File name: Pandora283s1_LaPaz_20241208_L2Fit_fwvt1c2d20240531p1-8.txt File generation date: 20241209T084458.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 283 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora283_OF_v3d20231025.txt Instrument calibration file used: Pandora283s1_CF_v2d20240531.txt Level 1 file used: Pandora283s1_LaPaz_20241208_L1_smca1c2d20240531p1-8.txt Full location name: Laboratory for Atmospheric Physics, UMSA, La Paz Short location name: LaPaz Country of location: Bolivia Location latitude [deg]: -16.5389 Location longitude [deg]: -68.0661 Location altitude [m]: 3420 Local noon date: 20241208 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 1626 1775 Nominal wavelengths inside fitting window [nm]: 492.1135 492.2344 492.3554 492.4763 492.5971 492.7180 492.8389 492.9597 493.0805 493.2013 493.3221 493.4429 493.5636 493.6844 493.8051 493.9258 494.0465 494.1672 494.2878 494.4085 494.5291 494.6497 494.7703 494.8908 495.0114 495.1319 495.2524 495.3730 495.4934 495.6139 495.7344 495.8548 495.9752 496.0956 496.2160 496.3364 496.4567 496.5771 496.6974 496.8177 496.9380 497.0582 497.1785 497.2987 497.4190 497.5392 497.6593 497.7795 497.8997 498.0198 498.1399 498.2600 498.3801 498.5002 498.6202 498.7403 498.8603 498.9803 499.1003 499.2202 499.3402 499.4601 499.5800 499.6999 499.8198 499.9397 500.0595 500.1794 500.2992 500.4190 500.5388 500.6585 500.7783 500.8980 501.0177 501.1374 501.2571 501.3768 501.4964 501.6160 501.7357 501.8552 501.9748 502.0944 502.2139 502.3335 502.4530 502.5725 502.6919 502.8114 502.9309 503.0503 503.1697 503.2891 503.4085 503.5278 503.6472 503.7665 503.8858 504.0051 504.1244 504.2436 504.3629 504.4821 504.6013 504.7205 504.8397 504.9588 505.0780 505.1971 505.3162 505.4353 505.5543 505.6734 505.7924 505.9114 506.0304 506.1494 506.2684 506.3874 506.5063 506.6252 506.7441 506.8630 506.9819 507.1007 507.2195 507.3384 507.4572 507.5759 507.6947 507.8134 507.9322 508.0509 508.1696 508.2883 508.4069 508.5256 508.6442 508.7628 508.8814 509.0000 509.1185 509.2371 509.3556 509.4741 509.5926 509.7111 509.8295 509.9480 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241208T111525.0Z 9108.469039 74 1 6.35 2 72.22 109.21 153.57 152.78 0.00 1 0.00 1 0 15 3.503e-03 3.480e-03 1.249e-03 1.246e-03 3.004612e+03 6.984137e+01 2.372792e+02 -6.000000e+00 1.785570e+02 274.70 -2.00 20.00 -2.00 505.27 0.00e+00 6.234472e-04 3.287898e-05 3.651199e-05 -6.000000e+00 9.437680e-05 274.70 -2.00 20.00 -2.00 500.48 0.00e+00 2.027612e-01 2.402837e-02 2.013667e-02 -6.000000e+00 6.765453e-02 225.35 -2.00 3.03 -2.00 502.06 0.00e+00 3.233 0.000 489.00 513.00 1 6.0056e+00 1.8313e-03 3.6516e-03 -6.0000e+00 5.1587e-03 8.2122e-03 4.8110e-04 5.4688e-04 -6.0000e+00 1.3621e-03 3.4570e-03 5.8005e-04 1.0031e-04 3.4877e-05 -6.0000e+00 2.9025e-04 4.5526e-02 -1.6549e-04 12 1 1 12 1 1 -840.79 24.45 0.81 0.04553 0.04955 5 5 1 4 0 1057.930 33.25 19.91 24.45 20.85 3.6 900.27 -537 -507 -134 -59 505 590 595 681 300 421 85 -92 -63 -449 -398 -206 20 63 -174 19 436 162 294 425 358 203 315 25 -381 -261 -750 -398 236 126 79 17 112 -205 -266 -163 -416 -99 123 186 522 412 307 244 -48 -222 -600 -758 -597 -264 -312 94 -62 -25 8 130 147 111 460 208 248 -7 126 18 -570 -340 -314 -278 74 114 -48 -418 -80 -476 -368 -178 -295 -460 -214 -327 4 -15 -342 -213 92 -107 379 532 520 361 284 389 -86 -261 -679 -598 -905 -444 55 -238 -80 181 -293 -339 -425 -221 -12 142 33 393 431 414 737 328 376 162 -41 45 180 -73 596 502 177 295 549 -136 18 69 -407 -705 -104 -175 85 81 269 12 125 268 333 552 473 94 -242 -386 -750 -475 -528 -507 -136 -61 520 621 625 716 313 438 87 -95 -63 -453 -400 -209 20 65 -184 20 459 