File name: Pandora91s1_Kigali_20260728_L2Fit_fwvt1c2d20250101p1-8.txt File generation date: 20260728T221318.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Tador Tekeste Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 91 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora91_OF_v4d20241022.txt Instrument calibration file used: Pandora91s1_CF_v2d20250101.txt Level 1 file used: Pandora91s1_Kigali_20260728_L1_smca1c2d20250101p1-8.txt Full location name: US Embassy of Rwanda Short location name: Kigali Country of location: Rwanda Location latitude [deg]: -1.9363 Location longitude [deg]: 30.0779 Location altitude [m]: 1495 Local noon date: 20260728 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 1615 1765 Nominal wavelengths inside fitting window [nm]: 492.0440 492.1650 492.2859 492.4068 492.5277 492.6486 492.7695 492.8904 493.0112 493.1320 493.2528 493.3736 493.4944 493.6152 493.7359 493.8566 493.9773 494.0980 494.2187 494.3393 494.4600 494.5806 494.7012 494.8218 494.9424 495.0629 495.1835 495.3040 495.4245 495.5450 495.6654 495.7859 495.9063 496.0267 496.1471 496.2675 496.3879 496.5082 496.6286 496.7489 496.8692 496.9895 497.1097 497.2300 497.3502 497.4704 497.5906 497.7108 497.8310 497.9511 498.0713 498.1914 498.3115 498.4315 498.5516 498.6717 498.7917 498.9117 499.0317 499.1517 499.2716 499.3916 499.5115 499.6314 499.7513 499.8712 499.9910 500.1109 500.2307 500.3505 500.4703 500.5901 500.7098 500.8296 500.9493 501.0690 501.1887 501.3084 501.4280 501.5476 501.6673 501.7869 501.9065 502.0260 502.1456 502.2651 502.3846 502.5041 502.6236 502.7431 502.8625 502.9820 503.1014 503.2208 503.3401 503.4595 503.5789 503.6982 503.8175 503.9368 504.0561 504.1753 504.2946 504.4138 504.5330 504.6522 504.7714 504.8905 505.0097 505.1288 505.2479 505.3670 505.4861 505.6051 505.7241 505.8432 505.9622 506.0811 506.2001 506.3191 506.4380 506.5569 506.6758 506.7947 506.9136 507.0324 507.1512 507.2701 507.3888 507.5076 507.6264 507.7451 507.8639 507.9826 508.1013 508.2199 508.3386 508.4572 508.5759 508.6945 508.8131 508.9316 509.0502 509.1687 509.2872 509.4057 509.5242 509.6427 509.7611 509.8796 509.9980 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Column 101: Humidity inside spectrometer box [%], -9=no humidity signal Column 102: Temperature inside spectrometer box [°C], 999=no temperature signal Column 103: Pressure inside spectrometer box [hPa], -9=no pressure signal Columns 104-254: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 255-405: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20260728T060541.6Z 9705.253953 718 1 1.34 2 62.64 67.44 129.47 234.92 0.00 1 0.00 1 0 15 4.251e-03 4.223e-03 2.705e-03 2.702e-03 2.405741e+03 1.602208e+02 1.687718e+02 -6.000000e+00 2.355527e+02 285.30 -2.00 20.00 -2.00 505.29 0.00e+00 6.125297e-04 7.433881e-05 4.077388e-05 -6.000000e+00 1.192921e-04 285.30 -2.00 20.00 -2.00 500.57 0.00e+00 1.422449e-01 5.231234e-02 1.911734e-02 -6.000000e+00 8.308343e-02 226.97 -2.00 3.05 -2.00 502.15 0.00e+00 2.165 0.000 489.00 513.00 1 5.1558e+00 4.0132e-03 3.1926e-03 -6.0000e+00 6.3785e-03 -2.5595e-02 1.0303e-03 4.5395e-04 -6.0000e+00 1.6470e-03 8.5370e-03 -1.7225e-04 2.5562e-04 2.4093e-05 -6.0000e+00 4.1219e-04 4.8977e-03 -1.4057e-04 12 9 1 12 1 1 999.00 25.16 1.09 0.00490 0.00370 1 5 1 4 0 667.220 33.75 20.01 25.16 29.91 0.0 980.67 12.3 25.92 855.02 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-497 -600 -332 -475 -506 -678 -153 -318 -422 -333 178 105 58 -33 175 86 680 -34 -85 -304 -472 -1043 -679 -846 416 29 72 398 -300 -234 -42 -21 -452 426 149 477 682 485 329 553 279 61 715 -102 167 108 -67 343 419 766 535 416 -107 101 -30 -225 -357 75 127 320 305 501 -200 569 539 -126 276 -228 -383 -712 -514 -493 SO 20260728T074259.3Z 