File name: Pandora198s1_Kobe_20250924_L2Fit_fwvt1c6d20240405p1-8.txt File generation date: 20251126T031230.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c6p1-8 Local principal investigator: Kazuyo Yamaji Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 198 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora198_OF_v3d20240310.txt Instrument calibration file used: Pandora198s1_CF_v6d20240405.txt Level 1 file used: Pandora198s1_Kobe_20250924_L1_smca1c6d20240405p1-8.txt Full location name: Kobe University Short location name: Kobe Country of location: Japan Location latitude [deg]: 34.7190 Location longitude [deg]: 135.2900 Location altitude [m]: 23 Local noon date: 20250924 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB CF based on session 5 + additional lab measurements and new OF with operating temp of 20C First and last pixel inside fitting window: 1756 1906 Nominal wavelengths inside fitting window [nm]: 492.0453 492.1658 492.2863 492.4068 492.5272 492.6476 492.7680 492.8884 493.0088 493.1291 493.2495 493.3698 493.4901 493.6104 493.7306 493.8509 493.9711 494.0913 494.2115 494.3317 494.4519 494.5720 494.6921 494.8122 494.9323 495.0524 495.1725 495.2925 495.4125 495.5325 495.6525 495.7725 495.8924 496.0124 496.1323 496.2522 496.3721 496.4919 496.6118 496.7316 496.8514 496.9712 497.0910 497.2108 497.3305 497.4502 497.5699 497.6896 497.8093 497.9289 498.0486 498.1682 498.2878 498.4074 498.5269 498.6465 498.7660 498.8855 499.0050 499.1245 499.2440 499.3634 499.4828 499.6022 499.7216 499.8410 499.9604 500.0797 500.1990 500.3183 500.4376 500.5569 500.6761 500.7953 500.9146 501.0338 501.1529 501.2721 501.3912 501.5104 501.6295 501.7486 501.8676 501.9867 502.1057 502.2247 502.3437 502.4627 502.5817 502.7006 502.8196 502.9385 503.0574 503.1763 503.2951 503.4140 503.5328 503.6516 503.7704 503.8891 504.0079 504.1266 504.2453 504.3640 504.4827 504.6014 504.7200 504.8387 504.9573 505.0759 505.1944 505.3130 505.4315 505.5500 505.6686 505.7870 505.9055 506.0240 506.1424 506.2608 506.3792 506.4976 506.6159 506.7343 506.8526 506.9709 507.0892 507.2075 507.3257 507.4439 507.5622 507.6804 507.7985 507.9167 508.0348 508.1530 508.2711 508.3892 508.5072 508.6253 508.7433 508.8614 508.9794 509.0973 509.2153 509.3332 509.4512 509.5691 509.6870 509.8049 509.9227 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250923T205655.5Z 9397.872865 28 1 44.60 2 89.03 91.20 112.90 89.75 0.00 1 0.00 1 0 71 4.143e-01 2.678e-01 1.729e-01 1.207e-01 5.313245e+04 1.289104e+04 1.936850e+03 -6.000000e+00 2.451563e+04 290.72 -2.00 20.00 -2.00 505.42 0.00e+00 3.345733e-04 3.768982e-03 3.979148e-04 -6.000000e+00 1.207679e-02 290.72 -2.00 20.00 -2.00 500.50 0.00e+00 -2.978043e+00 2.601522e+00 6.622482e-01 -6.000000e+00 8.301678e+00 228.69 -2.00 3.38 -2.00 502.14 0.00e+00 18.579 0.099 489.00 513.00 1 1.0409e+01 2.0440e-01 5.7832e-02 -6.0000e+00 6.3864e-01 9.5484e-02 4.8251e-02 8.7961e-03 -6.0000e+00 1.6414e-01 4.2001e-06 -7.0014e-02 8.2576e-03 7.3656e-04 -6.0000e+00 4.3458e-02 -7.4114e-02 1.3070e-03 12 8 8 10 0 0 16.84 22.33 30.29 -0.07411 -0.55976 23 8 1 4 0 1938.550 26.94 20.00 22.33 30.43 3.8 986.71 -26018 14892 883 24653 -7928 58093 -12876 -10551 -28246 -15204 56786 49470 26338 15978 239216 -4096 76004 37724 21648 -5398 10195 34136 -12870 -22779 9010 3084 24222 -547 52659 32295 -22410 9666 605 -17482 -16249 13708 -18623 23165 -10291 3299 -25257 -1284 -674 -2194 -5453 32152 29768 -4111 15909 16215 65974 -7999 -6082 -11791 30683 25012 65312 28275 102235 25516 13569 62791 83787 -1700 -28336 101395 20568 53509 67402 37468 900000 23136 62597 11525 79826 17543 9786 -13602 49605 -37112 1335 -8092 -53557 29479 -37732 -37394 22296 30647 17606 