File name: Pandora283s1_LaPaz_20241124_L2Fit_fout2c2d20240531p1-8.txt File generation date: 20241125T042534.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 283 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora283_OF_v3d20231025.txt Instrument calibration file used: Pandora283s1_CF_v2d20240531.txt Level 1 file used: Pandora283s1_LaPaz_20241124_L1_smca1c2d20240531p1-8.txt Full location name: Laboratory for Atmospheric Physics, UMSA, La Paz Short location name: LaPaz Country of location: Bolivia Location latitude [deg]: -16.5389 Location longitude [deg]: -68.0661 Location altitude [m]: 3420 Local noon date: 20241124 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 203 345 Nominal wavelengths inside fitting window [nm]: 305.0233 305.1640 305.3046 305.4453 305.5860 305.7266 305.8672 306.0078 306.1485 306.2891 306.4296 306.5702 306.7108 306.8513 306.9919 307.1324 307.2729 307.4134 307.5539 307.6944 307.8349 307.9754 308.1158 308.2563 308.3967 308.5371 308.6775 308.8179 308.9583 309.0987 309.2390 309.3794 309.5197 309.6600 309.8004 309.9407 310.0810 310.2213 310.3615 310.5018 310.6420 310.7823 310.9225 311.0627 311.2029 311.3431 311.4833 311.6235 311.7636 311.9038 312.0439 312.1840 312.3242 312.4643 312.6044 312.7444 312.8845 313.0246 313.1646 313.3046 313.4447 313.5847 313.7247 313.8647 314.0046 314.1446 314.2846 314.4245 314.5644 314.7044 314.8443 314.9842 315.1241 315.2639 315.4038 315.5437 315.6835 315.8233 315.9631 316.1029 316.2427 316.3825 316.5223 316.6621 316.8018 316.9416 317.0813 317.2210 317.3607 317.5004 317.6401 317.7797 317.9194 318.0590 318.1987 318.3383 318.4779 318.6175 318.7571 318.8967 319.0362 319.1758 319.3153 319.4549 319.5944 319.7339 319.8734 320.0129 320.1524 320.2918 320.4313 320.5707 320.7101 320.8495 320.9890 321.1283 321.2677 321.4071 321.5465 321.6858 321.8251 321.9645 322.1038 322.2431 322.3824 322.5216 322.6609 322.8002 322.9394 323.0786 323.2178 323.3570 323.4962 323.6354 323.7746 323.9138 324.0529 324.1920 324.3312 324.4703 324.6094 324.7485 324.8876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20241124T132905.8Z 9094.561873 1596 1 26.37 2 40.39 102.73 35.55 306.72 0.00 1 0.00 1 0 17 2.098e-02 1.970e-02 1.777e-03 1.382e-03 1.574424e-01 6.971212e-04 1.700413e-03 -6.000000e+00 1.168962e-02 226.03 -2.00 3.03 -2.00 314.21 0.00e+00 1.132012e-03 5.069977e-05 4.687170e-05 -6.000000e+00 5.017269e-04 274.48 -2.00 20.00 -2.00 313.80 0.00e+00 1.312 0.000 302.00 328.00 3 5.2297e+00 1.7709e-03 1.1230e-02 -6.0000e+00 2.9030e-02 3.4442e-02 1.9644e-03 7.1540e-03 -6.0000e+00 3.1604e-02 -9.1165e-03 1.1291e-03 3.4557e-03 -6.0000e+00 1.8751e-02 -7.3494e-03 4.9325e-04 1.2239e-03 -6.0000e+00 8.0102e-03 1.0169e-03 6.4262e-05 3.6803e-05 1.3217e-05 -6.0000e+00 5.3442e-04 3.5074e-02 -1.1469e-04 12 9 9 12 1 1 -16.98 24.51 0.21 0.03507 0.03556 13 3 1 5 0 1883.390 33.50 19.99 24.51 25.48 3.6 935.99 722 -390 1284 -2050 -3407 -2186 -1172 -1248 692 -1143 -3409 -2767 -1039 -766 1107 1079 903 1491 1284 2101 2937 1279 1524 1445 1382 250 327 -804 -840 1107 1899 1702 2422 697 -1762 -1971 -1259 -543 8 291 -538 -294 -363 87 273 586 497 39 226 665 1228 1273 -20859 2165 1440 1038 1265 887 632 506 1443 1358 1946 2530 1230 334 -95 110 865 1220 1200 938 1007 747 192 9 -903 -1394 -955 -310 -854 -639 -1227 -1486 -555 -435 136 435 681 888 552 166 -208 -405 379 207 703 996 724 27 -221 -816 -1474 -895 -734 -1100 -1203 -578 -496 333 518 650 380 -2 -191 -228 -185 -8 120 417 36 67 195 163 95 -18 -166 499 418 536 269 -92 -278 224 304 214 214 344 253 33 -440 -511 -827 318 -174 564 -916 -1341 -853 -439 -525 316 -511 -1493 -1277 -481 -399 593 621 498 829 734 1225 1725 747 888 875 876 156 212 -491 -501 619 1084 1034 1466 436 -1038 -1181 -759 -358 6 236 -454 -256 -324 77 241 514 423 32 186 535 1016 1066 -20840 1956 1275 933 1149 804 562 468 1297 1306 1918 2618 1276 332 -89 98 798 1216 1255 984 1058 763 193 8 -801 -1205 -837 -286 -847 -663 -1300 -1640 -621 -504 166 528 827 1082 650 184 -217 -416 383 219 783 1170 910 34 -270 -917 -1638 -1022 -878 -1350 -1540 -735 -654 443 720 910 511 -2 -232 -266 -213 -10 148 535 48 90 253 211 117 -22 -198 578 489 670 338 -119 -359 297 409 295 303 481 359 46 -622 -698 -1144 SU 20241124T133123.2Z 9094.563462 1599 1 51.10 2 39.85 102.71 35.98 306.10 0.00 1 0.00 1 0 17 3.092e-02 3.164e-02 1.690e-03 1.295e-03 1.615686e-01 6.525437e-04 1.751248e-03 -6.000000e+00 1.723478e-02 226.03 -2.00 3.03 -2.00 314.31 0.00e+00 1.726579e-03 4.822189e-05 9.681030e-05 -6.000000e+00 7.396027e-04 274.48 -2.00 20.00 -2.00 313.89 0.00e+00 1.301 0.000 302.00 328.00 3 5.7195e+00 1.6590e-03 1.1357e-02 -6.0000e+00 4.2801e-02 6.6816e-02 1.8423e-03 7.6034e-03 -6.0000e+00 4.6593e-02 -1.5109e-02 1.0575e-03 3.5745e-03 -6.0000e+00 2.7644e-02 -9.8669e-03 4.6232e-04 1.5703e-03 -6.0000e+00 1.1812e-02 6.1480e-04 3.7338e-04 3.4515e-05 1.4432e-05 -6.0000e+00 7.8775e-04 3.3490e-02 -1.2642e-04 12 9 9 12 1 1 95.97 24.51 0.14 0.03349 0.03630 15 2 1 5 0 3193.450 33.25 20.06 24.51 25.75 3.6 938.50 295 -118 1897 -2022 -3551 -1994 -1942 -1768 -412 -1681 -4845 -3621 -1197 -1113 1610 1769 1318 1748 2410 2421 3369 1844 2183 1381 1619 393 -770 -1099 -521 1714 1667 2755 3108 1732 -1173 -1428 -332 555 600 680 -165 -725 -184 718 376 981 1138 582 1010 977 2132 1959 -32337 2648 2111 1536 1999 1180 875 883 2000 2167 2329 3135 1521 862 220 250 1319 1929 1647 1445 1137 1069 552 119 -330 -1214 -788 -136 -750 -344 -608 -940 -441 -233 333 754 696 1201 286 -45 -393 -608 784 316 942 1188 991 198 