File name: Pandora58s1_LaPorteTX_20211122_L2Fit_fout2c1d20210728p1-8.txt File generation date: 20251118T111421.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 58 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora58_OF_v4d20210621.txt Instrument calibration file used: Pandora58s1_CF_v1d20210728.txt Level 1 file used: Pandora58s1_LaPorteTX_20211122_L1_smca1c1d20210728p1-8.txt Full location name: University Of Houston Trailer Short location name: LaPorteTX Country of location: United States Location latitude [deg]: 29.6721 Location longitude [deg]: -95.0647 Location altitude [m]: 22 Local noon date: 20211122 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 248 390 Nominal wavelengths inside fitting window [nm]: 305.0025 305.1433 305.2840 305.4247 305.5654 305.7061 305.8468 305.9875 306.1281 306.2688 306.4094 306.5500 306.6906 306.8312 306.9718 307.1124 307.2529 307.3935 307.5340 307.6745 307.8151 307.9556 308.0960 308.2365 308.3770 308.5174 308.6579 308.7983 308.9387 309.0791 309.2195 309.3599 309.5002 309.6406 309.7809 309.9212 310.0615 310.2018 310.3421 310.4824 310.6227 310.7629 310.9032 311.0434 311.1836 311.3238 311.4640 311.6042 311.7443 311.8845 312.0246 312.1648 312.3049 312.4450 312.5851 312.7252 312.8652 313.0053 313.1453 313.2853 313.4254 313.5654 313.7054 313.8453 313.9853 314.1253 314.2652 314.4051 314.5451 314.6850 314.8249 314.9647 315.1046 315.2445 315.3843 315.5241 315.6640 315.8038 315.9436 316.0833 316.2231 316.3629 316.5026 316.6423 316.7821 316.9218 317.0615 317.2011 317.3408 317.4805 317.6201 317.7597 317.8994 318.0390 318.1786 318.3181 318.4577 318.5973 318.7368 318.8763 319.0159 319.1554 319.2949 319.4343 319.5738 319.7133 319.8527 319.9922 320.1316 320.2710 320.4104 320.5498 320.6891 320.8285 320.9678 321.1072 321.2465 321.3858 321.5251 321.6644 321.8036 321.9429 322.0821 322.2214 322.3606 322.4998 322.6390 322.7782 322.9174 323.0565 323.1957 323.3348 323.4739 323.6130 323.7521 323.8912 324.0303 324.1693 324.3084 324.4474 324.5864 324.7254 324.8644 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211122T142540.4Z 7996.601163 338 1 14.49 2 72.92 126.30 75.97 292.04 0.00 1 0.00 1 0 25 4.628e-02 6.072e-03 3.546e-02 3.326e-03 4.347369e-01 1.680537e-03 4.812565e-03 -6.000000e+00 2.617617e-02 224.88 -2.00 3.24 -2.00 318.98 0.00e+00 3.490985e-04 4.102795e-04 2.139486e-04 -6.000000e+00 1.190910e-03 288.07 -2.00 20.00 -2.00 318.21 0.00e+00 3.353 0.000 302.00 328.00 3 3.7597e+00 4.6388e-03 3.9231e-02 -6.0000e+00 6.4532e-02 -8.6011e-03 5.4142e-03 2.0815e-02 -6.0000e+00 6.9920e-02 -8.6542e-04 4.0575e-03 1.0319e-02 -6.0000e+00 4.1858e-02 -5.5992e-03 2.1742e-03 3.0384e-03 -6.0000e+00 1.8413e-02 2.6417e-04 -3.1620e-04 9.1703e-05 3.1145e-05 -6.0000e+00 1.2241e-03 -1.6464e-03 