9705.321519 1399 1 35.72 2 40.93 57.66 146.48 216.12 0.00 1 0.00 1 0 15 4.176e-03 4.153e-03 2.053e-03 2.049e-03 1.653427e+03 1.197573e+02 1.252748e+02 -6.000000e+00 2.313818e+02 285.30 -2.00 20.00 -2.00 505.28 0.00e+00 4.628705e-04 5.621148e-05 2.617637e-05 -6.000000e+00 1.171975e-04 285.30 -2.00 20.00 -2.00 500.45 0.00e+00 -8.340876e-02 3.983023e-02 1.103158e-02 -6.000000e+00 8.171653e-02 226.97 -2.00 3.05 -2.00 502.06 0.00e+00 1.322 0.000 489.00 513.00 1 8.4239e+00 3.0577e-03 1.9485e-03 -6.0000e+00 6.2722e-03 -1.0186e-02 7.8746e-04 2.8185e-04 -6.0000e+00 1.6219e-03 3.6678e-04 2.8384e-03 1.9397e-04 1.7049e-05 -6.0000e+00 4.0493e-04 3.7987e-04 -2.0745e-04 11 8 0 10 0 0 99.92 25.97 1.20 0.00038 0.02007 15 2 1 4 0 2381.290 34.25 20.01 25.97 33.38 0.0 993.34 9.4 30.59 855.67 -813 -388 -239 -275 115 281 658 436 71 197 -148 238 136 -348 -564 -273 -119 -302 92 -119 544 -116 -42 -19 279 652 374 532 -197 146 -614 -590 121 146 -87 259 55 310 -342 -567 92 384 -79 866 699 430 239 615 45 -263 140 -750 -869 -530 -768 89 296 262 -192 789 231 125 102 340 126 -71 -209 505 -600 -389 -803 -559 -211 -180 200 27 -431 -561 -407 -361 -235 -593 -757 423 -306 558 539 -490 13 -277 80 246 308 557 205 275 263 368 -334 -778 -548 -631 -558 219 -626 -629 319 -249 -175 531 -136 -385 90 149 39 518 251 600 615 426 708 -194 200 163 283 35 -50 700 276 825 -17 -10 20 -266 184 -67 -349 43 -113 99 435 369 58 467 197 -291 -317 -502 -585 -1054 -167 -784 -375 -238 -271 116 290 688 462 76 208 -154 243 136 -347 -559 -270 -119 -310 97 -127 581 -124 -46 -21 301 702 402 565 -206 147 -609 -586 121 151 -89 268 56 314 -362 -595 95 400 -80 876 715 443 246 623 45 -270 139 -731 -835 -510 -758 89 292 263 -193 786 231 126 103 343 127 -70 -205 508 -603 -385 -790 -550 -209 -181 193 26 -431 -551 -395 -348 -227 -580 -749 416 -293 536 520 -478 12 -271 78 244 310 563 207 273 257 350 -311 -747 -522 -608 -527 213 -632 -640 319 -246 -171 516 -135 -389 92 153 39 516 251 601 612 418 713 -194 198 162 282 35 -50 695 274 815 -17 -10 20 -253 173 -63 -340 43 -109 97 425 363 57 463 196 -290 -310 -481 -573 -1028 -162 SO 20260728T074734.9Z 9705.324710 1429 1 7.21 2 39.96 56.90 147.12 214.73 0.00 1 0.00 1 0 15 3.714e-03 3.691e-03 2.331e-03 2.327e-03 1.121524e+03 1.327930e+02 7.631589e+01 -6.000000e+00 2.057962e+02 285.30 -2.00 20.00 -2.00 505.28 0.00e+00 4.118369e-04 6.392179e-05 2.559801e-05 -6.000000e+00 1.042162e-04 285.30 -2.00 20.00 -2.00 500.51 0.00e+00 6.383854e-02 4.507919e-02 1.004716e-02 -6.000000e+00 7.256872e-02 226.97 -2.00 3.05 -2.00 502.10 0.00e+00 1.303 0.000 489.00 513.00 1 6.8947e+00 3.4606e-03 1.8676e-03 -6.0000e+00 5.5715e-03 -1.0514e-02 8.9150e-04 2.2991e-04 -6.0000e+00 1.4381e-03 1.6811e-03 3.7419e-04 2.2109e-04 1.2024e-05 -6.0000e+00 3.6008e-04 -4.6493e-03 -6.2694e-05 12 1 1 12 1 1 999.00 25.99 1.09 -0.00465 -0.00205 2 2 1 4 0 2403.510 34.25 20.00 25.99 33.40 0.0 994.09 9.3 30.67 855.66 -842 -523 -198 109 154 580 976 166 76 433 484 315 46 -464 -346 -210 -1 -373 43 -256 52 -64 -186 222 386 448 361 249 -116 -183 -457 -753 49 75 117 -44 -57 164 206 127 -139 20 -105 161 505 155 581 353 244 135 86 -445 -630 -1072 -391 -210 394 60 -246 171 67 148 510 292 229 -130 338 -5 -400 90 -770 -42 -237 356 -147 -318 -605 -605 -567 -481 -450 -652 -255 13 -186 -327 73 -270 133 -134 57 304 198 402 310 382 8 -250 -357 -919 -621 -415 145 -45 -257 -248 33 316 -383 -112 6 -246 227 715 272 96 333 637 608 312 298 70 -292 -103 658 -70 135 8 587 -60 672 181 216 20 93 -31 203 146 -212 263 -33 -363 420 3 604 40 -358 -161 -204 -882 -652 -818 -511 -194 110 156 597 1021 173 80 445 502 323 47 -464 -343 -209 -1 -385 44 -269 54 -67 -195 233 406 472 380 260 -119 -186 -454 -752 49 75 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