File name: Pandora283s1_LaPaz_20241119_L2Fit_fout2c2d20240531p1-8.txt File generation date: 20241120T042357.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 283 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora283_OF_v3d20231025.txt Instrument calibration file used: Pandora283s1_CF_v2d20240531.txt Level 1 file used: Pandora283s1_LaPaz_20241119_L1_smca1c2d20240531p1-8.txt Full location name: Laboratory for Atmospheric Physics, UMSA, La Paz Short location name: LaPaz Country of location: Bolivia Location latitude [deg]: -16.5389 Location longitude [deg]: -68.0661 Location altitude [m]: 3420 Local noon date: 20241119 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 203 345 Nominal wavelengths inside fitting window [nm]: 305.0233 305.1640 305.3046 305.4453 305.5860 305.7266 305.8672 306.0078 306.1485 306.2891 306.4296 306.5702 306.7108 306.8513 306.9919 307.1324 307.2729 307.4134 307.5539 307.6944 307.8349 307.9754 308.1158 308.2563 308.3967 308.5371 308.6775 308.8179 308.9583 309.0987 309.2390 309.3794 309.5197 309.6600 309.8004 309.9407 310.0810 310.2213 310.3615 310.5018 310.6420 310.7823 310.9225 311.0627 311.2029 311.3431 311.4833 311.6235 311.7636 311.9038 312.0439 312.1840 312.3242 312.4643 312.6044 312.7444 312.8845 313.0246 313.1646 313.3046 313.4447 313.5847 313.7247 313.8647 314.0046 314.1446 314.2846 314.4245 314.5644 314.7044 314.8443 314.9842 315.1241 315.2639 315.4038 315.5437 315.6835 315.8233 315.9631 316.1029 316.2427 316.3825 316.5223 316.6621 316.8018 316.9416 317.0813 317.2210 317.3607 317.5004 317.6401 317.7797 317.9194 318.0590 318.1987 318.3383 318.4779 318.6175 318.7571 318.8967 319.0362 319.1758 319.3153 319.4549 319.5944 319.7339 319.8734 320.0129 320.1524 320.2918 320.4313 320.5707 320.7101 320.8495 320.9890 321.1283 321.2677 321.4071 321.5465 321.6858 321.8251 321.9645 322.1038 322.2431 322.3824 322.5216 322.6609 322.8002 322.9394 323.0786 323.2178 323.3570 323.4962 323.6354 323.7746 323.9138 324.0529 324.1920 324.3312 324.4703 324.6094 324.7485 324.8876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241119T110148.7Z 9089.459592 243 1 8.48 2 74.45 106.32 65.90 312.16 0.00 1 0.00 1 0 25 2.705e-02 6.720e-03 3.011e-03 7.436e-04 4.073356e-01 3.686555e-04 4.187602e-03 -6.000000e+00 1.508342e-02 226.28 -2.00 3.03 -2.00 317.64 0.00e+00 7.936296e-04 5.663980e-05 1.797803e-04 -6.000000e+00 6.467317e-04 274.40 -2.00 20.00 -2.00 317.05 0.00e+00 3.669 0.000 302.00 328.00 3 1.0341e+00 9.7449e-04 3.0252e-02 -6.0000e+00 3.7480e-02 -2.4316e-03 1.0975e-03 1.7796e-02 -6.0000e+00 4.0800e-02 -9.2353e-03 6.9171e-04 8.8544e-03 -6.0000e+00 2.4201e-02 1.6282e-03 3.5591e-04 2.6159e-03 -6.0000e+00 1.0330e-02 9.7185e-03 -1.8871e-04 1.9697e-05 2.6138e-05 -6.0000e+00 