File name: Pandora91s1_Kigali_20250725_L2Fit_fout2c2d20250101p1-8.txt File generation date: 20250828T082941.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 91 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora91_OF_v1d20241022.txt Instrument calibration file used: Pandora91s1_CF_v2d20250101.txt Level 1 file used: Pandora91s1_Kigali_20250725_L1_smca1c2d20250101p1-8.txt Full location name: US Embassy of Rwanda Short location name: Kigali Country of location: Rwanda Location latitude [deg]: -1.9363 Location longitude [deg]: 30.0779 Location altitude [m]: 1495 Local noon date: 20250725 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 194 336 Nominal wavelengths inside fitting window [nm]: 305.0653 305.2061 305.3469 305.4877 305.6285 305.7693 305.9101 306.0508 306.1916 306.3323 306.4730 306.6138 306.7545 306.8951 307.0358 307.1765 307.3172 307.4578 307.5984 307.7391 307.8797 308.0203 308.1609 308.3014 308.4420 308.5826 308.7231 308.8636 309.0042 309.1447 309.2852 309.4257 309.5661 309.7066 309.8471 309.9875 310.1279 310.2684 310.4088 310.5492 310.6896 310.8299 310.9703 311.1107 311.2510 311.3913 311.5317 311.6720 311.8123 311.9526 312.0928 312.2331 312.3733 312.5136 312.6538 312.7940 312.9342 313.0744 313.2146 313.3548 313.4950 313.6351 313.7753 313.9154 314.0555 314.1956 314.3357 314.4758 314.6159 314.7559 314.8960 315.0360 315.1760 315.3160 315.4560 315.5960 315.7360 315.8760 316.0159 316.1559 316.2958 316.4358 316.5757 316.7156 316.8555 316.9953 317.1352 317.2751 317.4149 317.5547 317.6946 317.8344 317.9742 318.1140 318.2537 318.3935 318.5332 318.6730 318.8127 318.9524 319.0921 319.2318 319.3715 319.5112 319.6509 319.7905 319.9301 320.0698 320.2094 320.3490 320.4886 320.6282 320.7677 320.9073 321.0468 321.1864 321.3259 321.4654 321.6049 321.7444 321.8839 322.0233 322.1628 322.3022 322.4417 322.5811 322.7205 322.8599 322.9993 323.1387 323.2780 323.4174 323.5567 323.6960 323.8353 323.9747 324.1139 324.2532 324.3925 324.5318 324.6710 324.8102 324.9495 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250725T080740.9Z 9337.338667 163 1 30.12 2 36.19 52.14 44.07 56.04 0.00 1 0.00 1 0 17 9.600e-03 7.661e-03 1.145e-03 8.440e-04 1.476363e-01 4.275460e-04 1.564917e-03 -6.000000e+00 5.394350e-03 226.93 -2.00 3.05 -2.00 314.54 0.00e+00 4.869693e-04 3.407801e-05 2.519288e-05 -6.000000e+00 2.415314e-04 285.31 -2.00 20.00 -2.00 313.95 0.00e+00 1.238 0.000 302.00 328.00 3 3.9458e+00 1.0896e-03 1.2230e-02 -6.0000e+00 1.3370e-02 -7.8569e-03 1.2100e-03 6.5531e-03 -6.0000e+00 1.4523e-02 5.6116e-04 6.9534e-04 3.2004e-03 -6.0000e+00 8.6686e-03 -5.3795e-03 3.0585e-04 9.2649e-04 -6.0000e+00 3.7152e-03 3.2532e-03 -5.6478e-05 2.2806e-05 1.1551e-05 -6.0000e+00 2.4884e-04 -9.1847e-03 0.0000e+00 11 8 0 10 0 0 99.99 26.15 0.39 -0.00918 -0.00961 87 87 1 5 0 346.110 34.50 20.00 26.15 34.46 0.0 1007.48 219 242 -133 -2011 -3057 -2161 -756 603 703 -60 -1768 -1240 -490 -45 902 641 855 749 1239 1650 767 811 1380 1300 361 423 397 -638 -1083 18 702 812 1176 -856 -3023 -2956 -2474 -1136 -369 -118 -710 -329 -350 -680 -205 -99 -416 -688 -817 -388 502 577 992 1007 842 1016 668 579 454 408 938 1221 1838 1934 611 -165 -735 -830 49 529 642 642 359 544 89 -590 -1280 -2107 -1833 -1495 -1400 -1602 -1899 -1439 -740 -302 6 576 1005 764 678 177 -327 -728 -408 -321 388 983 514 97 -352 -862 -1084 -504 -813 -807 -702 -381 86 543 890 723 820 368 -203 -346 -433 -53 135 287 144 388 540 383 576 73 91 347 201 43 -46 -91 -425 -145 -95 98 264 391 258 53 -304 -628 -871 87 95 -53 -817 -1083 -715 -258 225 290 -24 -753 -517 -204 -21 458 327 441 392 663 903 430 445 761 750 218 263 246 -371 -575 10 391 436 671 -510 -1684 -1703 -1438 -747 -268 -94 -578 -275 -300 -588 -175 -84 -343 -579 -661 -306 408 496 833 884 759 921 617 533 410 366 862 1129 1815 1910 636 -156 -674 -726 44 507 677 670 378 553 90 -571 -1114 -1819 -1605 -1368 -1344 -1692 -2023 -1583 -825 -361 7 711 1247 916 787 198 -348 -731 -424 -344 454 1203 637 119 -425 -1022 -1213 -581 -983 -981 -888 -503 112 739 1260 1029 1112 485 -256 -405 -503 -64 167 384 191 533 728 496 735 90 110 413 241 54 -58 -118 -552 -193 -129 140 385 559 375 76 -441 -888 -1205 SS 20250725T081916.3Z 9337.346717 169 1 30.45 2 33.94 49.44 41.73 54.23 0.00 1 0.00 1 0 17 9.766e-03 7.820e-03 1.745e-03 1.274e-03 1.436441e-01 6.439719e-04 1.533446e-03 -6.000000e+00 5.487789e-03 226.93 -2.00 3.05 -2.00 314.59 0.00e+00 4.525107e-04 5.185147e-05 3.994039e-05 -6.000000e+00 2.457036e-04 285.31 -2.00 20.00 -2.00 314.00 0.00e+00 1.205 0.000 302.00 328.00 3 4.7612e+00 1.6436e-03 1.1907e-02 -6.0000e+00 1.3601e-02 -4.4419e-03 1.8254e-03 6.3869e-03 -6.0000e+00 1.4774e-02 8.1599e-04 1.0475e-03 3.1218e-03 -6.0000e+00 8.8187e-03 -5.7960e-03 4.6179e-04 8.9089e-04 -6.0000e+00 3.7797e-03 1.4909e-03 -5.5209e-05 3.4481e-05 1.1413e-05 -6.0000e+00 2.5314e-04 -9.4486e-03 0.0000e+00 11 8 0 10 0 0 99.91 26.20 0.39 -0.00945 -0.00986 21 21 1 5 0 1449.780 34.50 20.00 26.20 34.25 0.0 1007.11 568 352 -330 -2134 -2660 -2529 -436 114 1972 196 -1532 -1631 -916 110 626 570 414 870 1462 1039 1163 847 1337 737 593 615 -45 -652 -718 38 1090 738 1069 -966 -2884 -2904 -2662 -961 -386 -91 -606 -392 -38 -610 -439 -171 -314 -409 -1179 -684 114 551 1051 919 803 962 901 168 236 331 745 1239 1864 2009 863 -76 -908 -811 245 492 672 674 393 727 161 -698 -1289 -2119 -1528 -1209 -1593 -1423 -2057 -1606 -935 -207 11 593 817 776 828 331 -360 -683 -169 -92 548 995 617 205 -338 -1091 -1345 -819 -776 -1118 -734 -475 276 605 930 909 703 400 -142 -483 -239 -379 278 369 250 288 553 379 625 67 -134 305 130 6 -92 -80 -391 -32 -134 128 242 258 222 13 -379 -475 -656 212 141 -135 -817 -962 -861 -152 40 754 80 -610 -640 -388 51 297 292 215 456 781 573 650 465 737 427 356 381 -28 -379 -379 21 558 394 605 -572 -1591 -1540 -1536 -625 -276 -71 -513 -341 -32 -515 -366 -151 -269 -336 -935 -528 91 462 913 784 701 846 804 151 207 288 665 1175 1887 2017 863 -74 -805 -729 226 482 679 713 419 749 167 -652 -1154 -1769 -1289 -1130 -1559 -1436 -2217 -1788 -1048 -248 13 730 1014 930 963 372 -366 -696 -177 -100 645 1216 760 262 -408 -1232 -1517 -952 -938 -1431 -925 -623 373 812 1301 1275 942 523 -178 -564 -277 -457 359 488 344 393 740 486 794 82 -163 365 156 7 -121 -102 -501 -42 -187 180 346 381 331 19 -541 -660 -938 SS 20250725T082433.6Z 9337.350388 172 1 30.10 2 32.95 48.07 40.68 53.33 0.00 1 0.00 1 0 17 9.761e-03 7.841e-03 1.109e-03 8.302e-04 1.419203e-01 4.204753e-04 1.505654e-03 -6.000000e+00 5.485348e-03 226.93 -2.00 3.05 -2.00 314.45 0.00e+00 4.656191e-04 3.305395e-05 3.008382e-05 -6.000000e+00 2.455909e-04 285.31 -2.00 20.00 -2.00 313.87 0.00e+00 1.191 0.000 302.00 328.00 3 3.9585e+00 1.0711e-03 1.1760e-02 -6.0000e+00 1.3595e-02 -4.3549e-03 1.1890e-03 6.2957e-03 -6.0000e+00 1.4767e-02 1.8393e-04 6.8259e-04 3.0731e-03 -6.0000e+00 8.8147e-03 -5.1979e-03 2.9977e-04 8.8327e-04 -6.0000e+00 3.7781e-03 3.3779e-03 -2.7333e-05 2.2489e-05 1.1316e-05 -6.0000e+00 2.5302e-04 -9.5256e-03 0.0000e+00 11 8 0 10 0 0 99.91 26.21 0.43 -0.00953 -0.00973 100 100 1 5 0 300.900 34.50 20.00 26.21 34.18 0.0 1006.03 283 159 -60 -2265 -3106 -1815 -148 504 981 -401 -1657 -1267 -355 -224 977 980 296 819 1202 1600 792 632 1252 1156 785 827 401 -737 -1137 256 625 856 1255 -877 -3240 -2981 -2600 -1273 -341 -65 -438 -769 -426 -596 -284 -248 -406 -588 -931 -187 526 452 1079 927 882 1005 740 514 217 310 976 1322 1885 1929 898 -205 -781 -830 49 552 684 507 369 587 213 -618 -1240 -2062 -1775 -1621 -1540 -1400 -1899 -1413 -906 -371 -18 582 913 815 573 260 -557 -601 -565 -325 368 1049 497 144 -228 -823 -1203 -558 -938 -901 -638 -311 92 571 871 816 811 292 -219 -411 -239 -74 82 300 257 469 565 356 757 154 -94 148 56 154 -67 -84 -410 -80 -90 153 258 379 262 48 -340 -622 -853 117 65 -25 -954 -1138 -618 -52 194 416 -166 -725 -544 -152 -106 506 508 157 436 654 890 451 353 701 677 477 518 251 -434 -657 140 351 498 718 -525 -1814 -1722 -1516 -840 -248 -52 -355 -645 -366 -515 -242 -210 -355 -492 -751 -146 424 386 954 808 786 901 676 469 194 276 887 1278 1838 1984 920 -202 -705 -758 43 551 708 548 381 619 211 -587 -1126 -1745 -1521 -1453 -1532 -1441 -2086 -1518 -1039 -434 -22 736 1163 1002 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