File name: Pandora239s1_Kosetice_20230731_L2Fit_fout2c2d20220901p1-8.txt File generation date: 20260325T160351.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Nadezda Zikova Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 239 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora239_OF_v3d20220426.txt Instrument calibration file used: Pandora239s1_CF_v2d20220901.txt Level 1 file used: Pandora239s1_Kosetice_20230731_L1_smca1c2d20220901p1-8.txt.bz2 Full location name: National Atmospheric Observatory Kosetice Short location name: Kosetice Country of location: Czech Republic Location latitude [deg]: 49.5733 Location longitude [deg]: 15.0803 Location altitude [m]: 534 Local noon date: 20230731 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Initial instrument OoB session based on session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0356 305.1770 305.3183 305.4597 305.6010 305.7424 305.8837 306.0250 306.1663 306.3076 306.4488 306.5901 306.7314 306.8726 307.0138 307.1551 307.2963 307.4374 307.5786 307.7198 307.8610 308.0021 308.1432 308.2844 308.4255 308.5666 308.7077 308.8487 308.9898 309.1309 309.2719 309.4129 309.5540 309.6950 309.8360 309.9769 310.1179 310.2589 310.3998 310.5408 310.6817 310.8226 310.9635 311.1044 311.2453 311.3861 311.5270 311.6678 311.8087 311.9495 312.0903 312.2311 312.3719 312.5126 312.6534 312.7942 312.9349 313.0756 313.2163 313.3570 313.4977 313.6384 313.7791 313.9197 314.0604 314.2010 314.3416 314.4822 314.6228 314.7634 314.9040 315.0445 315.1851 315.3256 315.4661 315.6066 315.7471 315.8876 316.0281 316.1686 316.3090 316.4495 316.5899 316.7303 316.8707 317.0111 317.1515 317.2918 317.4322 317.5725 317.7129 317.8532 317.9935 318.1338 318.2741 318.4144 318.5546 318.6949 318.8351 318.9753 319.1155 319.2557 319.3959 319.5361 319.6763 319.8164 319.9566 320.0967 320.2368 320.3769 320.5170 320.6571 320.7971 320.9372 321.0772 321.2173 321.3573 321.4973 321.6373 321.7773 321.9172 322.0572 322.1971 322.3371 322.4770 322.6169 322.7568 322.8967 323.0366 323.1764 323.3163 323.4561 323.5959 323.7358 323.8756 324.0153 324.1551 324.2949 324.4346 324.5744 324.7141 324.8538 324.9935 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230731T130701.5Z 8612.546545 8 1 6.18 2 39.61 228.58 137.86 75.82 0.00 1 0.00 1 0 17 4.238e-02 2.894e-02 1.027e-03 8.095e-04 1.775521e-01 4.223690e-04 2.229109e-03 -6.000000e+00 2.446946e-02 232.74 -2.00 3.74 -2.00 314.22 0.00e+00 1.294934e-03 3.068452e-05 2.603542e-05 -6.000000e+00 1.059905e-03 281.86 -2.00 20.00 -2.00 313.68 0.00e+00 1.297 0.000 302.00 328.00 3 1.8791e+00 1.0851e-03 1.5724e-02 -6.0000e+00 6.1552e-02 1.6375e-01 1.1994e-03 9.8507e-03 -6.0000e+00 6.6697e-02 -1.5017e-01 6.8765e-04 4.6554e-03 -6.0000e+00 3.9551e-02 6.6153e-02 2.9146e-04 1.4077e-03 -6.0000e+00 1.6499e-02 2.0062e-02 -1.0263e-03 2.2353e-05 1.6260e-05 -6.0000e+00 1.1333e-03 -4.7221e-02 -1.2748e-03 12 9 9 12 5 1 94.53 22.54 0.40 -0.04722 -0.05493 156 797 1 8 0 37.590 20.02 22.54 30.01 26.11 25.39 15.4 950.62 5999 8239 7924 1472 -8127 -13769 -12288 -8259 -4034 -3631 -7621 -9246 -5398 -471 4069 6424 6100 5728 5839 6426 5661 3327 2998 3414 3108 3000 1596 -2377 -6787 -8252 -6710 -5698 -3690 -4862 -10332 -12123 -9764 -4573 701 4309 5370 5322 5465 5249 4626 4404 2762 1377 -506 -1109 123 987 1673 2241 1741 1479 1361 491 -434 -597 570 1777 3461 3999 2112 -956 -3227 -4688 -2668 -590 528 1144 864 271 -1510 -4038 -6853 -8926 -7906 -5749 -4013 -2767 -2892 -1954 -251 759 1943 2633 2940 2253 1001 -838 -2791 -3727 -3058 -1797 -205 1350 1516 688 -223 -1771 -2219 -1130 -347 100 853 1292 2038 2948 3235 3064 2327 1056 -572 -1279 -1440 -902 304 1104 1441 1528 1432 822 400 -818 -1642 -1422 -1243 -1022 -742 -878 -1064 -766 -133 131 430 882 613 385 -209 -926 -1456 2734 3581 3475 701 -3658 -6007 -5385 -3761 -1920 -1786 -3749 -4509 -2726 -251 2089 3470 3361 3191 3309 3682 3289 1925 1732 2024 1895 1867 998 -1436 -3889 -4590 -3773 -3311 -2223 -3023 -6235 -7099 -6003 -3042 522 3287 4378 4468 4675 4509 3949 3731 2304 1114 -400 -865 98 825 1445 2004 1595 1365 1270 458 -399 -545 529 1602 3294 3982 2104 -890 -3035 -4283 -2499 -563 544 1219 922 280 -1480 -3936 -6154 -7649 -6901 -5470 -3852 -2872 -3181 -2059 -278 895 2380 3085 3445 2729 1128 -938 -2885 -3711 -3167 -2010 -231 1653 1815 866 -265 -1981 -2550 -1246 -414 125 1104 1621 2644 3992 4551 4309 3132 1326 -712 -1503 -1694 -1105 396 1429 1902 1994 1827 1076 495 -975 -1869 -1620 -1498 -1296 -976 -1178 -1347 -1002 -184 188 632 1238 865 564 -298 -1288 -1996 SS 20230731T131155.0Z 8612.549942 11 1 52.15 2 40.21 230.13 137.13 76.89 0.00 1 0.00 1 0 25 4.598e-02 3.183e-02 2.697e-04 2.122e-04 1.788487e-01 1.103923e-04 2.246589e-03 -6.000000e+00 2.656340e-02 232.74 -2.00 3.74 -2.00 314.27 0.00e+00 1.278232e-03 8.157078e-06 5.931197e-05 -6.000000e+00 1.150077e-03 281.86 -2.00 20.00 -2.00 313.74 0.00e+00 1.308 0.000 302.00 328.00 3 1.3037e+00 2.8378e-04 1.5834e-02 -6.0000e+00 6.6820e-02 1.7240e-01 3.1377e-04 9.8842e-03 -6.0000e+00 7.2394e-02 -1.6640e-01 1.7942e-04 4.6657e-03 -6.0000e+00 4.2930e-02 7.0804e-02 7.5901e-05 1.3730e-03 -6.0000e+00 1.7917e-02 3.5367e-02 -6.4823e-04 5.8413e-06 1.6325e-05 -6.0000e+00 1.2295e-03 -4.9030e-02 -1.2281e-03 12 9 8 11 4 0 99.54 22.57 0.43 -0.04903 -0.05390 3115 516 2 8 0 16.490 20.02 22.57 29.86 26.11 25.39 15.7 953.32 6210 9059 8154 1991 -8689 -14430 -13514 -8940 -4514 -3914 -7859 -9862 -5842 -724 4378 6832 6521 6255 6306 6794 6158 3762 3242 3507 3449 