File name: Pandora121s1_Izana_20160515_L2Fit_fwvt1c60d20160420p1-8.txt File generation date: 20260206T160439.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c60p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 121 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora121_OF_v2d20160420.txt Instrument calibration file used: Pandora121s1_CF_v60d20160420.txt Level 1 file used: Pandora121s1_Izana_20160515_L1_smca1c60d20160420p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20160515 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1642 1791 Nominal wavelengths inside fitting window [nm]: 492.0784 492.1996 492.3208 492.4420 492.5632 492.6843 492.8055 492.9266 493.0477 493.1688 493.2898 493.4109 493.5319 493.6529 493.7739 493.8949 494.0159 494.1369 494.2578 494.3787 494.4996 494.6205 494.7414 494.8622 494.9831 495.1039 495.2247 495.3455 495.4662 495.5870 495.7077 495.8284 495.9491 496.0698 496.1905 496.3111 496.4318 496.5524 496.6730 496.7936 496.9141 497.0347 497.1552 497.2757 497.3962 497.5167 497.6372 497.7576 497.8780 497.9985 498.1189 498.2392 498.3596 498.4799 498.6003 498.7206 498.8409 498.9612 499.0814 499.2017 499.3219 499.4421 499.5623 499.6825 499.8026 499.9228 500.0429 500.1630 500.2831 500.4032 500.5233 500.6433 500.7633 500.8833 501.0033 501.1233 501.2432 501.3632 501.4831 501.6030 501.7229 501.8428 501.9626 502.0825 502.2023 502.3221 502.4419 502.5616 502.6814 502.8011 502.9209 503.0406 503.1602 503.2799 503.3996 503.5192 503.6388 503.7584 503.8780 503.9975 504.1171 504.2366 504.3561 504.4756 504.5951 504.7146 504.8340 504.9534 505.0729 505.1922 505.3116 505.4310 505.5503 505.6696 505.7890 505.9082 506.0275 506.1468 506.2660 506.3852 506.5044 506.6236 506.7428 506.8619 506.9811 507.1002 507.2193 507.3384 507.4574 507.5765 507.6955 507.8145 507.9335 508.0525 508.1715 508.2904 508.4093 508.5283 508.6471 508.7660 508.8849 509.0037 509.1225 509.2413 509.3601 509.4789 509.5977 509.7164 509.8351 509.9538 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Columns 99-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-398: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20160515T062134.9Z 5979.264987 285 1 33.73 2 89.61 68.55 134.72 314.05 0.00 1 0.00 1 0 22 5.617e-03 5.555e-03 1.463e-04 1.458e-04 7.367588e+03 9.517615e+00 5.087311e+02 -6.000000e+00 3.144718e+02 278.27 -2.00 20.00 -2.00 505.41 0.00e+00 1.691726e-03 4.045466e-06 9.537450e-05 -6.000000e+00 1.574204e-04 278.27 -2.00 20.00 -2.00 501.05 0.00e+00 1.412286e+00 2.845634e-03 5.952265e-02 -6.000000e+00 1.130711e-01 229.23 -2.00 3.19 -2.00 502.56 0.00e+00 20.260 0.086 489.00 513.00 1 1.6526e+00 2.1754e-04 2.4543e-02 -6.0000e+00 8.6684e-03 -5.0344e-02 5.4554e-05 1.9135e-03 -6.0000e+00 2.2307e-03 3.6663e-02 1.0074e-03 1.5261e-05 7.5714e-05 -6.0000e+00 6.1784e-04 -6.4906e-03 4.2596e-05 12 8 8 10 0 0 -1.65 16.75 1.58 -0.00649 0.00050 709 134 2 2 0 47.420 14.99 16.75 21.48 21.38 -1269 -1008 -474 -120 155 697 938 899 807 514 234 4 -369 -480 -640 -609 -308 189 332 105 249 349 426 659 769 581 545 339 -411 -806 -731 -661 -272 359 308 -9 56 92 -140 -200 -83 53 298 530 588 674 583 370 73 -482 -881 -1155 -1119 -739 -204 -27 147 184 306 425 607 657 610 559 395 168 -81 -144 -415 -728 -651 -543 -275 -24 -89 -508 -710 -692 -734 -857 -747 -673 -657 -372 -242 -315 -242 -236 -101 28 273 710 884 675 536 383 -27 -373 -875 -1263 -1240 -902 -331 -13 -255 -459 -518 -619 -371 -128 54 293 515 757 874 1111 1158 1028 611 487 226 71 395 524 331 325 403 329 431 418 -109 -374 -390 -574 -533 -119 -84 -42 282 418 281 340 502 436 290 -2 -540 -872 -932 -747 -1122 -908 -418 -109 145 663 905 875 785 497 225 4 -347 -449 -599 -575 -295 177 317 102 