File name: Pandora209s1_Izana_20221224_L2Fit_fout2c4d20221111p1-8.txt File generation date: 20250124T150216.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 209 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora209_OF_v3d20210806.txt Instrument calibration file used: Pandora209s1_CF_v4d20221111.txt Level 1 file used: Pandora209s1_Izana_20221224_L1_smca1c4d20221111p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20221224 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0169 305.1580 305.2990 305.4401 305.5811 305.7221 305.8631 306.0041 306.1451 306.2861 306.4270 306.5680 306.7089 306.8499 306.9908 307.1317 307.2726 307.4135 307.5543 307.6952 307.8360 307.9769 308.1177 308.2585 308.3993 308.5401 308.6809 308.8216 308.9624 309.1031 309.2439 309.3846 309.5253 309.6660 309.8067 309.9474 310.0880 310.2287 310.3693 310.5099 310.6506 310.7912 310.9318 311.0723 311.2129 311.3535 311.4940 311.6346 311.7751 311.9156 312.0561 312.1966 312.3371 312.4775 312.6180 312.7584 312.8989 313.0393 313.1797 313.3201 313.4605 313.6008 313.7412 313.8816 314.0219 314.1622 314.3025 314.4428 314.5831 314.7234 314.8637 315.0039 315.1442 315.2844 315.4246 315.5649 315.7051 315.8452 315.9854 316.1256 316.2657 316.4059 316.5460 316.6861 316.8262 316.9663 317.1064 317.2465 317.3865 317.5266 317.6666 317.8066 317.9466 318.0866 318.2266 318.3666 318.5066 318.6465 318.7865 318.9264 319.0663 319.2062 319.3461 319.4860 319.6259 319.7657 319.9056 320.0454 320.1852 320.3251 320.4649 320.6046 320.7444 320.8842 321.0239 321.1637 321.3034 321.4431 321.5828 321.7225 321.8622 322.0019 322.1416 322.2812 322.4208 322.5605 322.7001 322.8397 322.9793 323.1188 323.2584 323.3980 323.5375 323.6770 323.8165 323.9561 324.0955 324.2350 324.3745 324.5140 324.6534 324.7928 324.9323 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given 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2224 2359 3635 2227 1205 960 1277 446 2822 1056 4281 2094 2700 2748 4813 -130 3900 6639 4358 3005 1228 3429 1600 2257 -176 -2750 1164 -461 -2381 -1455 447 1556 1291 -594 4152 1162 1613 -188 -1678 -2329 -878 -4103 -56 -2618 -1956 -66 834 -387 -2474 -3234 -2873 -1693 -5757 -528 -3789 -6941 427 -457 3245 -821 -1094 -2595 -1472 -2057 -2005 143 2170 2179 4237 6659 2201 5354 4166 -3389 -1066 1484 -2134 4142 2041 -283 -2106 1794 1315 730 -1274 1975 -1626 -3255 -585 -2952 SS 20221224T083143.7Z 8393.355366 45 1 54.33 2 83.78 120.85 98.13 116.97 0.00 1 0.00 1 0 25 6.361e-01 9.202e-03 2.564e-01 3.719e-03 7.655844e-01 1.951047e-03 7.689317e-03 -6.000000e+00 3.343921e-01 223.10 -2.00 3.19 -2.00 321.65 0.00e+00 2.926459e-03 9.675451e-04 1.685517e-03 -6.000000e+00 1.526095e-02 273.55 -2.00 20.00 -2.00 321.22 0.00e+00 8.345 0.006 302.00 328.00 3 3.2385e-01 6.6686e-03 7.2792e-02 -6.0000e+00 8.2674e-01 1.6351e-01 1.0781e-02 3.8922e-02 -6.0000e+00 9.0362e-01 -2.1578e-01 1.2994e-02 2.3556e-02 -6.0000e+00 5.3750e-01 7.9243e-02 6.0357e-03 9.2167e-03 -6.0000e+00 2.3611e-01 3.4967e-04 -4.2430e-04 8.4610e-05 7.6322e-05 -6.0000e+00 1.3274e-02 -8.0326e-04 0.0000e+00 11 8 0 10 0 0 -21.24 18.82 0.68 -0.00080 -0.00399 374 39 1 8 0 144.909 15.00 18.82 13.43 23.25 23.50 20.0 738.86 -182273 900000 -88345 -83526 -256141 -286609 -249816 -212622 -178352 -208873 -198016 900000 -203764 33270 -116354 -89139 -107218 -75000 -97067 -57979 -71804 -66909 -14341 -64437 -11182 -4677 5840 -1594 19760 -80881 -64000 -19573 33951 -1506 -29359 -149 -19365 -8958 -26689 1588 259 22036 -3163 3059 -7529 2347 -7374 -7618 -246 1158 6459 3562 5137 8378 7527 2186 3535 4286 3341 5056 3744 7743 7650 2163 8041 2795 7179 -1735 -101 1675 3751 1456 2270 1894 3078 -325 -2849 -3239 -2504 -1081 -2189 234 -1188 -1593 -800 -684 335 386 434 1481 -257 478 -575 -2312 -848 -776 -488 534 876 659 483 -776 -1206 -1997 -111 -2000 -1288 -858 -1124 303 313 791 -68 276 26 -1063 186 -331 143 94 477 315 1099 755 964 1216 -893 -239 -35 23 453 -373 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-6.000000e+00 1.034509e-02 273.55 -2.00 20.00 -2.00 320.80 0.00e+00 7.239 0.004 302.00 328.00 3 2.9745e-01 3.3723e-03 6.3248e-02 -6.0000e+00 5.9025e-01 5.1696e-02 5.0542e-03 3.3471e-02 -6.0000e+00 6.4512e-01 -5.8524e-02 5.9642e-03 1.9324e-02 -6.0000e+00 3.8326e-01 1.1203e-02 2.8502e-03 7.2375e-03 -6.0000e+00 1.6678e-01 8.6287e-04 2.5311e-05 4.7078e-05 5.9055e-05 -6.0000e+00 9.4551e-03 -1.0346e-03 0.0000e+00 11 8 0 10 0 0 -25.71 18.83 0.67 -0.00103 -0.00084 601 63 1 8 0 89.935 15.00 18.83 13.73 23.25 23.25 20.2 740.32 -154757 -77052 -205764 -117577 -177066 -163733 -139443 -88112 -180600 -109197 -129387 -100336 -91364 -72556 -74190 -65870 -53049 3121 -33075 -25201 -42988 -40027 -30263 -21022 -21630 -6883 -18945 -18335 -27131 -17322 -32330 -21690 -9982 -5992 -13863 -15733 -12230 -10470 -13323 -8484 -1272 69 -3658 2310 880 473 -414 1231 -2696 -358 673 2754 1427 1523 3001 1733 1993 3531 413 -68 1426 1571 4262 2448 3336 469 1240 -482 1082 1287 2035 1855 1255 1412 1237 -911 -2023 -3633 -1609 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