File name: Pandora121s1_Izana_20160422_L2Fit_fwvt1c60d20160420p1-8.txt File generation date: 20260206T160302.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c60p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 121 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora121_OF_v2d20160420.txt Instrument calibration file used: Pandora121s1_CF_v60d20160420.txt Level 1 file used: Pandora121s1_Izana_20160422_L1_smca1c60d20160420p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20160422 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1642 1791 Nominal wavelengths inside fitting window [nm]: 492.0784 492.1996 492.3208 492.4420 492.5632 492.6843 492.8055 492.9266 493.0477 493.1688 493.2898 493.4109 493.5319 493.6529 493.7739 493.8949 494.0159 494.1369 494.2578 494.3787 494.4996 494.6205 494.7414 494.8622 494.9831 495.1039 495.2247 495.3455 495.4662 495.5870 495.7077 495.8284 495.9491 496.0698 496.1905 496.3111 496.4318 496.5524 496.6730 496.7936 496.9141 497.0347 497.1552 497.2757 497.3962 497.5167 497.6372 497.7576 497.8780 497.9985 498.1189 498.2392 498.3596 498.4799 498.6003 498.7206 498.8409 498.9612 499.0814 499.2017 499.3219 499.4421 499.5623 499.6825 499.8026 499.9228 500.0429 500.1630 500.2831 500.4032 500.5233 500.6433 500.7633 500.8833 501.0033 501.1233 501.2432 501.3632 501.4831 501.6030 501.7229 501.8428 501.9626 502.0825 502.2023 502.3221 502.4419 502.5616 502.6814 502.8011 502.9209 503.0406 503.1602 503.2799 503.3996 503.5192 503.6388 503.7584 503.8780 503.9975 504.1171 504.2366 504.3561 504.4756 504.5951 504.7146 504.8340 504.9534 505.0729 505.1922 505.3116 505.4310 505.5503 505.6696 505.7890 505.9082 506.0275 506.1468 506.2660 506.3852 506.5044 506.6236 506.7428 506.8619 506.9811 507.1002 507.2193 507.3384 507.4574 507.5765 507.6955 507.8145 507.9335 508.0525 508.1715 508.2904 508.4093 508.5283 508.6471 508.7660 508.8849 509.0037 509.1225 509.2413 509.3601 509.4789 509.5977 509.7164 509.8351 509.9538 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Columns 99-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-398: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20160422T063908.7Z 5956.277184 174 1 33.45 2 89.62 76.13 88.31 257.97 0.00 1 0.00 1 0 22 5.808e-03 5.730e-03 1.543e-04 1.536e-04 9.728549e+03 1.036580e+01 6.704147e+02 -6.000000e+00 3.228374e+02 276.52 -2.00 20.00 -2.00 505.43 0.00e+00 1.948622e-03 4.260707e-06 1.126605e-04 -6.000000e+00 1.620583e-04 276.52 -2.00 20.00 -2.00 501.08 0.00e+00 1.489316e+00 3.007215e-03 7.552215e-02 -6.000000e+00 1.167924e-01 228.20 -2.00 3.19 -2.00 502.58 0.00e+00 20.328 0.087 489.00 513.00 1 1.7450e+00 2.2977e-04 2.4978e-02 -6.0000e+00 8.9500e-03 -5.6964e-02 5.7306e-05 2.2402e-03 -6.0000e+00 2.3019e-03 3.2796e-02 -1.7320e-04 1.5817e-05 9.3880e-05 -6.0000e+00 6.3846e-04 1.3149e-02 -2.1694e-05 12 8 8 10 0 0 99.44 16.75 1.56 0.01315 0.01195 640 121 2 2 0 52.280 15.00 16.75 21.48 21.38 -1308 -957 -437 -81 208 778 985 958 820 467 273 -28 -384 -584 -660 -560 -295 232 313 134 273 374 500 709 803 543 575 253 -463 -900 -759 -671 -242 374 266 -33 54 105 -151 -186 -49 60 318 533 616 636 569 337 6 -513 -984 -1181 -1252 -776 -225 -17 154 183 282 428 620 648 606 587 443 183 -58 -160 -438 -731 -673 -540 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-923 -997 -819 SO 20160422T064534.6Z 5956.281650 177 1 33.17 2 88.24 76.89 89.66 258.71 0.00 1 0.00 1 0 22 3.718e-03 3.689e-03 7.390e-05 7.377e-05 4.088336e+03 4.549445e+00 2.936370e+02 -6.000000e+00 2.066929e+02 276.52 -2.00 20.00 -2.00 505.37 0.00e+00 1.370510e-03 2.026774e-06 7.581930e-05 -6.000000e+00 1.037620e-04 276.52 -2.00 20.00 -2.00 500.87 0.00e+00 1.364584e+00 1.451099e-03 