3402 1910 -2335 -7102 -8961 -7742 -6161 -4104 -5304 -10996 -13130 -10254 -4996 922 4976 6095 6244 6350 5996 5510 4941 3329 1565 -337 -991 348 1236 1929 2529 2136 1876 1634 743 -112 -491 564 2106 3711 4541 2492 -633 -3331 -5019 -3050 -427 828 1459 849 452 -1472 -4364 -7366 -9709 -8666 -6370 -4430 -2979 -2771 -1802 -175 1141 2186 2994 3249 2510 1032 -1015 -3305 -4266 -3505 -2041 -226 1426 1673 857 -302 -2000 -2584 -1412 -429 113 902 1356 2207 3042 3543 3270 2516 1119 -517 -1442 -1670 -1006 136 1171 1409 1612 1427 847 190 -904 -1927 -1771 -1495 -1113 -876 -940 -1152 -785 -184 280 579 928 794 468 -86 -769 -1420 2771 4212 3845 923 -3848 -6188 -5845 -3991 -2099 -1876 -3765 -4695 -2872 -375 2384 3909 3803 3346 3431 3738 3429 2086 1976 1996 2012 2023 1141 -1487 -4302 -5284 -4625 -3781 -2609 -3480 -7016 -8148 -6639 -3177 652 3912 4692 4939 5117 4857 4427 3952 2621 1309 -276 -799 286 1064 1573 2134 1845 1633 1439 654 -97 -423 495 1936 3604 4601 2531 -601 -2964 -4346 -2707 -416 870 1463 855 478 -1475 -4028 -6846 -8631 -7843 -5753 -4364 -3167 -2873 -1927 -197 1361 2714 3534 3838 3084 1181 -1076 -3514 -4370 -3730 -2162 -260 1775 2025 1018 -367 -2285 -2820 -1589 -521 143 1104 1723 2897 4174 5041 4657 3431 1426 -656 -1732 -2010 -1260 168 1540 1892 2138 1850 1052 241 -1103 -2250 -2073 -1849 -1446 -1098 -1200 -1489 -1047 -259 410 808 1322 1137 700 -124 -1091 -1987 SS 20230731T131754.8Z 8612.554106 14 1 52.92 2 40.97 231.98 136.22 78.18 0.00 1 0.00 1 0 17 4.670e-02 3.232e-02 2.600e-04 2.050e-04 1.809234e-01 1.064371e-04 2.264664e-03 -6.000000e+00 2.696416e-02 232.74 -2.00 3.74 -2.00 314.26 0.00e+00 1.325099e-03 7.875494e-06 5.450253e-05 -6.000000e+00 1.168086e-03 281.86 -2.00 20.00 -2.00 313.74 0.00e+00 1.323 0.000 302.00 328.00 3 1.2263e+00 2.7354e-04 1.6005e-02 -6.0000e+00 6.7827e-02 1.7726e-01 3.0266e-04 9.9901e-03 -6.0000e+00 7.3499e-02 -1.7187e-01 1.7312e-04 4.7080e-03 -6.0000e+00 4.3584e-02 7.3483e-02 7.3150e-05 1.3900e-03 -6.0000e+00 1.8180e-02 3.7525e-02 -1.1697e-03 5.6314e-06 1.6229e-05 -6.0000e+00 1.2490e-03 -4.7376e-02 -1.3026e-03 12 9 8 11 4 0 95.90 22.59 0.44 -0.04738 -0.05617 3138 519 2 8 0 16.370 20.01 22.59 30.24 26.11 25.39 15.8 954.69 6464 9376 8478 1973 -8718 -14516 -13570 -9007 -4523 -4064 -8052 -10017 -5933 -742 4496 7005 6683 6404 6523 7009 6220 3876 3294 3573 3458 3442 1854 -2412 -7358 -8986 -7888 -6222 -4132 -5333 -11187 -13175 -10412 -5011 1024 5052 6242 6403 6528 6108 5670 4997 3447 1505 -344 -1022 365 1261 1991 2517 2137 1924 1669 732 -238 -521 488 2160 3696 4579 2473 -714 -3425 -5062 -3020 -397 853 1451 904 414 -1565 -4544 -7518 -9942 -8794 -6393 -4454 -2950 -2744 -1802 -114 1177 2277 3044 3270 2522 1031 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