File name: Pandora283s1_LaPaz_20241115_L2Fit_fout2c2d20240531p1-8.txt File generation date: 20241116T042937.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 283 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora283_OF_v3d20231025.txt Instrument calibration file used: Pandora283s1_CF_v2d20240531.txt Level 1 file used: Pandora283s1_LaPaz_20241115_L1_smca1c2d20240531p1-8.txt Full location name: Laboratory for Atmospheric Physics, UMSA, La Paz Short location name: LaPaz Country of location: Bolivia Location latitude [deg]: -16.5389 Location longitude [deg]: -68.0661 Location altitude [m]: 3420 Local noon date: 20241115 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 203 345 Nominal wavelengths inside fitting window [nm]: 305.0233 305.1640 305.3046 305.4453 305.5860 305.7266 305.8672 306.0078 306.1485 306.2891 306.4296 306.5702 306.7108 306.8513 306.9919 307.1324 307.2729 307.4134 307.5539 307.6944 307.8349 307.9754 308.1158 308.2563 308.3967 308.5371 308.6775 308.8179 308.9583 309.0987 309.2390 309.3794 309.5197 309.6600 309.8004 309.9407 310.0810 310.2213 310.3615 310.5018 310.6420 310.7823 310.9225 311.0627 311.2029 311.3431 311.4833 311.6235 311.7636 311.9038 312.0439 312.1840 312.3242 312.4643 312.6044 312.7444 312.8845 313.0246 313.1646 313.3046 313.4447 313.5847 313.7247 313.8647 314.0046 314.1446 314.2846 314.4245 314.5644 314.7044 314.8443 314.9842 315.1241 315.2639 315.4038 315.5437 315.6835 315.8233 315.9631 316.1029 316.2427 316.3825 316.5223 316.6621 316.8018 316.9416 317.0813 317.2210 317.3607 317.5004 317.6401 317.7797 317.9194 318.0590 318.1987 318.3383 318.4779 318.6175 318.7571 318.8967 319.0362 319.1758 319.3153 319.4549 319.5944 319.7339 319.8734 320.0129 320.1524 320.2918 320.4313 320.5707 320.7101 320.8495 320.9890 321.1283 321.2677 321.4071 321.5465 321.6858 321.8251 321.9645 322.1038 322.2431 322.3824 322.5216 322.6609 322.8002 322.9394 323.0786 323.2178 323.3570 323.4962 323.6354 323.7746 323.9138 324.0529 324.1920 324.3312 324.4703 324.6094 324.7485 324.8876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241115T105630.7Z 9085.455911 240 1 54.41 2 75.70 105.59 112.22 285.85 0.00 1 0.00 1 0 17 4.197e-02 6.874e-03 1.527e-03 2.740e-04 4.478346e-01 1.360134e-04 4.566195e-03 -6.000000e+00 2.343134e-02 226.48 -2.00 3.03 -2.00 318.10 0.00e+00 1.071241e-03 2.391215e-05 2.603045e-04 -6.000000e+00 1.003335e-03 274.33 -2.00 20.00 -2.00 317.53 0.00e+00 3.968 0.000 302.00 328.00 3 6.5197e-01 3.6363e-04 3.2936e-02 -6.0000e+00 5.8251e-02 -8.2084e-03 4.1104e-04 1.9598e-02 -6.0000e+00 6.3395e-02 -1.3019e-02 2.7334e-04 9.7970e-03 -6.0000e+00 3.7598e-02 4.1637e-03 1.4402e-04 3.0035e-03 -6.0000e+00 1.6046e-02 1.1169e-02 1.5312e-04 7.2208e-06 2.9094e-05 -6.0000e+00 