3.516369e-02 -6.000000e+00 7.483882e-02 228.20 -2.00 3.19 -2.00 502.40 0.00e+00 17.013 0.051 489.00 513.00 1 6.9587e-01 1.1094e-04 1.9590e-02 -6.0000e+00 5.7341e-03 -2.1495e-02 2.8078e-05 1.3246e-03 -6.0000e+00 1.4765e-03 1.3738e-01 7.4286e-04 7.8441e-06 4.9370e-05 -6.0000e+00 4.0891e-04 1.0594e-02 -7.5028e-05 10 0 0 10 0 0 -16.54 16.74 1.05 0.01059 0.01575 2172 409 2 2 0 15.200 15.00 16.74 21.48 21.48 -705 -525 -244 -72 27 468 652 590 550 369 250 56 -208 -313 -402 -400 -207 160 167 -39 92 240 301 500 577 391 442 254 -309 -553 -375 -404 -159 298 86 -199 -24 88 -102 -117 -43 27 137 307 414 442 400 265 106 -337 -618 -774 -839 -519 -205 -152 -84 -40 76 220 373 417 394 383 310 139 15 -26 -215 -492 -435 -336 -188 29 -48 -376 -499 -362 -378 -530 -455 -462 -490 -203 -99 -214 -210 -118 -80 22 188 513 601 388 350 275 -13 -276 -565 -843 -793 -591 -193 17 -317 -378 -353 -371 -228 -48 -4 117 270 417 542 700 799 660 394 308 200 99 335 410 162 231 319 240 390 382 -28 -262 -224 -385 -340 -16 -56 -109 122 270 178 286 384 333 229 -18 -374 -608 -591 -467 -652 -474 -226 -69 27 450 636 581 541 360 241 54 -196 -305 -392 -378 -199 156 167 -39 94 245 308 494 572 388 436 257 -309 -540 -361 -393 -158 293 86 -202 -24 88 -101 -116 -43 27 139 314 425 455 409 268 106 -328 -612 -754 -815 -510 -198 -151 -85 -41 77 225 382 428 406 394 317 140 15 -26 -210 -477 -420 -326 -184 28 -48 -371 -486 -347 -360 -506 -436 -447 -478 -200 -99 -214 -211 -118 -81 22 185 509 601 388 346 277 -13 -266 -537 -795 -751 -572 -192 17 -321 -384 -355 -370 -227 -49 -4 121 282 424 554 720 825 683 406 313 208 102 346 425 163 233 322 242 393 384 -28 -269 -227 -391 -347 -16 -58 -113 129 287 192 298 402 350 241 -18 -398 -637 -613 -486 SO 20160422T064859.4Z 5956.284021 180 1 32.85 2 87.51 77.29 90.38 259.09 0.00 1 0.00 1 0 15 3.267e-03 3.256e-03 5.902e-05 5.893e-05 3.151167e+03 3.583922e+00 2.279504e+02 -6.000000e+00 1.816435e+02 276.52 -2.00 20.00 -2.00 505.35 0.00e+00 1.175772e-03 1.622543e-06 6.453251e-05 -6.000000e+00 9.118691e-05 276.52 -2.00 20.00 -2.00 500.78 0.00e+00 1.263293e+00 1.167190e-03 2.793662e-02 -6.000000e+00 6.576899e-02 228.20 -2.00 3.19 -2.00 502.34 0.00e+00 15.005 0.035 489.00 513.00 1 4.8335e-01 8.9363e-05 1.6959e-02 -6.0000e+00 5.0392e-03 -1.3314e-02 2.2646e-05 1.1088e-03 -6.0000e+00 1.2975e-03 2.1348e-01 6.8895e-04 6.2930e-06 3.8756e-05 -6.0000e+00 3.5935e-04 9.2084e-03 -6.6566e-05 10 0 0 10 0 0 16.26 16.75 0.98 0.00921 0.01399 3088 582 2 2 0 10.600 15.00 16.75 21.48 21.48 -594 -475 -223 -102 -25 394 533 515 475 304 223 64 -192 -277 -367 -381 -207 144 118 -100 47 209 256 470 524 340 397 241 -244 -475 -277 -323 -114 296 70 -215 -32 111 -104 -88 -30 14 130 262 358 379 363 238 101 -290 -541 -678 -751 -474 -168 -148 -113 -75 44 183 348 385 353 345 280 137 41 -1 -184 -431 -380 -274 -150 64 -17 -342 -430 -286 -298 -449 -384 -396 -412 -153 -62 -196 -185 -102 -60 27 154 452 520 319 291 249 -14 -252 -484 -718 -683 -521 -160 25 -320 -364 -335 -349 -225 -33 -11 96 212 357 450 607 703 582 344 251 170 83 299 344 93 195 282 207 362 357 -49 -282 -198 -361 -296 21 -39 -108 86 228 136 240 346 294 193 -39 -374 -561 -546 -443 -553 -450 -208 -98 -24 382 525 511 471 299 217 64 -190 -272 -359 -375 -200 142 119 -102 48 214 264 484 542 352 408 245 -243 -464 -267 -313 -113 302 71 -218 -32 110 -103 -87 -30 14 130 267 366 389 370 239 99 -292 -532 -655 -722 -461 -167 -146 -114 -76 45 185 353 392 360 351 283 137 40 -1 -177 -429 -376 -272 -145 62 -16 -334 -414 -281 -291 -439 -377 -378 -397 -149 -61 -194 -183 -101 -59 27 155 459 533 316 295 248 -14 -241 -455 -695 -639 -497 -157 25 -318 -363 -331 -342 -220 -32 -11 98 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