File name: Pandora283s1_LaPaz_20241116_L2Fit_fout2c2d20240531p1-8.txt File generation date: 20241117T042729.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 283 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora283_OF_v3d20231025.txt Instrument calibration file used: Pandora283s1_CF_v2d20240531.txt Level 1 file used: Pandora283s1_LaPaz_20241116_L1_smca1c2d20240531p1-8.txt Full location name: Laboratory for Atmospheric Physics, UMSA, La Paz Short location name: LaPaz Country of location: Bolivia Location latitude [deg]: -16.5389 Location longitude [deg]: -68.0661 Location altitude [m]: 3420 Local noon date: 20241116 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 203 345 Nominal wavelengths inside fitting window [nm]: 305.0233 305.1640 305.3046 305.4453 305.5860 305.7266 305.8672 306.0078 306.1485 306.2891 306.4296 306.5702 306.7108 306.8513 306.9919 307.1324 307.2729 307.4134 307.5539 307.6944 307.8349 307.9754 308.1158 308.2563 308.3967 308.5371 308.6775 308.8179 308.9583 309.0987 309.2390 309.3794 309.5197 309.6600 309.8004 309.9407 310.0810 310.2213 310.3615 310.5018 310.6420 310.7823 310.9225 311.0627 311.2029 311.3431 311.4833 311.6235 311.7636 311.9038 312.0439 312.1840 312.3242 312.4643 312.6044 312.7444 312.8845 313.0246 313.1646 313.3046 313.4447 313.5847 313.7247 313.8647 314.0046 314.1446 314.2846 314.4245 314.5644 314.7044 314.8443 314.9842 315.1241 315.2639 315.4038 315.5437 315.6835 315.8233 315.9631 316.1029 316.2427 316.3825 316.5223 316.6621 316.8018 316.9416 317.0813 317.2210 317.3607 317.5004 317.6401 317.7797 317.9194 318.0590 318.1987 318.3383 318.4779 318.6175 318.7571 318.8967 319.0362 319.1758 319.3153 319.4549 319.5944 319.7339 319.8734 320.0129 320.1524 320.2918 320.4313 320.5707 320.7101 320.8495 320.9890 321.1283 321.2677 321.4071 321.5465 321.6858 321.8251 321.9645 322.1038 322.2431 322.3824 322.5216 322.6609 322.8002 322.9394 323.0786 323.2178 323.3570 323.4962 323.6354 323.7746 323.9138 324.0529 324.1920 324.3312 324.4703 324.6094 324.7485 324.8876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241116T102852.2Z 9086.436716 225 1 54.44 2 82.03 107.44 94.43 294.81 0.00 1 0.00 1 0 17 4.324e-01 1.055e-02 2.392e-02 9.283e-04 7.020920e-01 4.730022e-04 6.969827e-03 -6.000000e+00 2.411859e-01 226.43 -2.00 3.03 -2.00 320.25 0.00e+00 3.783085e-03 1.655221e-04 1.314625e-03 -6.000000e+00 1.033582e-02 274.35 -2.00 20.00 -2.00 319.76 0.00e+00 6.775 0.000 302.00 328.00 3 9.3919e-01 1.3819e-03 5.4870e-02 -6.0000e+00 5.9952e-01 5.4457e-02 1.7355e-03 3.1664e-02 -6.0000e+00 6.5261e-01 -1.2675e-01 1.7247e-03 1.7676e-02 -6.0000e+00 3.8705e-01 5.1279e-02 8.8487e-04 7.0009e-03 -6.0000e+00 1.6512e-01 1.0727e-03 -6.2400e-04 2.2931e-05 7.1563e-05 -6.0000e+00 1.1020e-02 3.5943e-02 -2.0714e-04 12 8 8 10 0 0 0.93 24.37 0.33 0.03594 0.03125 329 34 1 5 0 165.460 33.25 20.16 24.37 20.25 3.5 895.75 -184519 -150234 -69189 -139653 -179102 -141845 -138150 -155209 -118660 -111865 -119590 -102702 -76569 -68728 -52975 -31574 -40667 -42572 -36444 -28673 -4272 -34472 -27081 -20343 -14252 -12996 -19145 -29117 -24882 -28581 -17677 -8862 -8683 -1683 -11449 -12717 -7295 -2156 -3251 846 -1020 -600 1901 4807 490 2741 4413 1488 792 2861 4083 3147 6215 4028 4266 2691 2917 1932 1550 797 3519 3689 3904 4739 2651 2069 1361 592 1498 1815 1694 1104 863 404 -168 -1230 -1801 -3001 -2221 -1394 -1703 -1399 -1814 -2097 -1313 -858 59 290 795 880 772 254 -573 -1335 -605 -787 80 499 307 -144 -477 -1180 -1319 -1237 -1118 -1089 -1171 -501 -341 499 622 654 498 115 -298 -95 -2 209 126 408 323 567 858 826 590 361 192 496 446 368 91 42 -345 -122 -135 -106 60 282 139 -50 -415 -396 -691 -3140 -2162 -482 -1922 -3340 -1785 -1826 -2810 -1697 -1620 -1970 -1646 -1234 -1363 -1161 -683 -1104 -1322 -1165 -901 -108 -1176 -897 -694 -501 -479 -764 -1255 -1023 -1332 -904 -512 -593 -116 -835 -920 -549 -185 -352 106 -134 -85 279 705 76 430 703 255 145 552 874 771 1634 1086 1222 819 917 612 477 241 1067 1237 1505 1915 1173 905 589 266 743 973 1009 693 537 238 -91 -643 -881 -1506 -1247 -867 -1173 -1038 -1493 -1728 -1143 -793 57 273 743 839 688 226 -491 -1185 -566 -815 90 616 400 -192 -595 -1386 -1466 -1367 -1333 -1310 -1480 -639 -456 716 956 1035 798 186 -459 -145 -3 320 205 663 521 907 1312 1278 881 521 277 735 688 626 165 78 -655 -246 -282 -227 130 620 298 -107 -861 -792 -1323 SS 20241116T104347.7Z 9086.447080 230 1 54.42 2 78.61 106.56 97.56 293.95 0.00 1 0.00 1 0 25 1.123e-01 7.466e-03 4.150e-03 3.846e-04 5.354102e-01 1.915509e-04 5.406334e-03 -6.000000e+00 6.262788e-02 226.43 -2.00 3.03 -2.00 318.93 0.00e+00 1.737148e-03 4.358574e-05 4.727500e-04 -6.000000e+00 2.683432e-03 274.35 -2.00 20.00 -2.00 318.38 0.00e+00 4.907 0.000 302.00 328.00 3 6.1352e-01 5.2259e-04 4.0282e-02 -6.0000e+00 1.5568e-01 -1.9708e-03 6.0057e-04 2.3567e-02 -6.0000e+00 1.6945e-01 -3.5786e-02 4.6090e-04 1.1966e-02 -6.0000e+00 1.0050e-01 1.4125e-02 2.4826e-04 3.9013e-03 -6.0000e+00 4.2881e-02 5.7723e-03 -3.5320e-04 9.9156e-06 3.7338e-05 -6.0000e+00 2.8606e-03 3.5034e-02 -1.9025e-04 11 8 0 10 0 0 10.82 24.36 0.31 0.03503 0.03238 854 88 1 5 0 63.710 33.25 20.14 24.36 22.49 3.5 915.03 -42819 -36300 -28143 -35716 -47466 -46209 -42880 -37109 -29913 -27593 -30416 -25980 -20386 -14658 -7876 -6585 -4670 -3591 -2917 -2267 -499 -3965 -3431 -2342 -2229 -1861 -3936 -4916 -5944 -4582 -2090 35 756 -371 -3856 -4488 -3079 -1428 18 658 329 748 874 987 1246 1469 1203 555 275 649 1575 1663 1789 1895 1539 1292 1068 506 79 64 790 