951 -600 -393 -133 -466 -282 -402 -383 -248 -81 -539 -313 -601 -310 201 416 628 862 727 552 778 333 394 238 558 678 1268 1253 848 -69 -289 -527 26 598 244 384 184 521 169 107 -468 -698 -973 -887 -1352 -1180 -1864 -1824 -1303 -951 -258 186 489 484 561 253 96 -86 104 -143 242 858 813 338 -80 -580 -879 -176 -539 -880 -818 -436 -469 524 652 1142 706 484 -92 -59 47 -220 14 228 -25 18 329 229 542 277 118 411 756 305 305 -144 -247 -212 -196 82 -152 425 163 -10 -286 -553 -963 SS 20231121T140454.2Z 8725.586738 281 1 47.76 2 51.37 202.16 96.70 97.65 0.00 1 0.00 1 0 17 8.387e-03 6.163e-03 1.805e-03 1.038e-03 2.000769e-01 5.205653e-04 2.244707e-03 -6.000000e+00 4.688123e-03 223.77 -2.00 3.19 -2.00 315.62 0.00e+00 4.518775e-04 4.989221e-05 2.671593e-05 -6.000000e+00 2.029808e-04 275.52 -2.00 20.00 -2.00 315.11 0.00e+00 1.599 0.000 302.00 328.00 3 6.7376e+00 1.3325e-03 1.5182e-02 -6.0000e+00 1.1582e-02 3.1297e-02 1.4848e-03 9.1715e-03 -6.0000e+00 1.2591e-02 5.7638e-04 8.5880e-04 4.5763e-03 -6.0000e+00 7.4846e-03 -3.1327e-03 4.0243e-04 1.3490e-03 -6.0000e+00 3.2636e-03 1.4814e-04 -1.4716e-04 2.8258e-05 1.5730e-05 -6.0000e+00 2.1693e-04 -1.9337e-03 0.0000e+00 11 1 0 11 8 0 99.96 20.96 0.13 -0.00193 -0.00304 75 19 1 5 0 636.690 20.96 15.00 14.41 13.25 0.1 914.19 -94 -10 -1009 -2244 -2407 -2346 521 -190 210 -2012 -1038 -1498 -108 -75 607 102 315 847 801 1096 93 1561 845 1080 245 509 -515 0 -689 1092 599 1582 289 -1855 -2248 -2241 -1305 -781 86 -549 -234 -669 -487 -426 64 -587 -449 -721 -389 134 450 848 911 1158 480 1095 458 449 44 750 723 1430 1498 957 8 -262 -626 -433 522 381 708 245 643 120 38 -785 -1155 -1569 -1182 -1522 -1291 -1544 -1766 -988 -879 -156 341 754 563 585 256 -156 -236 -130 -270 54 613 633 292 23 -505 -716 -299 -667 -623 -669 -356 -187 453 602 828 600 291 21 -121 -358 -398 79 244 70 -66 242 112 346 247 61 365 387 332 150 -47 -233 -51 -178 188 19 455 71 40 -313 -390 -756 -24 -3 -263 -550 -524 -503 118 -49 57 -558 -286 -417 -33 -26 227 41 127 350 341 480 41 669 375 487 117 246 -242 0 -290 449 263 737 140 -894 -1039 -1048 -654 -447 56 -395 -172 -510 -377 -328 49 -446 -340 -529 -276 96 341 657 739 973 400 923 392 378 37 639 625 1289 1452 940 8 -237 -543 -372 476 370 733 254 670 120 36 -708 -977 -1291 -1013 -1432 -1305 -1650 -1923 -1121 -1043 -191 424 952 703 710 293 -171 -243 -134 -290 62 732 804 384 29 -623 -836 -341 -796 -783 -856 -474 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