4.9964e-05 12 1 1 12 1 1 96.47 22.40 0.34 -0.00165 -0.00402 11 9 1 5 0 1192.700 25.17 20.00 22.40 21.83 20.0 957.08 900000 -9579 -10419 -9567 -15690 -28550 -17015 -3667 10268 9795 7128 -4057 10944 -5558 4492 -7508 15537 4156 -3864 4032 -5301 9219 2987 -1018 -8437 5155 -5073 -3094 -259 1481 -1995 6950 -1350 -1476 621 2959 -4316 -3588 -4077 -4414 -2572 -1283 -51 -357 95 1493 45 1173 -978 505 128 1038 1466 340 -838 2429 842 1049 1397 856 189 87 911 689 -141 685 829 -1794 2104 254 -36 303 423 491 -212 -30 -1421 -173 -540 243 -122 -339 -1604 -1157 -1041 -773 312 -541 113 194 581 369 763 533 773 148 224 489 -36 -460 -454 -19 110 335 -555 -1202 -708 -232 -407 184 94 584 236 219 211 -292 346 181 28 -483 -720 -19 -29 93 2 181 -444 1570 836 360 156 -65 350 -271 279 -279 -59 668 -261 -499 -46 -486 116 900000 -260 -310 -283 -453 -871 -477 -102 286 303 235 -155 410 -284 252 -559 1023 329 -341 347 -523 792 276 -105 -1019 582 -656 -383 -30 163 -244 888 -205 -246 100 443 -722 -686 -917 -1210 -766 -409 -17 -122 32 509 16 404 -347 180 48 414 635 155 -409 1193 435 548 716 431 96 47 522 426 -94 444 503 -1120 1267 171 -27 241 342 387 -158 -21 -932 -109 -336 170 -93 -286 -1473 -1124 -1039 -805 342 -610 129 217 630 380 743 496 745 156 252 606 -47 -618 -603 -24 130 382 -662 -1520 -934 -313 -569 271 144 930 381 349 321 -425 493 259 42 -751 -1167 -30 -45 142 3 261 -626 2157 1193 547 253 -109 595 -470 500 -525 -112 1299 -521 -989 -90 -915 212 SS 20211122T143037.1Z 7996.604596 341 1 11.23 2 72.06 127.11 76.93 292.53 0.00 1 0.00 1 0 25 4.006e-02 5.803e-03 2.220e-02 2.497e-03 4.153827e-01 1.251757e-03 4.616513e-03 -6.000000e+00 2.264319e-02 224.88 -2.00 3.24 -2.00 318.71 0.00e+00 3.805605e-04 2.797385e-04 1.278560e-04 -6.000000e+00 1.028047e-03 288.07 -2.00 20.00 -2.00 317.92 0.00e+00 3.202 0.000 302.00 328.00 3 3.1739e+00 3.4124e-03 3.7452e-02 -6.0000e+00 5.5820e-02 -1.0202e-02 3.9439e-03 1.9807e-02 -6.0000e+00 6.0458e-02 -8.8676e-03 2.8203e-03 9.8191e-03 -6.0000e+00 3.6218e-02 -5.4753e-04 1.5100e-03 2.8494e-03 -6.0000e+00 1.5825e-02 5.5986e-04 -4.7259e-04 6.8303e-05 2.9292e-05 -6.0000e+00 1.0508e-03 -2.4055e-04 -3.8907e-06 12 1 1 12 9 1 84.45 22.40 0.26 -0.00024 -0.00379 17 18 1 5 0 614.320 25.28 20.00 22.40 22.00 19.9 958.35 10491 927 -13848 118 -23088 1383 -26288 -403 -12624 -6984 -5410 -8782 -5805 -5869 754 -4669 7033 -2071 5875 -3432 -1309 -2378 114 -1878 -2121 -623 -1706 199 -1766 3390 -2527 4612 -1024 933 -3299 1989 -2452 -1921 -592 -2379 -463 -1585 -78 -1478 370 -557 5 -1162 523 -1551 1545 454 1744 1396 1015 2031 663 977 140 723 -83 649 1399 1327 730 671 1035 -485 1324 477 293 141 352 29 -310 -323 -87 0 62 37 -1065 -430 -2109 -992 -1571 -610 -464 -312 -244 -52 441 600 642 651 1255 569 733 429 -228 -578 -291 -578 -519 