File name: Pandora58s1_LaPorteTX_20220110_L2Fit_fout2c1d20210728p1-8.txt File generation date: 20251118T112459.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 58 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora58_OF_v4d20210621.txt Instrument calibration file used: Pandora58s1_CF_v1d20210728.txt Level 1 file used: Pandora58s1_LaPorteTX_20220110_L1_smca1c1d20210728p1-8.txt Full location name: University Of Houston Trailer Short location name: LaPorteTX Country of location: United States Location latitude [deg]: 29.6721 Location longitude [deg]: -95.0647 Location altitude [m]: 22 Local noon date: 20220110 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 248 390 Nominal wavelengths inside fitting window [nm]: 305.0025 305.1433 305.2840 305.4247 305.5654 305.7061 305.8468 305.9875 306.1281 306.2688 306.4094 306.5500 306.6906 306.8312 306.9718 307.1124 307.2529 307.3935 307.5340 307.6745 307.8151 307.9556 308.0960 308.2365 308.3770 308.5174 308.6579 308.7983 308.9387 309.0791 309.2195 309.3599 309.5002 309.6406 309.7809 309.9212 310.0615 310.2018 310.3421 310.4824 310.6227 310.7629 310.9032 311.0434 311.1836 311.3238 311.4640 311.6042 311.7443 311.8845 312.0246 312.1648 312.3049 312.4450 312.5851 312.7252 312.8652 313.0053 313.1453 313.2853 313.4254 313.5654 313.7054 313.8453 313.9853 314.1253 314.2652 314.4051 314.5451 314.6850 314.8249 314.9647 315.1046 315.2445 315.3843 315.5241 315.6640 315.8038 315.9436 316.0833 316.2231 316.3629 316.5026 316.6423 316.7821 316.9218 317.0615 317.2011 317.3408 317.4805 317.6201 317.7597 317.8994 318.0390 318.1786 318.3181 318.4577 318.5973 318.7368 318.8763 319.0159 319.1554 319.2949 319.4343 319.5738 319.7133 319.8527 319.9922 320.1316 320.2710 320.4104 320.5498 320.6891 320.8285 320.9678 321.1072 321.2465 321.3858 321.5251 321.6644 321.8036 321.9429 322.0821 322.2214 322.3606 322.4998 322.6390 322.7782 322.9174 323.0565 323.1957 323.3348 323.4739 323.6130 323.7521 323.8912 324.0303 324.1693 324.3084 324.4474 324.5864 324.7254 324.8644 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220110T135805.8Z 8045.582011 109 1 48.91 2 82.84 120.28 139.07 24.32 0.00 1 0.00 1 0 25 6.222e-01 1.124e-02 2.808e-01 5.069e-03 7.860618e-01 2.904701e-03 8.267570e-03 -6.000000e+00 3.601107e-01 224.33 -2.00 3.24 -2.00 321.71 0.00e+00 5.088692e-05 1.652089e-03 2.346609e-03 -6.000000e+00 1.842090e-02 285.21 -2.00 20.00 -2.00 321.22 0.00e+00 7.384 0.005 302.00 328.00 3 1.1522e+00 1.1081e-02 8.3842e-02 -6.0000e+00 8.9701e-01 7.1068e-02 1.7488e-02 4.4180e-02 -6.0000e+00 9.7805e-01 -1.1740e-01 1.9192e-02 2.3805e-02 -6.0000e+00 5.7413e-01 4.6134e-02 8.6971e-03 7.3278e-03 -6.0000e+00 2.5260e-01 5.6946e-05 -9.2830e-04 1.3996e-04 8.9771e-05 -6.0000e+00 1.7309e-02 -2.9446e-03 -1.5046e-05 12 8 8 10 0 0 85.33 21.56 0.48 -0.00294 -0.00992 75 17 1 5 0 652.070 24.56 19.80 21.56 15.04 22.0 927.25 900000 -246945 900000 -245352 900000 -246907 -280786 900000 900000 900000 -288985 900000 900000 58395 -169785 900000 37745 900000 -134118 -104256 -114504 -73670 900000 -67448 59601 -55677 -119378 -72277 17402 -23238 72476 -23317 -3033 -41320 -45662 -24523 -56291 10283 -41278 46101 -26708 36656 15326 61665 2387 8645 17173 5058 17248 -6795 13022 12097 19425 -14796 15562 23231 7012 -936 1076 7869 -4676 729 -9335 12468 8254 13384 3497 4924 7387 6856 2725 -2376 -1126 -1037 6734 1689 5380 2408 2679 2643 3501 2191 -682 -998 -2249 -1646 1224 224 -885 582 746 1953 -466 902 -2154 -1029 -763 1194 -512 -969 -1200 -701 -1665 -1841 -1481 -2039 -1386 -1534 -649 724 -114 64 -57 1059 437 -89 826 910 446 282 -366 195 597 -40 58 982 189 487 473 -228 915 -347 103 -112 -127 -504 -126 433 -279 -202 -4 -76 80 900000 -1218 900000 -1430 900000 -1329 -2267 900000 900000 900000 -4406 900000 900000 288 -1980 900000 186 900000 -2165 -1356 -1746 -760 900000 -756 294 -699 -2998 -1135 109 -229 358 -345 -45 -1038 -1229 -517 -1717 189 -1592 930 -1330 1085 605 1604 115 399 755 263 851 -463 818 811 1374 -1642 1401 2072 778 -115 128 844 -567 90 -1455 1825 1422 2267 648 927 1476 1601 704 -699 -334 -296 1646 422 1179 536 648 704 1120 837 -307 -490 -1192 -930 714 138 -520 357 434 1049 -245 472 -1279 -657 -574 1031 -515 -1041 -1260 -669 -1421 -1475 -1238 -1849 -1315 -1556 -712 828 -150 93 -88 1620 649 -127 1141 1295 674 451 -598 306 889 -57 82 1326 248 631 677 -383 1624 -686 216 -251 -289 -1233 -320 1111 -730 -521 -10 -172 181 SS 20220110T140855.5Z 8045.589531 112 1 48.80 2 80.82 121.80 138.04 27.87 0.00 1 0.00 1 0 25 4.158e-01 7.145e-03 1.252e-01 2.352e-03 6.651673e-01 1.247946e-03 7.063744e-03 -6.000000e+00 2.346658e-01 224.33 -2.00 3.24 -2.00 321.06 0.00e+00 2.123434e-03 5.920401e-04 4.603633e-04 -6.000000e+00 1.056990e-02 285.21 -2.00 20.00 -2.00 320.49 0.00e+00 5.952 0.002 302.00 328.00 3 1.2876e+00 4.1992e-03 6.7210e-02 -6.0000e+00 5.7841e-01 1.9719e-02 5.9061e-03 3.3116e-02 -6.0000e+00 6.2724e-01 -3.7175e-02 6.0828e-03 1.7798e-02 -6.0000e+00 3.7499e-01 9.3463e-03 2.9153e-03 6.4330e-03 -6.0000e+00 1.6473e-01 2.1171e-04 -7.8440e-04 6.3155e-05 6.4141e-05 -6.0000e+00 1.0994e-02 -3.3503e-03 1.7658e-05 11 8 0 10 0 0 86.30 21.54 0.36 -0.00335 -0.00924 156 35 1 5 0 312.800 24.56 20.11 21.54 15.35 21.9 928.49 900000 -139042 -63690 -191512 -99344 -125937 -206369 -131276 -137315 -53568 -167342 -47052 -88639 -83264 -87038 -34206 -15693 -5543 -14333 -53427 -25369 -40131 16790 -30909 -12358 -26121 -41688 -35713 -4666 -13813 -14870 11973 -15194 -6289 -7205 -2392 -17009 -6079 -10573 3338 -5298 2581 1429 4889 1721 1822 2579 -91 4954 