134 -956 -1461 -975 -1058 -1369 -1415 -906 -721 358 484 572 405 -25 -542 -351 -125 -92 20 183 -60 -421 -62 -130 -102 -295 -609 369 382 760 330 -157 78 285 672 191 321 267 551 265 -365 -540 -767 124 -50 845 -860 -1332 -743 -753 -707 -179 -759 -2163 -1585 -562 -548 866 953 726 974 1368 1412 1975 1073 1263 834 1017 241 -469 -668 -290 959 962 1561 1874 1074 -687 -801 -198 359 436 537 -142 -615 -159 616 322 831 987 486 806 766 1710 1673 -34892 2312 1885 1394 1828 1079 785 786 1810 2093 2301 3243 1583 820 199 226 1172 1838 1723 1505 1188 1137 553 113 -295 -1072 -667 -128 -749 -356 -637 -1025 -510 -276 398 928 860 1429 332 -50 -408 -627 786 348 1079 1428 1216 242 160 -1108 -1603 -1099 -1246 -1717 -1768 -1170 -964 479 677 806 546 -33 -672 -422 -148 -108 25 238 -82 -570 -81 -163 -127 -351 -714 420 458 926 422 -205 102 367 911 264 456 388 777 385 -516 -739 -1068 SU 20241124T133501.8Z 9094.565993 1605 1 18.01 2 39.00 102.68 36.67 305.14 0.00 1 0.00 1 0 17 3.567e-02 3.713e-02 3.331e-03 2.544e-03 1.617542e-01 1.281324e-03 1.760644e-03 -6.000000e+00 1.988236e-02 226.03 -2.00 3.03 -2.00 314.31 0.00e+00 1.996628e-03 9.478502e-05 1.146409e-04 -6.000000e+00 8.529801e-04 274.48 -2.00 20.00 -2.00 313.89 0.00e+00 1.286 0.000 302.00 328.00 3 5.8611e+00 3.2563e-03 1.1323e-02 -6.0000e+00 4.9377e-02 7.8871e-02 3.6148e-03 7.7738e-03 -6.0000e+00 5.3748e-02 -1.8229e-02 2.0764e-03 3.6031e-03 -6.0000e+00 3.1890e-02 -1.1232e-02 9.0844e-04 1.7330e-03 -6.0000e+00 1.3627e-02 5.3692e-04 5.7696e-04 6.7720e-05 1.5070e-05 -6.0000e+00 9.0842e-04 3.4669e-02 -3.3489e-05 12 9 9 12 1 1 89.25 24.52 0.19 0.03467 0.03901 4 2 1 5 0 3600.990 33.25 20.03 24.52 26.17 3.7 944.34 454 -922 2010 -1660 -3627 -1787 -1819 -1597 -491 -1951 -4699 -4828 -1745 -1270 1493 1470 2179 2218 2267 2843 3725 2231 2620 1736 1150 -40 -1567 -1247 837 2150 1587 2840 4714 2577 -590 -831 -611 850 -21 1150 -155 -696 126 754 294 1291 1190 600 1260 854 2029 2324 -37551 3463 1999 1960 2192 1125 1611 657 2504 2351 2257 3211 2033 957 565 597 1935 2657 1687 1680 1475 1327 741 -223 -868 -1068 -701 214 -692 73 -308 -1168 -131 -34 146 437 856 1364 -1 331 -595 -418 436 571 744 1582 715 467 -298 -981 -1417 -1055 -688 -1230 -1290 -1044 -920 586 524 379 362 -263 -371 -160 -200 -212 -122 45 -182 -313 -518 -186 -472 -266 -532 467 309 430 229 436 -113 425 563 190 223 503 426 397 -98 -734 -619 186 -412 874 -688 -1442 -649 -685 -619 -207 -857 -2031 -2073 -798 -608 781 827 1240 1282 1254 1607 2118 1257 1466 1013 703 -26 -994 -735 477 1160 888 1670 2905 1538 -357 -481 -379 564 -16 924 -128 -601 110 659 257 1112 997 513 1027 685 1666 2020 -41196 3054 1820 1801 2033 1046 1458 595 2290 2182 2261 3196 2027 922 517 517 1734 2542 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