File name: Pandora209s1_Izana_20221015_L2Fit_fwvt1c9d20220720p1-8.txt File generation date: 20250120T092622.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 209 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora209_OF_v3d20210806.txt Instrument calibration file used: Pandora209s1_CF_v9d20220720.txt Level 1 file used: Pandora209s1_Izana_20221015_L1_smca1c9d20220720p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20221015 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1618 1768 Nominal wavelengths inside fitting window [nm]: 492.0371 492.1581 492.2791 492.4001 492.5211 492.6420 492.7630 492.8839 493.0048 493.1257 493.2466 493.3674 493.4882 493.6091 493.7299 493.8507 493.9714 494.0922 494.2129 494.3336 494.4543 494.5750 494.6957 494.8163 494.9370 495.0576 495.1782 495.2988 495.4193 495.5399 495.6604 495.7809 495.9014 496.0219 496.1424 496.2628 496.3832 496.5036 496.6240 496.7444 496.8648 496.9851 497.1054 497.2257 497.3460 497.4663 497.5866 497.7068 497.8270 497.9472 498.0674 498.1876 498.3077 498.4278 498.5480 498.6681 498.7881 498.9082 499.0282 499.1483 499.2683 499.3883 499.5082 499.6282 499.7481 499.8681 499.9880 500.1079 500.2277 500.3476 500.4674 500.5872 500.7070 500.8268 500.9466 501.0663 501.1861 501.3058 501.4255 501.5452 501.6648 501.7845 501.9041 502.0237 502.1433 502.2629 502.3824 502.5019 502.6215 502.7410 502.8604 502.9799 503.0994 503.2188 503.3382 503.4576 503.5770 503.6963 503.8157 503.9350 504.0543 504.1736 504.2929 504.4121 504.5314 504.6506 504.7698 504.8890 505.0081 505.1273 505.2464 505.3655 505.4846 505.6037 505.7227 505.8418 505.9608 506.0798 506.1988 506.3178 506.4367 506.5556 506.6746 506.7935 506.9123 507.0312 507.1500 507.2689 507.3877 507.5065 507.6252 507.7440 507.8627 507.9814 508.1001 508.2188 508.3375 508.4561 508.5748 508.6934 508.8120 508.9305 509.0491 509.1676 509.2861 509.4046 509.5231 509.6416 509.7600 509.8785 509.9969 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20221015T071256.9Z 8323.300658 186 1 18.16 2 89.45 100.01 27.50 274.31 0.00 1 0.00 1 0 15 7.553e-03 7.456e-03 1.052e-03 1.050e-03 6.832808e+03 6.311720e+01 4.892389e+02 -6.000000e+00 3.908290e+02 278.65 -2.00 20.00 -2.00 505.33 0.00e+00 1.852412e-03 2.810247e-05 1.047456e-04 -6.000000e+00 2.057013e-04 278.65 -2.00 20.00 -2.00 500.76 0.00e+00 1.205494e+00 2.005268e-02 4.999172e-02 -6.000000e+00 1.465901e-01 225.65 -2.00 3.19 -2.00 502.30 0.00e+00 19.965 0.082 489.00 513.00 1 4.7662e+00 1.5266e-03 2.3967e-02 -6.0000e+00 1.1175e-02 -2.5875e-02 4.0015e-04 1.7480e-03 -6.0000e+00 2.9737e-03 1.7021e-03 -9.5745e-04 8.1772e-05 7.1674e-05 -6.0000e+00 6.1534e-04 1.2500e-02 -4.8878e-05 12 9 9 12 1 1 80.30 18.73 1.50 0.01250 0.00586 16 6 1 2 0 952.823 15.01 18.73 9.51 23.00 23.25 19.4 741.02 -2096 -1570 -417 -108 83 1019 900 1337 1085 741 499 275 -347 -197 -579 -1105 -735 155 699 632 457 415 245 637 952 658 872 850 -222 -763 -1398 -1837 -1445 153 359 255 364 64 -103 -249 -235 -164 47 415 786 836 907 725 382 -118 -528 -1263 -1759 -1605 -765 -43 348 618 275 208 297 639 563 1019 833 406 46 -355 -239 -640 -502 -886 -683 -88 277 244 -610 -702 -1036 -1165 -691 -876 -849 -544 -237 -422 -152 -117 -120 -406 -250 522 915 992 1172 914 153 5 -493 -1267 -1575 -1724 -872 129 439 166 -59 -850 -968 -387 -329 -132 598 606 774 778 1110 1235 1065 791 211 136 -35 608 296 605 706 180 403 844 207 110 -390 -1077 -1195 -429 -294 -261 141 496 -10 284 358 656 594 481 118 -698 -1014 -1335 900000 -1902 -1438 -392 -103 79 982 890 1338 1061 737 490 268 -336 -187 -548 -1058 -710 152 690 635 460 419 248 645 972 659 870 845 -224 -741 -1374 -1823 -1413 154 367 264 372 65 -104 -248 -235 -165 48 417 798 855 924 732 381 -119 -517 -1244 -1716 -1570 -746 -43 351 629 281 212 303 654 582 1051 856 414 47 -354 -235 -641 -496 -882 -669 -87 278 245 -604 -681 -1025 -1149 -679 -852 -832 -535 -236 -417 -150 -118 -118 -400 -247 520 930 1015 1177 899 152 5 -466 -1213 -1501 -1627 -846 127 440 169 -59 -851 -957 -383 -332 -133 603 618 792 800 1152 1266 1093 823 217 137 -35 610 302 617 721 181 412 865 208 111 -390 -1076 -1191 -430 -296 -269 144 512 -11 298 370 682 619 501 125 -722 -1029 -1351 900000 SQ 20221015T071805.5Z 8323.304230 192 1 5.94 2 88.34 100.63 28.60 274.74 0.00 1 0.00 1 0 15 6.045e-03 5.974e-03 1.806e-04 1.804e-04 5.390420e+03 1.062123e+01 3.901922e+02 -6.000000e+00 3.128250e+02 278.65 -2.00 20.00 -2.00 505.34 0.00e+00 1.283074e-03 4.808745e-06 7.268754e-05 -6.000000e+00 1.642682e-04 278.65 -2.00 20.00 -2.00 500.75 0.00e+00 1.163907e+00 3.406039e-03 4.008496e-02 -6.000000e+00 1.159445e-01 225.65 -2.00 3.19 -2.00 502.30 0.00e+00 17.232 0.053 489.00 513.00 1 5.3863e-01 2.5977e-04 1.9949e-02 -6.0000e+00 8.8606e-03 -1.8011e-02 6.7276e-05 1.4385e-03 -6.0000e+00 2.3196e-03 1.5890e-01 -2.3517e-04 1.4075e-05 5.3875e-05 -6.0000e+00 4.8971e-04 -4.9300e-04 -2.1049e-06 12 8 8 10 0 0 -24.41 18.72 1.18 -0.00049 -0.00212 546 57 1 2 0 10.530 15.00 18.72 9.38 23.00 23.25 19.5 741.00 -1561 -1213 -423 10 -69 580 800 983 871 474 297 63 -186 -204 -451 -946 -624 76 483 392 386 277 127 512 666 544 628 709 -37 -447 -1064 -1437 -1023 411 522 441 423 145 -161 -302 -152 -158 142 327 550 573 599 488 354 -53 -532 -974 -1503 -1343 -598 -32 257 357 168 52 274 424 533 615 668 353 60 13 -70 -499 -457 -671 -630 58 399 215 -465 -486 -879 -864 -601 -690 -717 -375 -75 -426 -80 -8 -119 -386 -213 203 845 811 780 773 118 -17 -301 -971 -1391 -1570 -710 286 339 214 -134 -766 -810 -428 -209 -32 433 470 537 764 984 1068 832 788 192 33 16 538 200 289 500 168 184 726 362 80 -229 -819 -1032 -238 -160 -131 127 307 46 254 333 468 525 543 179 -510 -830 -1081 -744 -1448 -1137 -393 10 -66 566 799 995 885 477 294 62 -181 -195 -430 -910 -606 76 477 394 388 280 128 518 680 558 642 722 -37 -446 -1043 -1421 -1024 408 543 449 441 149 -165 -306 -154 -162 146 331 563 590 614 495 354 -54 -526 -939 -1485 -1284 -585 -33 259 363 172 53 277 433 549 634 684 358 60 13 -68 -499 -451 -667 -613 57 397 214 -456 -467 -867 -848 -590 -664 -696 -365 -74 -428 -80 -8 -119 -387 -215 200 846 819 776 778 117 -16 -283 -930 -1328 -1472 -684 278 343 219 -136 -771 -803 -425 -212 -32 435 477 549 782 1016 1081 843 812 196 33 16 535 202 293 506 171 186 735 367 80 -225 -804 -1010 -234 -162 -132 130 317 48 259 341 482 543 560 182 -525 -837 -1086 -754 SQ 20221015T071811.7Z 8323.304302 192 2 5.94 2 88.31 100.64 28.62 274.75 0.00 1 0.00 1 0 15 6.044e-03 5.972e-03 1.782e-04 1.779e-04 5.330577e+03 1.050626e+01 3.860630e+02 -6.000000e+00 3.127657e+02 278.65 -2.00 20.00 -2.00 505.34 0.00e+00 1.286464e-03 4.750228e-06 7.293376e-05 -6.000000e+00 1.642387e-04 278.65 -2.00 20.00 -2.00 500.73 0.00e+00 1.160277e+00 3.369587e-03 3.989807e-02 -6.000000e+00 1.159164e-01 225.65 -2.00 3.19 -2.00 502.29 0.00e+00 17.170 0.052 489.00 513.00 1 5.1886e-01 2.5715e-04 1.9865e-02 -6.0000e+00 8.8586e-03 -1.7699e-02 6.6424e-05 1.4316e-03 -6.0000e+00 2.3188e-03 1.6322e-01 -3.3708e-04 1.3884e-05 5.3966e-05 -6.0000e+00 4.8962e-04 -2.2858e-03 1.3845e-05 12 8 8 10 0 0 -12.43 18.72 1.18 -0.00229 -0.00462 546 57 1 2 0 10.530 15.00 18.72 9.38 23.00 23.25 19.5 741.00 -1525 -1216 -433 -9 -58 562 771 995 841 482 323 67 -212 -240 -436 -930 -636 85 482 398 389 279 143 485 713 569 622 707 1 -481 -1067 -1438 -994 379 496 469 459 129 -136 -300 -157 -211 109 284 518 630 600 465 350 -116 -522 -968 -1582 -1343 -559 -30 301 382 181 30 257 438 510 692 657 331 50 -18 -65 -511 -451 -732 -613 71 397 198 -443 -475 -833 -838 -624 -665 -695 -375 -69 -405 -52 -15 -157 -448 -277 221 805 777 791 775 107 -40 -286 -936 -1425 -1534 -743 316 329 218 -137 -788 -826 -451 -207 -3 447 482 550 731 1004 1098 799 783 186 22 38 532 170 354 527 168 169 668 350 102 -178 -781 -1071 -257 -130 -120 108 309 28 268 351 455 509 504 205 -530 -794 -1081 -761 -1432 -1111 -408 -8 -57 556 780 985 835 474 324 67 -209 -232 -420 -906 -625 83 482 406 396 285 147 497 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