243 341 418 649 761 577 538 331 -396 -762 -683 -623 -262 355 311 -9 57 93 -141 -200 -84 51 293 526 589 676 582 366 71 -481 -863 -1114 -1076 -719 -203 -27 146 186 308 429 614 668 623 570 400 168 -80 -141 -404 -705 -628 -527 -269 -24 -88 -502 -694 -667 -704 -823 -720 -653 -644 -368 -242 -318 -244 -238 -102 29 279 703 879 670 545 382 -27 -357 -826 -1185 -1172 -872 -331 -12 -260 -471 -528 -628 -376 -131 56 307 545 806 900 1152 1211 1080 641 505 231 75 416 554 340 336 416 340 446 432 -113 -381 -394 -580 -545 -124 -89 -45 309 445 303 369 547 477 317 -2 -580 -924 -1019 -789 SO 20160515T063104.8Z 5979.271583 291 1 33.59 2 87.66 69.65 136.15 316.55 0.00 1 0.00 1 0 22 3.361e-03 3.346e-03 6.369e-05 6.361e-05 4.328612e+03 3.981144e+00 3.074374e+02 -6.000000e+00 1.881822e+02 278.27 -2.00 20.00 -2.00 505.35 0.00e+00 1.080891e-03 1.758495e-06 6.090409e-05 -6.000000e+00 9.420396e-05 278.27 -2.00 20.00 -2.00 500.77 0.00e+00 1.230365e+00 1.257759e-03 3.549798e-02 -6.000000e+00 6.767306e-02 229.23 -2.00 3.19 -2.00 502.33 0.00e+00 15.370 0.037 489.00 513.00 1 6.0269e-01 9.6338e-05 1.7509e-02 -6.0000e+00 5.1879e-03 -1.2801e-02 2.4404e-05 1.2508e-03 -6.0000e+00 1.3353e-03 1.8214e-01 6.9360e-04 6.7489e-06 4.3601e-05 -6.0000e+00 3.6974e-04 6.7445e-03 -4.9372e-05 10 0 0 10 0 0 -10.60 16.76 0.99 0.00674 0.01156 2690 507 2 2 0 12.420 15.00 16.76 21.48 21.38 -632 -496 -228 -116 -34 375 554 521 480 297 209 44 -214 -297 -381 -394 -223 149 141 -92 46 208 256 453 534 348 399 253 -244 -501 -296 -329 -95 328 111 -188 -29 94 -113 -111 -25 23 145 278 373 393 368 268 106 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-172 -350 -318 4 -48 -124 96 223 125 239 353 316 215 -35 -395 -601 -585 -458 SO 20160515T063604.8Z 5979.275056 295 1 33.60 2 86.62 70.23 136.88 317.92 0.00 1 0.00 1 0 22 3.005e-03 2.985e-03 5.084e-05 5.079e-05 3.359976e+03 3.117360e+00 2.404450e+02 -6.000000e+00 1.682322e+02 278.27 -2.00 20.00 -2.00 505.34 0.00e+00 9.259134e-04 1.400946e-06 5.191209e-05 -6.000000e+00 8.421615e-05 278.27 -2.00 20.00 -2.00 500.70 0.00e+00 1.083991e+00 1.005753e-03 2.812981e-02 -6.000000e+00 6.049551e-02 229.23 -2.00 3.19 -2.00 502.26 0.00e+00 12.834 0.022 489.00 513.00 1 4.4891e-01 7.7062e-05 1.4395e-02 -6.0000e+00 4.6377e-03 -7.7085e-03 1.9566e-05 1.0089e-03 -6.0000e+00 1.1936e-03 2.8345e-01 5.8078e-04 5.4017e-06 3.5562e-05 -6.0000e+00 3.3054e-04 3.4736e-03 -2.5763e-05 10 0 0 10 0 0 -10.62 16.76 0.98 0.00347 0.00750 3873 729 2 2 0 8.600 15.00 16.76 21.48 21.38 -532 -441 -223 -142 -85 317 483 451 431 272 184 50 -206 -264 -335 -371 -197 131 105 -104 21 175 227 438 511 312 382 257 -227 -440 -245 -283 -79 315 86 -224 -42 97 -83 -86 -7 38 125 242 335 369 350 248 115 -240 -482 -607 -644 -372 -96 -114 -108 -105 -6 139 288 322 283 303 251 122 29 11 -138 -415 -351 -260 -125 88 19 -295 -392 -252 -259 -410 -348 -377 -404 -127 -42 -179 -165 -87 -52 24 161 428 508 295 266 234 -6 -220 -450 -681 -627 -479 -100 67 -272 -342 -309 -320 -181 0 -3 83 195 310 414 575 666 540 308 230 155 67 295 360 101 180 254 181 328 357 -33 -236 -164 -324 -273 35 -26 -125 81 206 109 218 314 281 191 -38 -352 -541 -520 -410 -494 -417 -217 -137 -85 320 495 448 428 278 185 50 -203 -259 -327 -365 -197 134 106 -106 22 179 233 450 526 322 391 260 -225 -443 -243 -283 -77 319 89 -235 -44 100 -84 -87 -7 39 129 253 339 375 353 256 116 -238 -467 -578 -635 -356 -95 -115 -111 -105 -6 139 288 323 285 304 250 124 29 11 -136 -405 -342 -254 -123 88 19 -293 -383 -243 -248 -393 -336 -366 -396 -125 -42 -180 -161 -84 -50 23 159 426 510 296 264 227 -6 -213 -429 -643 -594 -463 -96 66 -275 -346 -309 -318 -179 0 -3 85 195 313 420 587 682 553 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