File name: Pandora58s1_LaPorteTX_20211010_L2Fit_fwvt1c1d20210728p1-8.txt File generation date: 20251118T110341.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 58 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora58_OF_v4d20210621.txt Instrument calibration file used: Pandora58s1_CF_v1d20210728.txt Level 1 file used: Pandora58s1_LaPorteTX_20211010_L1_smca1c1d20210728p1-8.txt Full location name: University Of Houston Trailer Short location name: LaPorteTX Country of location: United States Location latitude [deg]: 29.6721 Location longitude [deg]: -95.0647 Location altitude [m]: 22 Local noon date: 20211010 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1673 1823 Nominal wavelengths inside fitting window [nm]: 492.0345 492.1551 492.2758 492.3964 492.5170 492.6376 492.7581 492.8787 492.9992 493.1197 493.2402 493.3607 493.4812 493.6017 493.7221 493.8425 493.9629 494.0833 494.2037 494.3240 494.4444 494.5647 494.6850 494.8053 494.9256 495.0458 495.1661 495.2863 495.4065 495.5267 495.6469 495.7670 495.8872 496.0073 496.1274 496.2475 496.3676 496.4876 496.6077 496.7277 496.8477 496.9677 497.0877 497.2076 497.3276 497.4475 497.5674 497.6873 497.8072 497.9271 498.0469 498.1667 498.2865 498.4063 498.5261 498.6459 498.7656 498.8854 499.0051 499.1248 499.2445 499.3641 499.4838 499.6034 499.7230 499.8426 499.9622 500.0818 500.2013 500.3208 500.4404 500.5599 500.6793 500.7988 500.9183 501.0377 501.1571 501.2765 501.3959 501.5153 501.6346 501.7539 501.8733 501.9926 502.1118 502.2311 502.3504 502.4696 502.5888 502.7080 502.8272 502.9464 503.0655 503.1847 503.3038 503.4229 503.5420 503.6610 503.7801 503.8991 504.0182 504.1372 504.2561 504.3751 504.4941 504.6130 504.7319 504.8508 504.9697 505.0886 505.2074 505.3263 505.4451 505.5639 505.6827 505.8015 505.9202 506.0389 506.1577 506.2764 506.3951 506.5137 506.6324 506.7510 506.8696 506.9882 507.1068 507.2254 507.3440 507.4625 507.5810 507.6995 507.8180 507.9365 508.0549 508.1734 508.2918 508.4102 508.5286 508.6469 508.7653 508.8836 509.0019 509.1202 509.2385 509.3568 509.4750 509.5933 509.7115 509.8297 509.9479 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20211010T130541.2Z 7953.545616 92 1 0.83 2 80.87 103.34 136.61 93.79 0.00 1 0.00 1 0 15 3.892e-03 3.866e-03 9.886e-04 9.872e-04 9.957764e+03 6.546477e+01 6.662689e+02 -6.000000e+00 2.123447e+02 291.71 -2.00 20.00 -2.00 505.30 0.00e+00 1.158239e-03 2.726351e-05 7.931734e-05 -6.000000e+00 1.094530e-04 291.71 -2.00 20.00 -2.00 500.50 0.00e+00 4.464457e-01 1.890324e-02 5.745508e-02 -6.000000e+00 7.472486e-02 227.22 -2.00 3.24 -2.00 502.09 0.00e+00 5.976 0.002 489.00 513.00 1 2.8132e+00 1.4494e-03 1.0042e-02 -6.0000e+00 5.7345e-03 -1.1596e-02 3.7415e-04 1.4810e-03 -6.0000e+00 1.5042e-03 4.7001e-02 1.5327e-03 7.7691e-05 7.1773e-05 -6.0000e+00 3.2613e-04 1.3136e-02 -9.6341e-05 12 9 1 12 1 1 81.64 22.81 1.69 0.01314 0.02377 6 117 1 4 0 94.440 25.58 20.02 22.81 32.55 17.9 1011.85 -894 -711 -194 245 584 589 948 913 743 328 255 -5 -363 -380 -404 -418 -31 171 90 432 324 105 279 320 144 269 284 132 -151 -444 -871 -735 -394 -232 -86 203 282 193 -18 -230 -135 -160 195 154 394 342 440 357 64 -173 -370 -830 -1010 -726 -522 -259 -42 178 336 413 215 194 327 475 361 224 54 -101 -305 -329 -382 -385 -237 -59 -159 -224 -121 -238 -531 -580 -368 -727 -507 -126 -286 -253 -10 -194 -101 -231 -146 51 37 309 397 492 286 142 -516 -755 -816 -552 -496 -330 -138 163 1 -112 -179 -173 -158 -11 139 336 349 688 794 574 433 426 185 117 97 151 78 229 137 87 387 227 51 201 66 -326 -218 -69 -6 -131 568 195 314 100 409 252 208 217 -74 -118 -553 -523 -555 -857 -690 -192 245 591 602 973 950 775 338 263 -5 -366 -382 -403 -418 -31 175 93 451 335 108 288 332 151 282 297 137 -155 -446 -867 -732 -393 -237 -90 213 293 198 -19 -234 -138 -164 199 159 408 356 456 371 66 -175 -369 -817 -990 -710 -518 -259 -42 182 346 422 220 198 335 488 369 226 54 -102 -304 -323 -374 -378 -234 -59 -159 -224 -120 -234 -515 -558 -354 -708 -496 -123 -282 -250 -10 -192 -99 -227 -144 50 37 308 393 478 277 135 -481 -699 -748 -510 -468 -320 -137 163 1 -111 -175 -169 -155 -11 139 337 351 691 796 579 440 432 184 116 95 149 76 225 135 86 380 223 51 198 64 -315 -209 -66 -6 -129 563 194 314 101 413 253 210 219 -74 -118 -547 -510 -545 SQ 20211010T131105.6Z 7953.549370 94 1 10.41 2 79.73 104.05 135.50 94.37 0.00 1 0.00 1 0 22 3.230e-03 3.204e-03 4.507e-04 4.499e-04 9.446435e+03 2.973761e+01 6.357087e+02 -6.000000e+00 1.762167e+02 291.71 -2.00 20.00 -2.00 505.29 0.00e+00 1.103994e-03 1.242006e-05 7.497830e-05 -6.000000e+00 9.081901e-05 291.71 -2.00 20.00 -2.00 500.46 0.00e+00 4.141819e-01 8.633259e-03 5.422682e-02 -6.000000e+00 6.198373e-02 227.22 -2.00 3.24 -2.00 502.05 0.00e+00 5.376 0.002 489.00 513.00 1 4.1935e+00 6.6201e-04 9.1588e-03 -6.0000e+00 4.7571e-03 -4.7991e-03 1.7109e-04 1.3948e-03 -6.0000e+00 1.2472e-03 1.2926e-02 1.3076e-03 3.5559e-05 6.7610e-05 -6.0000e+00 2.7057e-04 4.0324e-04 7.4550e-06 12 1 1 12 1 1 99.97 22.80 1.71 0.00040 0.00947 46 51 1 4 0 217.870 25.47 20.05 22.80 32.74 17.9 1013.50 -776 -589 -159 99 358 579 608 699 582 488 193 52 -154 -227 -299 -271 -146 15 113 212 293 58 132 190 72 227 358 107 -275 -306 -632 -501 -309 -72 -33 290 310 3 -71 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158 -9 142 176 84 255 316 135 281 269 -7 14 58 -281 -240 10 -225 20 375 330 181 283 172 214 176 165 -7 -277 -310 -548 -422 SQ 20211010T131546.7Z 7953.552624 97 1 5.87 2 78.75 104.68 134.54 94.86 0.00 1 0.00 1 0 22 3.117e-03 3.098e-03 1.109e-04 1.108e-04 8.633143e+03 7.251522e+00 5.803180e+02 -6.000000e+00 1.700749e+02 291.71 -2.00 20.00 -2.00 505.29 0.00e+00 9.913292e-04 3.058438e-06 6.827115e-05 -6.000000e+00 8.764947e-05 291.71 -2.00 20.00 -2.00 500.48 0.00e+00 3.755277e-01 2.123352e-03 5.081423e-02 -6.000000e+00 5.980314e-02 227.22 -2.00 3.24 -2.00 502.07 0.00e+00 4.945 0.001 489.00 513.00 1 9.0614e-01 1.6285e-04 8.4540e-03 -6.0000e+00 4.5901e-03 -1.0390e-02 4.2071e-05 1.2957e-03 -6.0000e+00 1.2030e-03 3.7019e-01 9.0181e-04 8.7994e-06 6.1392e-05 -6.0000e+00 2.6109e-04 -1.5753e-03 4.2955e-05 10 0 0 10 0 0 98.31 22.80 1.75 -0.00158 0.00468 695 157 1 4 0 8.240 25.47 19.97 22.80 32.95 18.0 1015.62 -765 -588 -211 37 440 607 626 648 530 431 294 55 -159 -236 -333 -256 -92 36 32 215 313 182 160 198 147 225 348 80 -273 -301 -545 -553 -304 -81 -17 228 230 -25 -145 -175 -129 -48 153 257 351 334 323 258 85 -189 -359 -651 -771 -642 -477 -294 -80 120 117 195 200 225 295 355 299 189 124 5 -211 -363 -288 -331 -201 -38 -104 -138 -81 -175 -406 -483 -387 -380 -291 -142 -194 -119 -118 -170 -181 -188 -94 100 153 178 394 359 174 56 -362 -594 -629 -605 -379 -191 -183 61 91 -149 -154 -213 -206 -64 194 302 393 583 614 477 300 329 111 58 130 172 49 215 212 114 251 301 11 64 27 -229 -253 -53 -131 28 325 300 173 263 227 216 262 184 -75 -260 -360 -511 -461 -737 -574 -210 38 446 626 651 673 552 449 302 56 -161 -236 -336 -255 -93 37 33 223 325 189 166 207 154 236 365 83 -283 -304 -545 -554 -305 -84 -18 239 239 -26 -149 -178 -131 -49 158 266 368 347 334 268 87 -192 -358 -641 -757 -630 -474 -294 -82 123 120 199 204 231 301 363 304 193 124 5 -209 -360 -282 -324 -199 -38 -103 -137 -80 -171 -393 -465 -372 -369 -284 -138 -191 -118 -116 -167 -178 -184 -92 99 152 179 389 350 167 53 -340 -555 -581 -557 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