335 5158 2255 5454 -644 3241 5281 2881 1643 -1047 1873 -1017 961 -565 3909 1270 3396 2190 1622 3496 2071 1449 421 -190 352 1268 1740 1627 -784 395 857 726 -423 -2082 -1619 -2043 -1136 -572 -142 -244 332 447 1092 276 715 -7 -71 180 322 26 -643 -376 -536 -274 -403 -740 -1458 -862 -961 -463 454 -13 578 148 431 -257 657 526 175 365 -311 -260 -197 570 -398 179 358 206 804 454 7 427 -130 383 146 -190 -428 -429 344 -9 -205 -5 -180 67 900000 -893 -219 -2236 -478 -751 -2625 -994 -1291 -246 -2338 -237 -833 -974 -1377 -400 -180 -65 -204 -1103 -460 -778 208 -612 -249 -599 -1173 -946 -97 -297 -372 282 -564 -244 -287 -87 -752 -280 -630 214 -436 218 120 415 154 167 242 -9 493 37 601 307 807 -112 586 989 579 342 -220 372 -209 207 -140 984 365 972 618 464 1049 726 585 185 -86 153 509 627 532 -254 135 342 346 -238 -1251 -1045 -1407 -832 -443 -114 -201 267 341 770 185 471 -5 -58 161 334 31 -808 -457 -598 -272 -378 -732 -1569 -970 -1150 -595 605 -20 895 238 686 -418 1000 780 268 589 -506 -432 -319 933 -636 276 529 294 1118 688 12 786 -246 764 308 -429 -987 -1029 833 -21 -500 -10 -414 144 SS 20220110T141731.5Z 8045.595503 117 1 48.80 2 79.25 123.04 137.14 30.58 0.00 1 0.00 1 0 25 3.280e-01 6.895e-03 1.646e-01 3.009e-03 6.048823e-01 1.591418e-03 6.549735e-03 -6.000000e+00 1.851439e-01 224.33 -2.00 3.24 -2.00 320.79 0.00e+00 8.007479e-04 6.851689e-04 1.283468e-03 -6.000000e+00 8.335986e-03 285.21 -2.00 20.00 -2.00 320.20 0.00e+00 5.158 0.002 302.00 328.00 3 2.4914e+00 5.1102e-03 5.9108e-02 -6.0000e+00 4.5636e-01 -2.1071e-02 6.8500e-03 3.0564e-02 -6.0000e+00 4.9482e-01 1.8966e-02 6.8030e-03 1.5941e-02 -6.0000e+00 2.9582e-01 -1.3955e-02 3.3487e-03 4.8091e-03 -6.0000e+00 1.2999e-01 1.4238e-04 -2.0929e-04 8.2985e-05 5.7918e-05 -6.0000e+00 8.6690e-03 -3.1271e-03 1.3091e-04 11 8 0 10 0 0 99.92 21.52 0.30 -0.00313 -0.00470 115 26 1 5 0 424.310 24.56 19.93 21.52 15.37 21.9 928.40 900000 -50985 -129274 -69890 -76060 -81415 -108284 -48982 -11653 -49305 -113499 -54079 247843 -72168 -4655 -42623 24608 1353 -3591 -45595 -7283 8310 6962 7037 -24840 5421 -54076 -5345 -22380 1862 -247 11104 -5465 -5080 -3257 -5496 -4646 -5852 -7871 -318 -1156 -1157 4341 2862 2709 4709 3097 2473 232 2597 462 5729 -242 1066 -1536 7897 1697 486 861 2746 284 958 -929 1662 2088 -997 2066 -977 4093 1831 403 -16 -1081 491 752 2141 -760 -922 -1919 524 -820 776 -1624 -1525 -1498 -1135 203 -293 135 178 886 -613 -157 -676 -539 -254 201 1258 -311 -19 -752 215 -1448 -47 -1250 -880 -886 -502 19 718 835 528 569 813 456 61 218 -323 463 -569 -432 145 -48 -244 176 634 -667 733 -122 132 407 5 -237 -177 -309 -444 -175 326 242 -76 79 -309 291 900000 -231 -1448 -447 -487 -521 -953 -274 -53 -368 -1725 -490 727 -1213 -51 -771 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