171 310 445 375 212 327 26 -388 -261 -750 -403 243 131 83 18 116 -213 -273 -167 -427 -102 126 194 546 430 317 251 -48 -221 -590 -743 -584 -259 -314 96 -63 -25 9 133 148 113 468 212 252 -7 126 17 -559 -334 -307 -270 73 112 -47 -413 -78 -460 -354 -172 -286 -444 -207 -322 4 -15 -337 -209 90 -105 376 530 523 361 283 378 -84 -250 -638 -562 -847 -426 53 -237 -80 179 -286 -330 -414 -218 -12 141 33 394 432 419 748 329 376 159 -40 44 174 -72 584 492 174 287 535 -134 18 66 -385 -673 -98 -169 83 79 265 12 125 264 329 548 469 93 -234 -369 -721 -452 SQ 20241208T111903.4Z 9108.471567 77 1 11.77 2 71.39 109.05 153.19 151.05 0.00 1 0.00 1 0 15 3.498e-03 3.464e-03 1.199e-04 1.197e-04 2.822181e+03 6.664827e+00 2.235135e+02 -6.000000e+00 1.783182e+02 274.70 -2.00 20.00 -2.00 505.27 0.00e+00 6.128627e-04 3.157876e-06 3.507822e-05 -6.000000e+00 9.425339e-05 274.70 -2.00 20.00 -2.00 500.52 0.00e+00 1.946753e-01 2.299905e-03 1.910168e-02 -6.000000e+00 6.758906e-02 225.35 -2.00 3.03 -2.00 502.10 0.00e+00 3.098 0.000 489.00 513.00 1 2.1466e+00 1.7527e-04 3.4918e-03 -6.0000e+00 5.1534e-03 -1.2530e-03 4.6037e-05 5.1864e-04 -6.0000e+00 1.3613e-03 1.6623e-01 9.7824e-04 9.6525e-06 3.2978e-05 -6.0000e+00 2.8995e-04 3.4867e-02 -1.2530e-04 10 0 0 10 0 0 99.85 24.46 0.83 0.03487 0.04165 544 56 1 4 0 21.620 33.50 20.06 24.46 21.19 3.6 903.00 -782 -346 -181 -1 372 486 516 499 313 365 229 -120 -207 -285 -340 -229 69 169 26 233 188 100 313 312 327 497 457 -197 -380 -483 -655 -537 162 121 130 243 63 -117 -192 -100 -178 -16 128 283 307 297 302 303 -75 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-514 -220 -92 -102 132 248 133 184 290 339 434 390 68 -348 -544 -584 -521 SQ 20241208T111915.3Z 9108.471705 77 2 11.77 2 71.35 109.04 153.17 150.96 0.00 1 0.00 1 0 15 3.639e-03 3.606e-03 1.801e-04 1.798e-04 2.786801e+03 9.988791e+00 2.195842e+02 -6.000000e+00 1.854986e+02 274.70 -2.00 20.00 -2.00 505.27 0.00e+00 6.123625e-04 4.739445e-06 3.530930e-05 -6.000000e+00 9.804828e-05 274.70 -2.00 20.00 -2.00 500.50 0.00e+00 1.952308e-01 3.454110e-03 1.909989e-02 -6.000000e+00 7.030789e-02 225.35 -2.00 3.03 -2.00 502.08 0.00e+00 3.091 0.000 489.00 513.00 1 2.9551e+00 2.6322e-04 3.4850e-03 -6.0000e+00 5.3607e-03 2.3577e-03 6.9187e-05 5.1471e-04 -6.0000e+00 1.4160e-03 7.4110e-02 9.9522e-04 1.4472e-05 3.2677e-05 -6.0000e+00 3.0162e-04 3.5003e-02 -1.2355e-04 10 0 0 10 0 0 99.95 24.46 0.82 0.03500 0.04191 544 56 1 4 0 21.620 33.25 20.06 24.46 21.28 3.6 903.00 -882 -399 -184 2 402 472 567 498 325 366 202 -144 -210 -284 -335 -212 102 171 75 245 164 117 321 330 359 508 485 -213 -449 -569 -791 -599 130 177 172 261 124 -64 -204 -83 -138 -38 176 307 307 332 356 330 -129 -396 -689 -991 -858 -544 -262 -40 128 64 101 217 326 334 427 391 242 114 18 -119 -435 -390 -293 -309 13 126 -19 -131 -125 -361 -522 -412 -432 -525 -316 -131 -59 -16 -80 -96 -80 -65 228 494 442 486 469 255 24 -310 -620 -855 -826 -517 12 -66 -5 10 -408 -405 -309 -211 -122 98 250 286 435 613 572 443 368 202 -12 34 307 185 232 318 177 264 485 181 26 22 -322 -484 -240 -81 -59 133 283 139 196 266 319 398 404 82 -377 -571 -646 -588 -861 -394 -186 2 412 494 593 523 338 379 206 -148 -213 -284 -335 -214 104 177 79 259 172 124 338 345 376 529 502 -221 -455 -568 -787 -605 133 184 182 273 128 -67 -209 -84 -141 -39 181 320 322 347 368 340 -131 -395 -677 -971 -838 -535 -263 -40 130 65 102 222 330 340 436 398 242 114 18 -118 -427 -382 -286 -300 13 125 -19 -130 -120 -349 -503 -397 -421 -509 -308 -129 -58 -16 -79 -94 -79 -65 224 495 441 489 463 250 24 -299 -584 -808 -775 -490 11 -66 -5 10 -402 -397 -302 -207 -121 98 252 286 434 615 579 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