File name: Pandora91s1_Kigali_20260623_L2Fit_fout2c2d20250101p1-8.txt File generation date: 20260623T220710.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tador Tekeste Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 91 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora91_OF_v3d20241022.txt Instrument calibration file used: Pandora91s1_CF_v2d20250101.txt Level 1 file used: Pandora91s1_Kigali_20260623_L1_smca1c2d20250101p1-8.txt Full location name: US Embassy of Rwanda Short location name: Kigali Country of location: Rwanda Location latitude [deg]: -1.9363 Location longitude [deg]: 30.0779 Location altitude [m]: 1495 Local noon date: 20260623 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 194 336 Nominal wavelengths inside fitting window [nm]: 305.0653 305.2061 305.3469 305.4877 305.6285 305.7693 305.9101 306.0508 306.1916 306.3323 306.4730 306.6138 306.7545 306.8951 307.0358 307.1765 307.3172 307.4578 307.5984 307.7391 307.8797 308.0203 308.1609 308.3014 308.4420 308.5826 308.7231 308.8636 309.0042 309.1447 309.2852 309.4257 309.5661 309.7066 309.8471 309.9875 310.1279 310.2684 310.4088 310.5492 310.6896 310.8299 310.9703 311.1107 311.2510 311.3913 311.5317 311.6720 311.8123 311.9526 312.0928 312.2331 312.3733 312.5136 312.6538 312.7940 312.9342 313.0744 313.2146 313.3548 313.4950 313.6351 313.7753 313.9154 314.0555 314.1956 314.3357 314.4758 314.6159 314.7559 314.8960 315.0360 315.1760 315.3160 315.4560 315.5960 315.7360 315.8760 316.0159 316.1559 316.2958 316.4358 316.5757 316.7156 316.8555 316.9953 317.1352 317.2751 317.4149 317.5547 317.6946 317.8344 317.9742 318.1140 318.2537 318.3935 318.5332 318.6730 318.8127 318.9524 319.0921 319.2318 319.3715 319.5112 319.6509 319.7905 319.9301 320.0698 320.2094 320.3490 320.4886 320.6282 320.7677 320.9073 321.0468 321.1864 321.3259 321.4654 321.6049 321.7444 321.8839 322.0233 322.1628 322.3022 322.4417 322.5811 322.7205 322.8599 322.9993 323.1387 323.2780 323.4174 323.5567 323.6960 323.8353 323.9747 324.1139 324.2532 324.3925 324.5318 324.6710 324.8102 324.9495 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20260623T060812.6Z 9670.255702 666 1 12.48 2 62.18 62.12 157.92 123.18 0.00 1 0.00 1 0 17 1.190e-02 7.669e-03 3.527e-03 1.673e-03 2.563161e-01 8.354882e-04 2.685701e-03 -6.000000e+00 6.675182e-03 226.87 -2.00 3.05 -2.00 316.31 0.00e+00 7.910470e-04 9.626256e-05 1.121838e-04 -6.000000e+00 2.999302e-04 285.74 -2.00 20.00 -2.00 315.57 0.00e+00 2.132 0.000 302.00 328.00 3 3.5363e+00 2.1677e-03 2.1111e-02 -6.0000e+00 1.6539e-02 -4.6785e-02 2.4301e-03 1.1358e-02 -6.0000e+00 1.7975e-02 5.3794e-03 1.4096e-03 5.5704e-03 -6.0000e+00 1.0732e-02 -5.6130e-03 6.6528e-04 1.6208e-03 -6.0000e+00 4.5936e-03 1.9472e-03 3.4571e-04 4.5749e-05 1.7872e-05 -6.0000e+00 3.0865e-04 2.8416e-03 0.0000e+00 12 9 1 12 1 1 99.66 24.95 0.34 0.00284 0.00544 17 8 1 5 0 693.020 33.50 20.01 24.95 29.00 0.0 979.08 -1661 327 -397 -4090 -3650 -2118 -1631 -2888 -713 -118 -3204 -1696 -552 -22 1058 1056 228 1686 2522 1799 -47 257 1808 1284 1197 546 339 -822 -1820 -834 475 859 1151 -1135 -3683 -3371 -2839 -1592 -737 130 -310 77 -368 -429 176 266 -396 -305 -873 -322 700 581 1049 1202 922 411 961 218 274 411 789 1153 2197 2329 855 -231 -562 -886 526 763 844 813 323 467 191 -779 -1682 -1885 -1991 -1690 -1302 -1484 -1762 -1434 -692 -431 50 776 1053 809 481 32 -522 -508 -424 -143 141 915 449 -71 -517 -1268 -1442 -715 -839 -934 -492 -174 186 492 1173 829 541 325 -377 -347 -240 41 23 434 24 355 600 449 486 11 102 465 161 283 109 22 -265 -100 101 -96 243 330 134 -113 -273 -489 -959 -314 61 -76 -753 -640 -354 -291 -583 -144 -25 -682 -366 -134 -6 307 338 77 579 896 620 -17 90 641 486 474 227 141 -323 -668 -302 182 353 481 -499 -1634 -1466 -1269 -817 -424 82 -202 52 -243 -287 123 186 -273 -205 -579 -213 489 413 782 899 713 325 771 175 215 321 636 951 1954 2112 780 -204 -464 -751 446 706 817 820 326 453 181 -697 -1443 -1540 -1714 -1497 -1234 -1495 -1898 -1542 -765 -510 60 951 1294 956 545 35 -540 -531 -452 -162 171 1134 592 -91 -653 -1545 -1653 -847 -1052 -1189 -653 -233 253 711 1723 1235 775 448 -496 -444 -306 55 32 622 35 511 844 625 664 14 131 601 217 392 155 32 -393 -150 156 -151 390 542 216 -183 -427 -762 -1468 SU 20260623T062215.8Z 9670.265461 735 1 6.87 2 59.09 61.06 155.01 119.19 0.00 1 0.00 1 0 25 1.441e-02 9.156e-03 1.129e-02 5.025e-03 2.327877e-01 2.505851e-03 2.433715e-03 -6.000000e+00 8.092245e-03 226.87 -2.00 3.05 -2.00 316.47 0.00e+00 4.678302e-04 3.017827e-04 1.714905e-04 -6.000000e+00 3.631146e-04 285.74 -2.00 20.00 -2.00 315.73 0.00e+00 1.939 0.000 302.00 328.00 3 4.9493e+00 6.5227e-03 1.9183e-02 -6.0000e+00 2.0051e-02 -3.9024e-02 7.3205e-03 1.0273e-02 -6.0000e+00 2.1780e-02 5.4688e-03 4.2522e-03 5.0426e-03 -6.0000e+00 1.3004e-02 -6.6412e-03 2.0266e-03 1.4384e-03 -6.0000e+00 5.5755e-03 5.7609e-04 1.7898e-03 1.3836e-04 1.5589e-05 -6.0000e+00 3.7343e-04 -8.0873e-03 0.0000e+00 12 9 1 12 41 1 99.23 25.08 0.30 -0.00809 0.00536 3 3 1 5 0 1715.780 33.75 20.01 25.08 30.33 0.0 983.18 1276 -889 -471 -5385 -2150 -1195 208 -2818 -1124 5355 -5020 -2205 -266 1972 2681 2130 945 406 1118 2653 -1167 -1054 1578 -34 -595 392 -284 -974 -2589 -1452 1096 602 1414 -2678 -4475 -3597 -758 -2593 -920 559 -213 -279 383 -113 -88 1475 -104 96 -1794 186 -52 38 702 772 1361 -396 1239 252 317 1080 324 2192 1694 2391 301 -33 -323 -363 88 638 915 -229 271 372 -7 -849 -1688 -1845 -1376 -2162 -1002 -42 -2646 -1473 -300 98 92 1592 841 853 1216 388 -1658 -435 -209 -756 481 458 354 -620 -234 -1159 -1378 -1219 -1121 -1105 -1071 -787 120 462 1881 932 1074 22 -247 -685 -336 -620 1233 360 -63 706 -301 787 545 -272 745 53 -182 600 297 -21 -246 -171 -45 -473 468 1056 18 -452 -547 -349 -828 204 -157 -85 -938 -349 -186 34 -532 -211 990 -1002 -437 -58 482 739 647 300 134 381 921 -392 -379 568 -12 -222 150 -110 -352 -956 -524 411 222 561 -1135 -1771 -1385 -314 -1270 -492 345 -133 -182 255 -76 -59 975 -68 61 -1135 124 -34 27 516 599 1080 -303 952 194 256 862 251 1799 1518 2126 270 -29 -262 -286 74 568 889 -234 275 364 -7 -746 -1350 -1498 -1165 -1948 -937 -43 -2784 -1598 -347 114 112 1991 1065 1037 1433 420 -1777 -444 -226 -854 563 596 462 -796 -297 -1366 -1622 -1412 -1424 -1398 -1417 -1089 164 669 2830 1426 1571 31 -327 -901 -440 -808 1701 510 -92 1006 -424 1104 724 -367 943 68 -238 828 432 -30 -356 -256 -68 -760 764 1759 30 -748 -878 -541 -1257 SU 20260623T062655.4Z 9670.268697 747 1 37.77 2 58.07 60.68 154.03 118.07 0.00 1 0.00 1 0 17 1.288e-02 7.597e-03 4.372e-03 2.030e-03 2.269335e-01 1.011818e-03 2.382366e-03 -6.000000e+00 7.227438e-03 226.87 -2.00 3.05 -2.00 316.36 0.00e+00 6.792291e-04 1.186382e-04 1.175277e-04 -6.000000e+00 3.247044e-04 285.74 -2.00 20.00 -2.00 315.62 0.00e+00 1.884 0.000 302.00 328.00 3 5.0874e+00 2.6308e-03 1.8675e-02 -6.0000e+00 1.7907e-02 -3.0319e-02 2.9488e-03 1.0061e-02 -6.0000e+00 1.9461e-02 8.4277e-03 1.7081e-03 4.9381e-03 -6.0000e+00 1.1619e-02 -7.3152e-03 8.0833e-04 1.4280e-03 -6.0000e+00 4.9743e-03 5.2660e-04 4.7116e-04 5.5953e-05 1.5693e-05 -6.0000e+00 3.3412e-04 1.5848e-03 0.0000e+00 12 9 1 12 1 1 99.88 25.13 0.33 0.00158 0.00513 11 2 1 5 0 3147.080 33.75 20.00 25.13 30.58 0.0 983.21 -1025 367 694 -963 -3043 -3194 334 -4335 675 3614 -4987 -374 -2298 2762 763 1323 -319 1498 411 1065 -546 -1164 1319 3467 828 997 -506 -1453 -1094 -585 493 1038 1859 -1698 -4091 -3209 -2179 -1054 -748 -477 -1303 -14 161 -591 440 419 -671 -155 -2195 -238 765 281 1615 893 478 629 771 381 766 528 546 1174 2296 2272 941 -84 -61 -1046 -39 598 375 561 384 434 -189 -924 -1604 -1447 -1456 -1406 -1430 -545 -2256 -1388 -623 -428 131 441 1126 730 977 -57 -808 -81 -611 -61 278 553 585 -63 -250 -1363 -1044 -799 -1016 -840 -607 -334 255 809 1034 677 409 340 -304 -335 -345 125 227 237 14 179 473 363 619 -142 -166 409 334 0 -7 45 -310 -38 92 -85 381 423 271 -335 -216 -464 -737 -178 68 131 -170 -528 -536 58 -875 131 715 -1045 -76 -538 700 224 424 -107 510 147 392 -190 -437 495 1234 316 394 -203 -546 -412 -217 192 393 757 -734 -1660 -1266 -940 -522 -410 -305 -845 -10 110 -410 300 287 -453 -101 -1423 -163 509 201 1197 703 388 483 603 297 624 429 429 986 2070 2045 848 -75 -50 -838 -33 535 369 573 393 427 -174 -817 -1288 -1175 -1237 -1259 -1345 -561 -2363 -1502 -721 -501 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