File name: Pandora283s1_LaPaz_20241211_L2Fit_fout2c2d20240531p1-8.txt File generation date: 20241212T043217.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 283 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora283_OF_v3d20231025.txt Instrument calibration file used: Pandora283s1_CF_v2d20240531.txt Level 1 file used: Pandora283s1_LaPaz_20241211_L1_smca1c2d20240531p1-8.txt Full location name: Laboratory for Atmospheric Physics, UMSA, La Paz Short location name: LaPaz Country of location: Bolivia Location latitude [deg]: -16.5389 Location longitude [deg]: -68.0661 Location altitude [m]: 3420 Local noon date: 20241211 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 203 345 Nominal wavelengths inside fitting window [nm]: 305.0233 305.1640 305.3046 305.4453 305.5860 305.7266 305.8672 306.0078 306.1485 306.2891 306.4296 306.5702 306.7108 306.8513 306.9919 307.1324 307.2729 307.4134 307.5539 307.6944 307.8349 307.9754 308.1158 308.2563 308.3967 308.5371 308.6775 308.8179 308.9583 309.0987 309.2390 309.3794 309.5197 309.6600 309.8004 309.9407 310.0810 310.2213 310.3615 310.5018 310.6420 310.7823 310.9225 311.0627 311.2029 311.3431 311.4833 311.6235 311.7636 311.9038 312.0439 312.1840 312.3242 312.4643 312.6044 312.7444 312.8845 313.0246 313.1646 313.3046 313.4447 313.5847 313.7247 313.8647 314.0046 314.1446 314.2846 314.4245 314.5644 314.7044 314.8443 314.9842 315.1241 315.2639 315.4038 315.5437 315.6835 315.8233 315.9631 316.1029 316.2427 316.3825 316.5223 316.6621 316.8018 316.9416 317.0813 317.2210 317.3607 317.5004 317.6401 317.7797 317.9194 318.0590 318.1987 318.3383 318.4779 318.6175 318.7571 318.8967 319.0362 319.1758 319.3153 319.4549 319.5944 319.7339 319.8734 320.0129 320.1524 320.2918 320.4313 320.5707 320.7101 320.8495 320.9890 321.1283 321.2677 321.4071 321.5465 321.6858 321.8251 321.9645 322.1038 322.2431 322.3824 322.5216 322.6609 322.8002 322.9394 323.0786 323.2178 323.3570 323.4962 323.6354 323.7746 323.9138 324.0529 324.1920 324.3312 324.4703 324.6094 324.7485 324.8876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241211T105317.3Z 9111.453672 128 1 15.14 2 77.45 110.63 152.67 264.98 0.00 1 0.00 1 0 17 1.823e-01 1.068e-02 9.917e-02 4.255e-03 4.717522e-01 2.107452e-03 4.795930e-03 -6.000000e+00 1.012569e-01 225.21 -2.00 3.03 -2.00 318.95 0.00e+00 3.059348e-03 4.885880e-04 2.506615e-04 -6.000000e+00 4.366048e-03 274.75 -2.00 20.00 -2.00 318.40 0.00e+00 4.485 0.000 302.00 328.00 3 4.1532e+00 5.7471e-03 3.6309e-02 -6.0000e+00 2.5096e-01 2.9257e-02 6.6200e-03 2.0925e-02 -6.0000e+00 2.7341e-01 -2.1156e-02 5.0970e-03 1.0767e-02 -6.0000e+00 1.6234e-01 5.0514e-03 2.7455e-03 4.3762e-03 -6.0000e+00 6.9462e-02 2.3108e-04 -2.2886e-04 1.1309e-04 3.9297e-05 -6.0000e+00 4.6461e-03 3.5790e-02 -2.0689e-04 12 9 9 12 41 1 99.56 24.46 0.38 0.03579 0.03407 6 3 1 5 0 2161.920 33.25 20.10 24.46 19.71 3.4 889.36 -17385 -63887 175839 35099 -36870 44 -23094 -48593 15410 11317 -28335 -18907 -6182 -29983 1386 -843 -2898 -724 -11323 -12397 29745 1332 -667 924 7758 6436 2348 -4548 -1574 -6495 -13250 -1171 -199 4161 -6338 -11575 1285 3338 -4397 -447 -2785 -1704 434 3964 1474 1262 3156 -49 2398 -3448 1343 -2586 2703 3520 615 -1749 2908 -197 1034 667 2207 2652 1964 5772 371 -51 -429 90 896 1399 358 164 116 265 245 -106 -361 -3194 -1004 -685 -3046 -931 -546 -2891 -1381 -1544 -143 679 961 1433 191 1158 9 -1227 1045 -435 400 485 373 -271 311 -755 -1999 -656 -1206 -1605 -794 47 -947 515 682 354 702 -435 529 -496 -795 450 -36 369 285 615 772 379 298 291 -681 978 700 1108 -256 157 217 327 1 -133 -154 148 -22 244 -273 -981 -771 -411 -2757 730 568 -1101 1 -623 -1936 364 296 -1117 -737 -259 -1991 82 -59 -228 -60 -1123 -1307 2111 124 -65 96 808 713 273 -544 -176 -792 -1974 -180 -34 729 -1162 -1978 232 638 -1113 -129 -914 -589 141 1381 487 426 1051 -17 826 -1308 528 -1169 1253 1735 301 -905 1473 -102 517 329 1107 1447 1211 3790 248 -33 -280 58 580 1040 277 133 93 203 185 -72 -241 -2143 -663 -526 -2581 -871 -517 -2947 -1391 -1667 -161 782 1104 1582 198 1165 8 -1165 1058 -479 468 607 510 -373 397 -925 -2408 -789 -1496 -2122 -1031 64 -1322 779 1068 580 1131 -672 788 -703 -1124 655 -56 578 451 944 1198 569 428 422 -944 1346 1010 1772 -427 260 370 585 2 -256 -293 284 -42 459 -511 -1748 -1381 SS 20241211T110241.4Z 9111.460201 134 1 53.40 2 75.34 110.15 154.81 264.01 0.00 1 0.00 1 0 44 6.625e-01 1.827e-01 9.121e-02 3.405e-03 4.535615e-01 1.726824e-03 6.097535e-03 -6.000000e+00 3.678725e-01 225.21 -2.00 3.03 -2.00 318.60 0.00e+00 7.852779e-02 3.480319e-04 1.894874e-03 -6.000000e+00 1.597226e-02 274.75 -2.00 20.00 -2.00 318.05 0.00e+00 3.878 0.000 302.00 328.00 3 4.6765e+00 4.4679e-03 4.2197e-02 -6.0000e+00 9.1184e-01 1.0776e+00 4.9970e-03 5.1118e-02 -6.0000e+00 9.9305e-01 -5.9627e-01 3.8636e-03 2.3600e-02 -6.0000e+00 5.8983e-01 1.1293e-01 2.1800e-03 3.2082e-02 -6.0000e+00 2.5583e-01 1.0696e-04 -2.4665e-02 7.7673e-05 2.1669e-04 -6.0000e+00 1.6973e-02 7.5144e-02 -3.6165e-03 12 9 8 11 8 0 99.92 24.47 0.03 0.07514 -0.11020 19 2 1 5 0 2809.940 33.25 19.96 24.47 19.90 3.5 890.96 176360 147626 440557 218354 170479 168155 75100 55673 18584 11849 6211 -28820 32807 52636 104335 115989 125205 122093 124032 115118 158627 104950 73984 48539 20042 -4887 -27729 -10098 22958 56594 63781 82354 92154 94620 74342 59570 68244 54200 26434 11315 -6123 -4491 5561 19049 30092 44428 55924 55631 64230 57850 56472 48937 -113486 42764 30925 11091 5307 -7853 -4276 4000 16534 23663 25747 34228 32903 34989 