217 -690 -497 -664 -518 -485 -62 -293 118 157 386 179 152 571 272 238 -331 -206 -416 -100 120 533 433 214 1359 735 261 498 22 46 150 52 232 -491 137 -256 -362 -103 -301 -237 281 30 -554 4 -923 40 -1035 -14 -564 -325 -256 -442 -322 -392 57 -401 594 -205 573 -387 -151 -278 13 -235 -289 -89 -255 29 -243 434 -367 709 -188 184 -670 362 -485 -404 -150 -741 -151 -566 -29 -569 141 -215 2 -452 201 -619 632 206 797 687 531 1090 373 555 79 396 -46 379 844 887 523 470 675 -311 862 335 233 114 291 23 -249 -236 -60 0 41 26 -875 -377 -1975 -975 -1642 -647 -524 -351 -279 -58 488 642 633 610 1211 615 853 539 -306 -776 -391 -748 -609 256 -836 -621 -872 -715 -679 -89 -462 190 254 600 270 222 801 392 348 -522 -325 -652 -158 183 808 630 297 1884 1036 393 783 37 76 258 91 433 -928 262 -500 -703 -192 -553 -432 SS 20211122T143459.4Z 7996.607632 344 1 23.78 2 71.31 127.84 77.78 292.97 0.00 1 0.00 1 0 25 5.611e-02 6.872e-03 2.701e-02 3.195e-03 3.987063e-01 1.603251e-03 4.446110e-03 -6.000000e+00 3.171303e-02 224.88 -2.00 3.24 -2.00 318.65 0.00e+00 4.640000e-04 3.520924e-04 1.561842e-04 -6.000000e+00 1.440126e-03 288.07 -2.00 20.00 -2.00 317.87 0.00e+00 3.081 0.000 302.00 328.00 3 4.4679e+00 4.3615e-03 3.6020e-02 -6.0000e+00 7.8179e-02 -7.3801e-03 5.0268e-03 1.9022e-02 -6.0000e+00 8.4679e-02 -1.1861e-03 3.5477e-03 9.4391e-03 -6.0000e+00 5.0727e-02 -3.0927e-03 1.8982e-03 2.7266e-03 -6.0000e+00 2.2162e-02 1.7516e-04 -5.7360e-04 8.8123e-05 2.8925e-05 -6.0000e+00 1.4719e-03 -2.7796e-04 -5.1560e-05 12 9 1 12 1 1 99.12 22.40 0.26 -0.00028 -0.00459 10 5 1 5 0 2146.300 25.28 20.00 22.40 22.14 19.9 959.30 27727 -4340 -14740 -13585 -4483 -37260 -14148 -1876 19517 -10597 5130 -13873 9927 -10090 -1913 1497 7784 5572 -5161 -623 -10660 6750 5870 -4934 -2750 -2811 -4057 -3017 -350 -2666 -3368 3580 4490 636 -666 1661 -5321 -696 -4031 -2975 -2590 1045 2409 1819 -895 -232 752 1801 1159 -1256 1255 1069 1600 -613 748 1927 811 366 1607 16 886 -502 805 1269 187 436 609 -1670 2260 1013 -482 238 -655 -323 354 -289 619 -259 1338 -656 -355 -768 -756 -1266 -1015 -939 -489 -364 391 -411 433 128 -261 1217 1083 -254 63 154 -85 44 -514 -264 51 -517 166 -1499 -896 -614 122 436 -6 335 78 49 229 137 950 380 322 -650 -426 34 495 -501 267 665 -597 1589 936 560 398 -376 135 -150 -167 141 -251 286 -268 -426 -113 -333 8 670 -163 -640 -580 -165 -1703 -548 -72 699 -543 240 -777 495 -737 -155 131 707 551 -606 -74 -1397 774 685 -658 -389 -425 -639 -457 -49 -385 -503 564 790 127 -133 306 -1091 -151 -1066 -941 -904 380 904 706 -359 -93 300 706 458 -516 514 480 753 -316 403 1030 453 208 886 9 484 -295 501 845 134 303 405 -1096 1474 735 -381 200 -553 -271 278 -213 417 -169 875 -478 -283 -678 -718 -1251 -1033 -1004 -555 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