1.0694e-03 3.4208e-02 -1.1933e-04 11 8 0 10 0 0 99.84 24.26 0.31 0.03421 0.03536 1184 121 1 5 0 45.950 33.25 20.03 24.26 18.35 3.6 882.41 -14046 -10655 -9147 -13980 -17829 -18057 -15993 -13261 -11365 -10442 -12821 -11338 -8142 -5027 -1434 -802 -99 -81 797 1026 1320 -68 686 715 396 409 -425 -1800 -2213 -748 610 1573 1673 65 -2728 -3316 -2615 -1269 -83 274 -105 -69 216 461 642 689 379 57 -162 186 930 1102 1313 1388 1125 1000 833 409 267 116 806 1508 2131 2206 1118 218 -359 -633 276 680 590 498 231 248 -64 -469 -1067 -1629 -1458 -1176 -1230 -1362 -1972 -1949 -1213 -682 -160 305 651 744 682 212 -214 -307 -139 -167 245 608 464 -138 -579 -1040 -1102 -686 -852 -938 -848 -516 -66 502 655 713 487 247 -75 46 12 290 248 247 42 314 557 629 541 311 149 511 453 348 123 -24 -307 -144 -87 -28 54 249 140 -136 -413 -504 -697 -712 -594 -528 -808 -961 -942 -884 -824 -787 -765 -974 -911 -689 -506 -168 -108 -14 -13 120 162 213 -11 114 129 78 85 -89 -365 -430 -146 132 359 432 18 -733 -871 -745 -395 -29 107 -46 -30 98 213 297 322 178 27 -78 92 467 609 741 839 678 624 535 263 168 71 507 978 1532 1668 844 165 -257 -451 212 549 505 447 207 212 -53 -364 -790 -1177 -1130 -967 -1120 -1295 -1973 -2048 -1303 -755 -180 354 753 858 757 225 -219 -311 -147 -187 290 784 613 -183 -745 -1287 -1296 -814 -1067 -1211 -1109 -688 -91 733 1010 1115 752 371 -108 66 17 414 368 379 66 475 834 909 768 436 204 699 642 533 192 -38 -505 -242 -151 -50 98 457 259 -245 -727 -860 -1176 SS 20241115T110711.5Z 9085.463328 243 1 54.80 2 73.23 105.02 114.58 285.43 0.00 1 0.00 1 0 17 2.940e-02 8.037e-03 4.809e-03 1.086e-03 3.912801e-01 5.396679e-04 4.020574e-03 -6.000000e+00 1.641292e-02 226.48 -2.00 3.03 -2.00 317.69 0.00e+00 1.606651e-03 8.495928e-05 1.468879e-04 -6.000000e+00 7.026832e-04 274.33 -2.00 20.00 -2.00 317.13 0.00e+00 3.416 0.000 302.00 328.00 3 3.7523e+00 1.4305e-03 2.8540e-02 -6.0000e+00 4.0803e-02 2.8964e-02 1.6093e-03 1.7194e-02 -6.0000e+00 4.4404e-02 -9.7745e-03 1.0247e-03 8.5542e-03 -6.0000e+00 2.6335e-02 4.3325e-04 5.3108e-04 2.8174e-03 -6.0000e+00 1.1241e-02 7.5301e-04 3.3084e-04 2.8925e-05 2.6354e-05 -6.0000e+00 7.4891e-04 3.3806e-02 -9.4609e-05 11 8 0 10 0 0 99.95 24.28 0.34 0.03381 0.03629 60 6 1 5 0 913.250 33.25 19.77 24.28 19.39 3.5 888.78 -5797 -9807 11580 -6174 -15500 -8471 -9103 -10644 -4184 -548 -7711 -8526 -3022 -4505 946 409 216 -257 -435 1839 4307 148 415 1747 2222 951 -373 -2515 -1615 49 118 598 1351 1701 -3565 -3754 -1389 -783 -303 -155 -626 -955 -524 885 53 1079 814 51 133 123 1644 1195 -6569 1605 1333 589 1057 43 391 276 1427 1834 1865 2779 827 491 -193 -287 626 871 674 595 516 387 57 -316 -847 -1612 -1374 -1037 -1371 -1006 -1556 -1858 -1186 -906 -33 305 581 1048 749 235 -169 -441 380 -127 290 710 429 -83 -479 -1017 -1353 -965 -729 -1093 -891 -571 -278 541 580 599 575 167 -178 46 26 273 16 354 132 179 426 385 397 257 183 706 578 472 228 -84 -247 46 25 -23 105 304 67 -105 -528 -552 -687 -391 -776 771 -465 -1143 -557 -645 -877 -364 -49 -736 -867 -312 -570 135 67 38 -48 -87 374 876 31 89 362 492 223 -89 -582 -351 11 28 161 404 532 -1102 -1125 -442 -271 -118 -71 -298 -483 -274 463 28 570 429 27 70 67 882 705 -4228 1013 877 402 735 30 265 185 969 1271 1433 2189 681 381 -148 -217 480 726 621 546 472 357 49 -255 -658 -1211 -1096 -899 -1297 -1011 -1619 -1943 -1313 -1028 -40 358 682 1232 856 258 -172 -459 403 -146 357 902 569 -110 -622 -1246 -1600 -1156 -910 -1397 -1187 -767 -395 799 891 919 893 245 -250 62 35 384 23 525 199 266 629 549 559 360 243 929 796 691 347 -133 -386 75 41 -40 184 542 122 -185 -919 -913 -1135 SS 20241115T111622.0Z 9085.469699 246 1 54.44 2 71.10 104.55 116.60 285.09 0.00 1 0.00 1 0 17 1.606e-02 6.506e-03 7.663e-04 2.524e-04 3.512530e-01 1.254104e-04 3.624234e-03 -6.000000e+00 8.964285e-03 226.48 -2.00 3.03 -2.00 317.10 0.00e+00 6.072542e-04 1.674147e-05 1.150944e-04 -6.000000e+00 3.837977e-04 274.33 -2.00 20.00 -2.00 316.53 0.00e+00 3.053 0.000 302.00 328.00 3 1.1963e+00 3.2886e-04 2.5515e-02 -6.0000e+00 2.2286e-02 -3.6167e-03 3.6923e-04 1.5328e-02 -6.0000e+00 2.4253e-02 -3.3031e-04 2.2284e-04 7.5977e-03 -6.0000e+00 1.4383e-02 -2.5278e-03 1.1093e-04 2.2204e-03 -6.0000e+00 6.1394e-03 1.3226e-02 2.9822e-04 6.7434e-06 2.2700e-05 -6.0000e+00 4.0905e-04 3.3707e-02 -1.0349e-04 11 8 0 10 0 0 99.72 24.29 0.31 0.03371 0.03595 1351 139 1 5 0 40.290 33.25 19.78 24.29 19.85 3.5 891.92 -3237 -2562 -2523 -4912 -7334 -7413 -4910 -3628 -2216 -3205 -4876 -4109 -2572 -1149 498 375 460 778 1282 1818 1415 724 1308 1156 970 777 146 -663 -847 -87 785 1461 1392 -313 -2789 -3218 -2568 -1272 -349 -17 -515 -346 -212 -66 160 171 -27 -252 -571 -5 677 873 1039 1041 776 820 689 379 190 212 796 1316 1875 1940 751 -25 -609 -663 331 620 620 469 312 348 12 -420 -938 -1424 -1183 -1090 -1225 -1274 -1900 -1799 -1117 -626 -145 329 709 713 685 262 -123 -148 13 -69 338 698 458 -80 -531 -997 -1020 -592 -741 -877 -844 -561 -75 432 616 627 421 242 -152 45 7 288 227 247 25 236 479 575 487 288 192 511 478 330 89 -34 -313 -129 -40 17 82 255 173 -131 -368 -560 -715 -342 -300 -305 -574 -780 -755 -523 -438 -298 -460 -709 -619 -405 -212 106 83 109 193 333 491 393 200 368 324 293 246 47 -201 -242 -27 240 497 491 -117 -1002 -1123 -968 -526 -164 -9 -283 -200 -126 -40 96 103 -16 -150 -338 -3 408 573 694 738 546 594 512 281 138 151 580 987 1542 1660 636 -21 -492 -524 266 549 582 444 295 328 11 -360 -760 -1106 -967 -977 -1158 -1294 -2017 -1928 -1226 -710 -173 392 843 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