File name: Pandora121s1_Izana_20160622_L2Fit_fout2c60d20160420p1-8.txt File generation date: 20260206T161219.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c60p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 121 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora121_OF_v2d20160420.txt Instrument calibration file used: Pandora121s1_CF_v60d20160420.txt Level 1 file used: Pandora121s1_Izana_20160622_L1_smca1c60d20160420p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20160622 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 224 365 Nominal wavelengths inside fitting window [nm]: 305.1371 305.2782 305.4194 305.5605 305.7016 305.8427 305.9838 306.1249 306.2660 306.4071 306.5481 306.6892 306.8302 306.9712 307.1122 307.2532 307.3942 307.5352 307.6762 307.8171 307.9581 308.0990 308.2399 308.3808 308.5217 308.6626 308.8035 308.9444 309.0852 309.2260 309.3669 309.5077 309.6485 309.7893 309.9301 310.0708 310.2116 310.3523 310.4931 310.6338 310.7745 310.9152 311.0559 311.1966 311.3373 311.4779 311.6186 311.7592 311.8998 312.0404 312.1810 312.3216 312.4622 312.6027 312.7433 312.8838 313.0244 313.1649 313.3054 313.4459 313.5864 313.7268 313.8673 314.0077 314.1482 314.2886 314.4290 314.5694 314.7098 314.8502 314.9906 315.1309 315.2713 315.4116 315.5519 315.6922 315.8325 315.9728 316.1131 316.2534 316.3936 316.5339 316.6741 316.8143 316.9545 317.0947 317.2349 317.3751 317.5152 317.6554 317.7955 317.9356 318.0757 318.2158 318.3559 318.4960 318.6361 318.7761 318.9162 319.0562 319.1962 319.3362 319.4762 319.6162 319.7562 319.8962 320.0361 320.1761 320.3160 320.4559 320.5958 320.7357 320.8756 321.0155 321.1553 321.2952 321.4350 321.5748 321.7146 321.8544 321.9942 322.1340 322.2738 322.4135 322.5533 322.6930 322.8327 322.9724 323.1121 323.2518 323.3915 323.5311 323.6708 323.8104 323.9500 324.0896 324.2292 324.3688 324.5084 324.6480 324.7875 324.9271 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature at electronics board 1 [°C], 999=no temperature signal Column 97: Temperature at electronics board 2 [°C], 999=no temperature signal Columns 98-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-381: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20160622T081352.0Z 6017.342963 6 1 34.03 2 65.34 75.54 93.43 251.44 0.00 1 0.00 1 0 17 1.445e-02 6.820e-03 1.032e-03 2.229e-04 3.012678e-01 1.112088e-04 3.253978e-03 -6.000000e+00 8.135367e-03 228.70 -2.00 3.19 -2.00 318.05 0.00e+00 4.064932e-04 1.935694e-05 1.265662e-04 -6.000000e+00 3.552885e-04 281.06 -2.00 20.00 -2.00 317.34 0.00e+00 2.382 0.000 302.00 328.00 3 3.9606e-01 2.9807e-04 2.3025e-02 -6.0000e+00 2.0287e-02 -3.3341e-03 3.3783e-04 1.4110e-02 -6.0000e+00 2.2025e-02 3.5145e-03 2.1774e-04 6.9559e-03 -6.0000e+00 1.3087e-02 -7.8884e-03 1.1264e-04 1.9836e-03 -6.0000e+00 5.6131e-03 3.9713e-02 -8.0181e-05 6.1732e-06 1.9748e-05 -6.0000e+00 3.6771e-04 -2.6251e-03 0.0000e+00 11 8 0 10 0 0 -8.88 16.11 0.16 -0.00263 -0.00323 2090 394 2 8 0 16.050 15.00 16.11 20.96 20.96 -2512 -2156 -3580 -6171 -5728 -3440 -2228 -1041 -1546 -3861 -4766 -2996 -1772 -949 -165 -1005 -345 121 645 1163 -285 571 813 985 1013 1243 315 -448 -228 970 1611 2391 2159 -2073 -2870 -2613 -1860 -454 -560 -3049 -1212 -735 -763 -528 113 -592 -391 -871 -832 437 926 796 1325 942 1012 1379 767 466 251 284 965 1354 2071 1350 -350 -635 -1222 -255 1216 847 1051 809 1071 1078 301 -28 -1063 -992 -537 -1077 -968 -1884 -2323 -1477 -983 -290 -28 453 653 540 482 -285 -224 267 102 240 953 727 19 -233 -1029 -1230 -333 -130 -1203 -774 -948 -590 271 345 460 249 220 -356 -164 64 -115 223 249 -218 -47 500 493 849 847 -115 771 718 458 350 -168 -331 -283 106 142 -238 463 195 -148 -117 -637 -722 -180 -164 -272 -430 -360 -214 -153 -81 -132 -342 -421 -285 -195 -121 -24 -157 -56 20 113 210 -52 103 154 199 217 272 67 -89 -43 187 341 555 543 -524 -679 -642 -522 -152 -226 -1301 -589 -368 -390 -269 57 -300 -194 -426 -405 219 500 461 741 552 607 846 476 284 150 172 618 947 1565 1066 -265 -440 -812 -174 931 729 957 747 957 907 230 -19 -746 -706 -393 -905 -907 -1931 -2310 -1545 -1103 -344 -35 560 786 608 495 -291 -216 267 114 275 1208 1005 26 -309 -1253 -1385 -374 -159 -1589 -1062 -1364 -825 402 548 753 400 331 -493 -227 86 -162 335 373 -337 -72 739 703 1235 1176 -152 994 992 690 521 -260 -521 -463 183 260 -419 828 353 -263 -215 -1124 -1234 SU 20160622T082110.9Z 6017.348043 10 1 33.80 2 63.78 76.22 94.90 252.26 0.00 1 0.00 1 0 17 1.408e-02 6.896e-03 8.332e-04 2.053e-04 2.855487e-01 1.020631e-04 3.095139e-03 -6.000000e+00 7.929144e-03 228.70 -2.00 3.19 -2.00 317.82 0.00e+00 3.294583e-04 1.678659e-05 1.003030e-04 -6.000000e+00 3.462701e-04 281.06 -2.00 20.00 -2.00 317.12 0.00e+00 2.251 0.000 302.00 328.00 3 3.7134e-01 2.7253e-04 2.1789e-02 -6.0000e+00 1.9773e-02 -5.3240e-03 3.0813e-04 1.3376e-02 -6.0000e+00 2.1466e-02 4.1135e-03 1.9446e-04 6.5870e-03 -6.0000e+00 1.2755e-02 -7.6973e-03 9.9700e-05 1.8680e-03 -6.0000e+00 5.4709e-03 4.6027e-02 -6.4211e-05 5.6563e-06 1.8594e-05 -6.0000e+00 3.5838e-04 -2.8801e-03 0.0000e+00 11 8 0 10 0 0 11.63 16.13 0.16 -0.00288 -0.00336 2275 429 2 8 0 14.750 15.00 16.13 20.96 20.96 -2656 -1971 -3509 -6325 -5437 -4123 -1774 -886 -1128 -3510 -3891 -2136 -1670 -362 -240 -769 -356 117 908 1330 9 586 1058 1014 1222 1388 512 31 -136 1459 1549 2661 2017 -1971 -2875 -2639 -1865 -526 -471 -3076 -1114 -700 -687 -637 68 -518 -411 -709 -822 370 920 698 1208 847 923 1253 738 358 205 266 961 1376 2017 1279 -399 -685 -1339 -244 1212 840 1029 794 1122 1036 303 -78 -1100 -1031 -530 -1061 -1000 -1846 -2358 -1480 -1002 -320 -18 454 659 550 516 -321 -162 264 107 251 951 740 29 -216 -1065 -1151 -288 -133 -1161 -796 -941 -611 278 333 472 229 203 -330 -179 102 -124 244 229 -229 -63 446 500 807 834 -101 761 718 489 381 -142 -308 -275 152 112 -233 483 155 -143 -109 -646 -773 -222 -173 -309 -511 -393 -327 -140 -79 -110 -355 -389 -229 -207 -52 -39 -134 -64 22 175 265 2 116 220 226 287 333 119 7 -31 335 355 663 545 -533 -729 -694 -559 -188 -202 -1398 -574 -372 -372 -344 37 -278 -215 -365 -420 194 519 422 768 517 575 798 476 227 128 167 638 996 1576 1042 -311 -488 -913 -170 948 738 956 748 1024 891 237 -55 -787 -747 -393 -902 -948 -1910 -2365 -1562 -1135 -383 -22 567 801 624 580 -330 -157 265 118 287 1202 1019 40 -285 -1293 -1292 -324 -163 -1532 -1091 -1353 -852 411 525 766 364 302 -487 -244 136 -172 361 339 -352 -96 654 762 1162 1147 -132 970 978 726 557 -216 -474 -439 256 199 -402 845 275 -249 -197 -1119 -1298 SU 20160622T082633.8Z 6017.351780 13 1 33.56 2 62.63 76.72 95.98 252.85 0.00 1 0.00 1 0 17 1.346e-02 6.915e-03 7.124e-04 1.942e-04 2.748774e-01 9.662309e-05 2.982367e-03 -6.000000e+00 7.579953e-03 228.70 -2.00 3.19 -2.00 317.67 0.00e+00 3.379220e-04 1.520234e-05 9.319013e-05 -6.000000e+00 3.310148e-04 281.06 -2.00 20.00 -2.00 316.97 0.00e+00 2.164 0.000 302.00 328.00 3 3.5659e-01 2.5719e-04 2.0954e-02 -6.0000e+00 1.8902e-02 -6.0107e-03 2.9033e-04 1.2862e-02 -6.0000e+00 2.0521e-02 4.2421e-03 1.8069e-04 6.3322e-03 -6.0000e+00 1.2193e-02 -7.7004e-03 9.1814e-05 1.7976e-03 -6.0000e+00 5.2301e-03 5.0704e-02 -3.1348e-05 5.3536e-06 1.8016e-05 -6.0000e+00 3.4259e-04 -3.0116e-03 0.0000e+00 11 8 0 10 0 0 4.83 16.13 0.16 -0.00301 -0.00325 2401 452 2 8 0 13.970 14.99 16.13 20.96 20.96 -2710 -1872 -3391 -5942 -5051 -3714 -1539 -298 -808 -3381 -3674 -1798 -1501 -308 -215 -849 -392 377 830 1455 6 603 1133 1035 1300 1382 506 -4 62 1554 1602 2620 2206 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