File name: Pandora91s1_Kigali_20250515_L2Fit_fout2c2d20250101p1-8.txt File generation date: 20250828T081718.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 91 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora91_OF_v1d20241022.txt Instrument calibration file used: Pandora91s1_CF_v2d20250101.txt Level 1 file used: Pandora91s1_Kigali_20250515_L1_smca1c2d20250101p1-8.txt Full location name: US Embassy of Rwanda Short location name: Kigali Country of location: Rwanda Location latitude [deg]: -1.9363 Location longitude [deg]: 30.0779 Location altitude [m]: 1495 Local noon date: 20250515 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 194 336 Nominal wavelengths inside fitting window [nm]: 305.0653 305.2061 305.3469 305.4877 305.6285 305.7693 305.9101 306.0508 306.1916 306.3323 306.4730 306.6138 306.7545 306.8951 307.0358 307.1765 307.3172 307.4578 307.5984 307.7391 307.8797 308.0203 308.1609 308.3014 308.4420 308.5826 308.7231 308.8636 309.0042 309.1447 309.2852 309.4257 309.5661 309.7066 309.8471 309.9875 310.1279 310.2684 310.4088 310.5492 310.6896 310.8299 310.9703 311.1107 311.2510 311.3913 311.5317 311.6720 311.8123 311.9526 312.0928 312.2331 312.3733 312.5136 312.6538 312.7940 312.9342 313.0744 313.2146 313.3548 313.4950 313.6351 313.7753 313.9154 314.0555 314.1956 314.3357 314.4758 314.6159 314.7559 314.8960 315.0360 315.1760 315.3160 315.4560 315.5960 315.7360 315.8760 316.0159 316.1559 316.2958 316.4358 316.5757 316.7156 316.8555 316.9953 317.1352 317.2751 317.4149 317.5547 317.6946 317.8344 317.9742 318.1140 318.2537 318.3935 318.5332 318.6730 318.8127 318.9524 319.0921 319.2318 319.3715 319.5112 319.6509 319.7905 319.9301 320.0698 320.2094 320.3490 320.4886 320.6282 320.7677 320.9073 321.0468 321.1864 321.3259 321.4654 321.6049 321.7444 321.8839 322.0233 322.1628 322.3022 322.4417 322.5811 322.7205 322.8599 322.9993 323.1387 323.2780 323.4174 323.5567 323.6960 323.8353 323.9747 324.1139 324.2532 324.3925 324.5318 324.6710 324.8102 324.9495 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20250515T112148.1Z 9266.473473 7 1 28.78 2 29.69 315.77 148.30 198.49 0.00 1 0.00 1 0 17 1.358e-02 1.055e-02 7.351e-03 4.812e-03 1.338208e-01 2.418367e-03 1.416240e-03 -6.000000e+00 7.633779e-03 227.02 -2.00 3.05 -2.00 315.16 0.00e+00 8.349281e-04 2.172091e-04 5.209823e-05 -6.000000e+00 3.430672e-04 286.28 -2.00 20.00 -2.00 314.50 0.00e+00 1.151 0.000 302.00 328.00 3 6.7372e+00 6.2049e-03 1.1280e-02 -6.0000e+00 1.8918e-02 4.3238e-02 6.9070e-03 5.9816e-03 -6.0000e+00 2.0544e-02 8.9918e-03 3.9514e-03 2.8839e-03 -6.0000e+00 1.2269e-02 -1.0954e-02 1.7683e-03 9.0731e-04 -6.0000e+00 5.2622e-03 2.1667e-04 2.0318e-04 1.3213e-04 9.9115e-06 -6.0000e+00 3.5202e-04 -9.0638e-03 0.0000e+00 12 8 8 10 0 0 99.97 25.92 0.90 -0.00906 -0.00754 11 11 1 5 0 2616.000 34.00 20.11 25.92 32.16 0.0 1002.90 1619 -1045 1167 -1805 -4229 -2976 472 -2685 -83 -459 -2563 -411 -1181 -775 2575 1826 -227 1867 1976 1020 -958 611 270 -556 695 -46 -102 -2298 -337 -775 1810 3025 3277 -477 -3039 -3018 -3667 -938 -291 155 289 556 505 465 -266 -1157 -660 675 -1813 -1199 -142 99 1168 909 867 868 1200 118 161 103 1279 919 2132 2830 924 -36 -2156 -1031 -593 907 901 678 738 1286 357 -551 -1452 -2246 -3361 -2409 -1592 -1784 -2422 -1385 -1267 228 138 707 1159 1523 291 -488 -922 -959 -1261 -769 -332 1476 1006 -60 57 -1729 -1579 -939 -497 -834 -333 -697 166 989 1100 1498 1131 530 -1098 -1327 -1045 -489 246 554 474 470 523 570 1049 -736 330 118 54 -425 -214 14 -126 -180 37 -70 137 912 669 132 -333 -1072 -1155 517 -366 403 -591 -1222 -800 128 -829 -27 -160 -872 -135 -424 -307 1094 841 -108 879 952 509 -494 303 136 -294 373 -26 -56 -1207 -157 -349 818 1401 1607 -248 -1478 -1410 -1883 -537 -197 110 222 438 408 378 -215 -939 -517 498 -1443 -925 -113 75 912 742 723 728 1017 101 134 85 1080 831 2042 2834 926 -33 -1817 -898 -534 829 902 710 775 1302 342 -524 -1244 -1792 -2754 -2173 -1436 -1765 -2555 -1499 -1468 281 179 944 1554 1959 348 -533 -909 -975 -1332 -800 -377 1818 1316 -77 69 -1975 -1697 -1040 -603 -1069 -443 -970 237 1468 1559 2306 1663 721 -1375 -1543 -1202 -583 314 762 675 665 726 755 1301 -885 369 131 62 -524 -274 18 -164 -242 53 -106 210 1431 1065 207 -508 -1603 -1687 SU 20250515T112842.2Z 9266.478266 16 1 29.97 2 30.92 313.64 148.78 195.88 0.00 1 0.00 1 0 17 9.430e-03 7.837e-03 7.091e-04 5.675e-04 1.358719e-01 2.883264e-04 1.446262e-03 -6.000000e+00 5.300593e-03 227.02 -2.00 3.05 -2.00 314.02 0.00e+00 4.785626e-04 2.121822e-05 1.710351e-05 -6.000000e+00 2.382487e-04 286.28 -2.00 20.00 -2.00 313.49 0.00e+00 1.165 0.000 302.00 328.00 3 3.2905e+00 7.3155e-04 1.1438e-02 -6.0000e+00 1.3136e-02 1.6757e-02 8.1086e-04 6.0550e-03 -6.0000e+00 1.4266e-02 4.8274e-04 4.6671e-04 2.9468e-03 -6.0000e+00 8.5196e-03 -4.4775e-03 2.0313e-04 8.5330e-04 -6.0000e+00 3.6535e-03 6.7762e-03 7.8950e-05 1.5230e-05 1.0881e-05 -6.0000e+00 2.4447e-04 -8.1838e-03 0.0000e+00 11 8 0 10 0 0 99.87 25.85 0.43 -0.00818 -0.00759 144 144 1 5 0 208.070 33.50 20.03 25.85 32.73 0.0 1005.40 173 324 -459 -2154 -2618 -1849 -166 544 927 -452 -1657 -1129 -452 169 886 557 574 853 1237 1649 941 876 1272 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463 144 -410 -1023 -1191 -632 -1079 -1051 -794 -374 81 794 1121 1222 875 501 -143 -323 -366 -107 170 547 193 528 708 708 833 121 12 310 241 60 62 -78 -414 -182 -225 8 292 542 366 126 -527 -895 -1219 SU 20250515T113054.9Z 9266.479802 19 1 30.01 2 31.32 312.99 148.92 195.03 0.00 1 0.00 1 0 17 9.545e-03 7.767e-03 4.827e-04 3.679e-04 1.364204e-01 1.865085e-04 1.445587e-03 -6.000000e+00 5.365479e-03 227.02 -2.00 3.05 -2.00 314.31 0.00e+00 4.424761e-04 1.440751e-05 2.780193e-05 -6.000000e+00 2.411546e-04 286.28 -2.00 20.00 -2.00 313.75 0.00e+00 1.170 0.000 302.00 328.00 3 2.3355e+00 4.7465e-04 1.1476e-02 -6.0000e+00 1.3296e-02 1.1567e-02 5.2630e-04 6.0518e-03 -6.0000e+00 1.4440e-02 6.9031e-04 3.0205e-04 2.9508e-03 -6.0000e+00 8.6238e-03 -4.8579e-03 1.3256e-04 8.4719e-04 -6.0000e+00 3.6983e-03 1.7550e-02 8.9613e-05 9.9670e-06 1.0714e-05 -6.0000e+00 2.4745e-04 -8.4386e-03 0.0000e+00 11 8 0 10 0 0 99.99 25.88 0.44 -0.00844 -0.00777 1065 1065 1 5 0 28.170 34.00 20.01 25.88 32.93 0.0 1006.67 97 -44 -39 -2286 -2830 -1887 -510 784 772 -469 -1713 -1215 -416 80 836 595 456 669 1131 1560 953 773 1419 1201 678 728 102 -513 -1054 23 753 867 1220 -1009 -3135 -2888 -2467 -1311 -311 -94 -571 -519 -447 -540 -144 -316 -479 -580 -1086 -293 529 530 1112 1039 880 973 742 511 326 447 911 1256 1867 1912 585 -191 -690 -933 162 386 577 529 438 647 105 -515 -1268 -1909 -1613 -1523 -1499 -1592 -1990 -1441 -821 -401 -30 551 905 718 542 134 -366 -591 -397 -302 343 953 512 110 -332 -821 -1124 -528 -819 -932 -680 -341 100 608 920 866 764 372 -204 -305 -350 -135 114 417 158 348 569 476 648 60 39 215 121 42 -27 -80 -389 -64 -150 48 254 356 304 8 -297 -652 -939 40 -20 -17 -970 -1040 -647 -181 303 330 -212 -751 -522 -193 37 432 332 257 381 656 925 576 458 843 747 407 449 63 -318 -597 13 413 493 734 -634 -1835 -1622 -1507 -842 -220 -77 -479 -447 -395 -479 -126 -275 -404 -500 -900 -235 437 435 943 921 799 888 689 473 296 403 842 1235 1842 1987 606 -179 -628 -809 144 367 600 575 478 684 104 -491 -1161 -1626 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