53735 1219 62103 4915 -5118 18938 27849 -37729 39669 57261 154951 42431 -14164 14124 -17415 11780 14117 1342 -10490 90773 3772 62953 9815 41222 50342 53548 7254 2007 13657 6711 25761 34286 -28059 -11293 10817 12662 27645 2695 -15605 35129 7228 -1242 -896 34422 18697 -7209 9316 -16215 41956 -34161 27567 39293 920 15357 38606 -37667 27620 23497 7017 -15582 -7805 900000 -35397 13051 860 18807 -8388 33093 -15187 -12486 -40307 -19563 36703 34345 22738 15006 28283 -4578 38340 27497 18493 -6061 10043 27361 -16562 -32319 9429 3431 21858 -634 36391 27121 -31880 9862 654 -22088 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1.176861e-03 290.71 -2.00 20.00 -2.00 500.12 0.00e+00 6.396542e-01 2.895540e-01 1.280999e-01 -6.000000e+00 8.104505e-01 228.68 -2.00 3.38 -2.00 501.76 0.00e+00 4.754 0.002 489.00 513.00 1 1.0214e+01 2.2340e-02 1.2850e-02 -6.0000e+00 6.2493e-02 1.9968e-02 5.5784e-03 2.3158e-03 -6.0000e+00 1.5923e-02 3.5169e-05 -1.3775e-03 1.3605e-03 6.2496e-05 -6.0000e+00 4.2781e-03 5.6538e-02 -1.0574e-05 12 8 8 10 0 0 96.51 22.36 6.86 0.05654 0.04698 17 6 1 4 0 2673.390 27.05 20.00 22.36 31.44 3.7 989.54 -11109 -1040 -788 2753 1286 2135 195 -23 -5099 4853 -3442 2683 547 2339 3879 -6805 4812 -1166 3499 -351 2027 6028 -3139 -4783 337 999 2282 1594 7118 3883 -2001 -2042 -2091 -350 985 4308 -3813 4019 -4652 565 -5992 2178 333 -3113 -1801 5246 -1239 -4100 -549 -1893 5466 484 -1209 -7406 1307 2306 10340 1498 3236 -235 -2521 3109 6804 -2732 -7353 7780 -1694 3493 2680 1523 12672 -266 3698 3171 633 -714 1435 -4317 -323 -5447 -5658 -5715 -13033 8167 -1879 -6173 2866 45 2310 745 -1590 589 1138 -714 -1732 -1128 -5349 1914 4060 -5013 3792 -216 433 2632 1924 3902 -1059 -1813 509 -151 10908 -116 1853 2028 6232 -2016 -320 1981 -5883 -527 3190 -7338 -2376 5294 841 2024 -484 2604 502 247 2905 5978 896 4282 -2312 968 -11636 1911 -1480 4778 -221 1594 977 2879 -3577 -3425 71 -4144 -1905 1351 515 -11963 -1034 -808 2813 1353 2275 215 -25 -5932 5064 -3841 2800 571 2386 3886 -7577 4886 -1278 3773 -395 2233 6400 -3633 -5618 379 1110 2489 1731 7165 3908 -2106 -2162 -2241 -382 1089 4617 -4355 4241 -5247 602 -6780 2290 359 -3488 -2004 5459 -1359 -4560 -579 -1974 5158 469 -1179 -7689 1276 2290 9714 1537 3262 -244 -2670 3143 6642 -2905 -8119 7338 -1722 3326 2548 1445 10705 -256 3443 2988 618 -702 1358 -4237 -302 -5320 -5542 -5655 -13858 7169 -1837 -6343 2710 44 2190 718 -1567 572 1105 -703 -1682 -1063 -5088 1652 3379 -4467 3113 -187 383 2392 1824 3684 -1046 -1788 485 -145 9513 -113 1780 1950 5751 -2016 -317 1937 -6202 -522 2998 -7497 -2275 4708 786 1862 -456 2379 466 229 2620 5150 800 3681 -2111 863 -11943 1754 -1418 4385 -215 1534 952 2764 -3634 -3463 69 -4102 -1819 1238 478 SQ 20250923T215930.5Z 9397.916326 69 1 44.65 2 76.26 100.33 100.62 98.39 0.00 1 0.00 1 0 29 3.715e-02 3.638e-02 1.182e-02 1.169e-02 8.718473e+03 8.752149e+02 2.937279e+02 -6.000000e+00 2.191857e+03 290.71 -2.00 20.00 -2.00 505.26 0.00e+00 -3.012908e-04 3.335406e-04 9.090181e-05 -6.000000e+00 1.074352e-03 290.71 -2.00 20.00 -2.00 500.07 0.00e+00 1.523532e+00 2.389837e-01 1.066213e-01 -6.000000e+00 7.399464e-01 228.68 -2.00 3.38 -2.00 501.72 0.00e+00 4.110 0.001 489.00 513.00 1 1.0089e+01 1.8423e-02 1.0388e-02 -6.0000e+00 5.7054e-02 8.2774e-03 4.6087e-03 1.9051e-03 -6.0000e+00 1.4541e-02 4.0024e-05 -1.0485e-03 1.1398e-03 2.6575e-05 -6.0000e+00 3.9079e-03 6.0058e-02 -4.6323e-05 12 9 8 11 32 0 -28.05 22.36 7.03 0.06006 0.05278 13 4 1 4 0 3433.820 27.05 20.00 22.36 31.35 3.7 989.22 -7679 -2999 1615 130 3098 -102 1336 -52 -4723 2347 -2197 2961 -825 362 4109 -5209 3738 3158 3498 365 376 998 -4730 -3579 1964 -544 4714 2381 10309 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