6.8925e-04 3.4925e-02 -1.8058e-04 12 9 1 12 1 1 36.68 24.26 0.32 0.03492 0.03351 115 76 1 5 0 73.080 33.25 19.93 24.26 18.71 3.4 882.07 -7895 -6823 -5028 -6998 -13947 -12605 -8966 -8462 -4513 -6335 -7491 -7601 -4809 -2442 24 259 964 557 1777 1534 1764 576 1688 794 728 519 79 -918 -1235 -742 308 1631 2000 -213 -2581 -3288 -2402 -1488 -47 211 -321 -239 38 424 170 328 123 -259 -207 129 1056 1026 992 1319 872 1057 812 140 165 36 890 1353 1912 1980 947 -25 -361 -708 350 826 682 336 220 477 -143 -549 -1060 -1613 -1329 -1204 -1192 -1285 -2038 -1840 -966 -604 -120 292 661 754 743 326 -73 -232 -11 -59 234 593 376 -146 -566 -1053 -1124 -708 -789 -873 -858 -484 -89 484 601 685 471 281 -112 118 9 239 228 262 -16 211 593 652 560 307 165 460 504 321 139 -18 -335 -120 -129 -4 51 293 169 -191 -422 -482 -714 -566 -546 -413 -555 -1060 -1001 -741 -729 -424 -644 -774 -835 -606 -334 4 47 186 106 355 322 379 124 370 190 188 131 20 -241 -309 -187 79 470 602 -69 -802 -998 -788 -539 -19 97 -156 -123 20 228 92 170 67 -141 -113 69 599 608 605 855 566 707 559 97 111 24 600 945 1416 1543 766 -20 -271 -527 278 698 614 307 200 429 -124 -445 -815 -1252 -1053 -1018 -1115 -1260 -2106 -1930 -1039 -674 -141 343 774 877 828 345 -73 -238 -12 -67 281 754 505 -197 -738 -1280 -1336 -851 -976 -1118 -1117 -660 -125 702 917 1059 715 413 -160 162 12 339 328 392 -24 314 870 946 795 429 224 624 706 472 215 -29 -529 -197 -216 -6 89 518 301 -334 -719 -814 -1167 SS 20241119T111125.0Z 9089.466261 246 1 45.74 2 72.24 105.83 67.56 310.84 0.00 1 0.00 1 0 17 1.707e-02 6.701e-03 1.275e-03 3.923e-04 3.628001e-01 1.942203e-04 3.734661e-03 -6.000000e+00 9.521379e-03 226.28 -2.00 3.03 -2.00 317.22 0.00e+00 7.168446e-04 2.693852e-05 1.426267e-04 -6.000000e+00 4.079882e-04 274.40 -2.00 20.00 -2.00 316.65 0.00e+00 3.237 0.000 302.00 328.00 3 1.7651e+00 5.0983e-04 2.6769e-02 -6.0000e+00 2.3660e-02 3.7051e-03 5.7289e-04 1.5813e-02 -6.0000e+00 2.5750e-02 -4.0895e-03 3.4920e-04 7.8515e-03 -6.0000e+00 1.5274e-02 -1.0586e-03 1.7565e-04 2.3270e-03 -6.0000e+00 6.5234e-03 6.5344e-03 4.6692e-04 1.0449e-05 2.3038e-05 -6.0000e+00 4.3468e-04 3.3733e-02 -7.2042e-05 12 9 1 12 1 1 99.98 24.25 0.30 0.03373 0.03724 508 62 1 5 0 89.840 33.25 20.16 24.25 19.34 3.5 889.50 -3410 -3260 -1878 -5554 -7528 -7805 -5188 -3869 -2927 -4040 -5036 -4618 -2458 -1182 441 464 852 1040 1219 1542 1675 840 1225 1048 1097 675 160 -1090 -1249 -455 391 1213 1270 -364 -3107 -3285 -2607 -1354 -424 -83 -434 -285 -146 46 343 219 99 -205 -413 1 767 926 686 1124 865 926 761 416 269 45 908 1314 1910 2050 791 -28 -579 -689 303 757 642 524 420 357 58 -420 -1000 -1680 -1432 -1074 -1331 -1283 -1849 -1817 -1061 -593 -98 380 738 771 644 169 -282 -441 -89 -71 292 708 498 -95 -515 -1035 -1113 -683 -781 -908 -819 -473 16 528 722 789 498 293 -122 -76 -56 260 201 267 40 193 495 572 490 270 122 505 397 304 87 -61 -335 -135 -64 3 123 268 200 -142 -370 -530 -714 -327 -350 -206 -596 -733 -730 -507 -429 -363 -536 -673 -643 -390 -203 88 104 188 242 298 392 436 218 324 298 311 202 48 -314 -365 -132 114 395 430 -131 -1075 -1179 -944 -538 -192 -42 -242 -158 -84 27 199 128 58 -118 -237 1 474 593 450 779 596 655 553 302 191 31 647 1009 1540 1722 659 -23 -462 -539 242 664 597 492 394 334 52 -356 -803 -1298 -1167 -959 -1256 -1302 -1960 -1948 -1164 -673 -117 453 876 913 733 183 -292 -460 -95 -79 355 901 666 -127 -669 -1261 -1298 -809 -977 -1171 -1069 -645 23 773 1073 1208 747 425 -172 -104 -75 354 284 392 60 284 723 827 675 367 161 665 550 436 130 -94 -518 -212 -104 6 210 456 343 -245 -627 -855 -1144 SS 20241119T111734.3Z 9089.470536 250 1 7.24 2 70.82 105.53 68.64 310.03 0.00 1 0.00 1 0 17 1.478e-02 7.107e-03 3.092e-03 1.190e-03 3.397237e-01 5.910909e-04 3.517829e-03 -6.000000e+00 8.242969e-03 226.28 -2.00 3.03 -2.00 316.83 0.00e+00 6.091717e-04 7.359577e-05 1.276170e-04 -6.000000e+00 3.533256e-04 274.40 -2.00 20.00 -2.00 316.26 0.00e+00 3.011 0.000 302.00 328.00 3 2.3081e+00 1.5422e-03 2.4963e-02 -6.0000e+00 2.0483e-02 7.4836e-03 1.7290e-03 1.4804e-02 -6.0000e+00 2.2294e-02 -4.9344e-03 1.0276e-03 7.3432e-03 -6.0000e+00 1.3225e-02 -2.2398e-04 5.0304e-04 2.1369e-03 -6.0000e+00 5.6468e-03 4.5341e-03 1.1778e-04 3.1729e-05 2.2444e-05 -6.0000e+00 3.7649e-04 3.3566e-02 -1.4678e-04 12 9 1 12 1 1 32.27 24.23 0.32 0.03357 0.03445 33 26 1 5 0 212.900 33.25 20.07 24.23 19.87 3.5 892.50 -1904 -1478 -691 -4143 -7964 -6141 -4015 -122 -144 -2562 -4574 -3078 -2583 -1494 792 540 745 1456 813 1447 1858 591 1925 1726 662 619 -185 -1746 -1096 23 735 647 440 -683 -2967 -3160 -2920 -1106 -165 -212 -202 -55 -116 -90 451 482 351 -588 -483 248 977 682 1348 1236 994 898 761 399 128 215 867 1181 1945 2275 741 -142 -589 -927 102 549 476 295 403 573 190 -382 -1324 -2115 -1460 -1399 -1343 -1216 -1736 -1837 -1014 -541 80 541 738 832 312 -56 -425 -772 -130 -42 442 711 478 13 -433 -942 -1340 -654 -722 -903 -666 -439 -74 564 819 810 611 252 16 -101 -127 327 155 224 64 212 762 620 511 312 97 419 361 274 76 -48 -528 -191 -82 146 2 276 137 -65 -350 -536 -748 -259 -204 -98 -570 -1103 -797 -546 -17 -22 -429 -777 -536 -517 -324 196 140 204 416 229 423 554 176 578 556 231 212 -64 -615 -360 7 256 236 168 -274 -1139 -1248 -1176 -489 -83 -120 -120 -33 -71 -56 279 300 216 -360 -293 152 632 460 926 901 723 671 583 306 96 158 652 919 1594 1943 653 -122 -489 -754 85 485 448 281 397 541 173 -337 -1101 -1688 -1219 -1239 -1264 -1233 -1844 -1983 -1123 -622 94 655 893 973 361 -61 -438 -801 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