31657 27767 22851 19459 15500 11615 7287 4450 2313 2723 1683 1094 5661 12570 11345 13376 10320 4256 1700 -267 1106 831 1686 5512 2940 3470 -1566 -6709 -3158 -3069 1897 5477 8331 9561 12119 9115 2248 -2870 -6740 -7816 -6988 -5287 -6659 -4259 -3361 -2189 -248 -2000 -1896 -2316 -3158 -2632 -3399 -2244 -1347 -1979 -2546 -3527 -2640 -2209 -1902 -2355 -3034 -967 742 1779 1895 2587 819 -357 258 105 1365 2782 2790 2742 900000 5095 7304 1463 5800 6057 4523 3491 2218 802 421 202 -1646 1776 4195 7656 10129 11973 13784 14909 15481 13168 12754 9458 5577 2203 -578 -4051 -1405 2904 6878 10123 14165 16860 17531 15107 12521 12758 11716 7522 3354 -2126 -1581 1981 6843 11082 16227 20224 21696 23615 22771 23269 22852 -178171 21583 16402 6378 2904 -4523 -2326 2141 8899 13936 15944 22162 22979 23013 19841 16995 14866 14479 12854 9304 5850 3684 1776 1853 1053 680 3742 9367 10008 11804 9898 4392 1848 -288 1235 965 1962 6049 3083 3500 -1484 -6338 -3084 -3484 2240 7246 11193 13038 16249 11170 2589 -3305 -8469 -10512 -9052 -7103 -9672 -6612 -5291 -3578 -393 -3047 -2836 -3244 -4388 -3801 -5279 -3448 -2098 -3029 -3999 -5378 -3802 -3037 -2660 -3261 -4292 -1511 1175 2952 3229 4521 1441 -669 496 205 2677 5338 5131 4773 900000 SS 20241211T111250.6Z 9111.467253 137 1 54.45 2 73.05 109.67 157.12 262.83 0.00 1 0.00 1 0 17 1.753e-02 6.603e-03 1.886e-03 5.457e-04 3.665047e-01 2.692259e-04 3.785001e-03 -6.000000e+00 9.736235e-03 225.21 -2.00 3.03 -2.00 317.31 0.00e+00 8.149455e-04 3.831002e-05 1.249052e-04 -6.000000e+00 4.196238e-04 274.75 -2.00 20.00 -2.00 316.73 0.00e+00 3.383 0.000 302.00 328.00 3 2.5132e+00 7.0630e-04 2.7579e-02 -6.0000e+00 2.4131e-02 -1.7199e-03 7.9479e-04 1.5947e-02 -6.0000e+00 2.6285e-02 -2.9119e-03 4.8934e-04 7.9460e-03 -6.0000e+00 1.5608e-02 -1.8801e-03 2.4829e-04 2.3878e-03 -6.0000e+00 6.6809e-03 2.8212e-03 2.5771e-04 1.4495e-05 2.3677e-05 -6.0000e+00 4.4640e-04 3.5056e-02 -1.1030e-04 11 8 0 10 0 0 99.62 24.48 0.32 0.03506 0.03699 230 24 1 5 0 236.720 33.50 19.96 24.48 20.15 3.4 892.80 -3731 -4283 -1280 -3801 -8732 -7324 -6422 -3210 -2045 -3573 -5124 -5901 -1959 -1996 682 126 468 130 1181 1081 2142 97 873 1082 877 900 75 -1098 -847 -559 116 1363 1582 -310 -3136 -3772 -2670 -1263 -521 -30 -734 -191 -63 165 262 380 420 -196 -270 -135 735 827 967 1171 864 809 751 511 233 158 818 1414 1937 2131 885 80 -512 -592 343 701 436 443 186 293 -60 -425 -950 -1554 -1202 -1067 -1399 -1284 -1868 -1895 -1106 -590 -24 331 589 805 744 182 -211 -221 114 -204 313 739 493 -172 -456 -834 -1111 -605 -793 -1009 -830 -475 -108 411 695 626 516 204 -83 29 -10 227 253 263 25 156 405 497 464 328 157 621 536 444 109 -58 -307 -90 -44 7 87 201 135 -161 -399 -511 -666 -327 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