1646 2269 2569 1451 510 -148 -416 574 987 821 655 378 299 -296 -762 -1444 -2048 -1637 -1187 -1200 -1393 -1890 -1952 -1268 -673 -125 328 774 953 788 361 -257 -535 -361 -317 178 553 346 -186 -540 -1042 -1108 -735 -925 -1049 -880 -597 -116 496 634 682 507 278 -174 -50 -34 313 187 261 135 376 689 678 549 295 181 418 408 325 100 -6 -245 -184 -116 -20 62 252 149 -105 -388 -512 -636 -1084 -997 -759 -999 -1351 -1263 -1234 -1168 -999 -968 -1128 -1014 -928 -795 -494 -479 -369 -307 -266 -197 -44 -360 -322 -237 -246 -216 -473 -573 -678 -539 -277 5 132 -70 -716 -818 -606 -303 5 187 105 255 289 333 424 508 422 199 102 251 619 728 852 912 784 686 551 262 42 34 425 904 1398 1664 943 339 -95 -269 380 718 630 527 304 228 -219 -534 -986 -1385 -1141 -920 -1031 -1242 -1771 -1930 -1274 -720 -135 365 857 1016 816 361 -253 -528 -375 -348 214 702 465 -252 -713 -1284 -1292 -860 -1134 -1321 -1159 -801 -162 737 972 1068 813 428 -258 -72 -48 467 289 412 215 578 1046 1026 798 426 257 579 607 511 166 -11 -422 -325 -212 -38 120 495 287 -201 -725 -925 -1135 SS 20241116T104918.3Z 9086.450906 233 1 54.43 2 77.34 106.25 98.72 293.66 0.00 1 0.00 1 0 25 6.877e-02 7.050e-03 2.896e-03 3.671e-04 4.899215e-01 1.822123e-04 4.974908e-03 -6.000000e+00 3.838069e-02 226.43 -2.00 3.03 -2.00 318.54 0.00e+00 1.334148e-03 3.657480e-05 3.304547e-04 -6.000000e+00 1.643964e-03 274.35 -2.00 20.00 -2.00 317.97 0.00e+00 4.449 0.000 302.00 328.00 3 8.7002e-01 4.9233e-04 3.6624e-02 -6.0000e+00 9.5405e-02 -4.4546e-03 5.6084e-04 2.1514e-02 -6.0000e+00 1.0383e-01 -2.3829e-02 3.9997e-04 1.0835e-02 -6.0000e+00 6.1583e-02 8.4838e-03 2.1379e-04 3.4309e-03 -6.0000e+00 2.6285e-02 6.2904e-03 3.3794e-05 9.5892e-06 3.2484e-05 -6.0000e+00 1.7521e-03 3.4185e-02 -1.3280e-04 11 8 0 10 0 0 99.38 24.37 0.30 0.03419 0.03444 796 82 1 5 0 68.370 33.25 20.12 24.37 23.50 3.5 922.02 -25450 -20540 -15781 -20682 -31190 -29019 -25859 -23901 -18358 -14965 -20299 -16032 -12588 -8599 -3799 -2484 -2565 -1685 -805 451 1226 -1625 -780 -279 -228 -332 -1704 -2962 -3514 -2943 -699 1192 1493 163 -3089 -3574 -2547 -977 333 387 -14 -30 271 744 666 1052 827 232 123 560 1140 1256 1506 1428 1032 921 818 346 211 196 788 1525 2207 2367 1253 433 -182 -459 435 813 613 562 364 341 -9 -565 -1149 -1682 -1393 -1262 -1265 -1489 -1911 -1969 -1243 -666 -200 261 755 896 847 419 -12 -179 -80 -232 151 547 282 -183 -596 -1090 -1168 -696 -890 -982 -992 -568 -159 426 588 647 405 214 -155 85 135 364 270 210 58 308 579 669 544 365 198 548 445 352 124 30 -239 -51 -30 -8 60 202 136 -167 -455 -529 -664 -885 -780 -605 -797 -1204 -1062 -994 -1043 -863 -729 -1064 -874 -805 -657 -338 -231 -261 -184 -93 54 151 -205 -101 -39 -35 -53 -280 -472 -541 -465 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