File name: Pandora63s1_LaPorteTX_20220913_L2Fit_fwvt1c14d20220908p1-8.txt File generation date: 20250514T182015.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 63 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora63_OF_v2d20210219.txt Instrument calibration file used: Pandora63s1_CF_v14d20220908.txt Level 1 file used: Pandora63s1_LaPorteTX_20220913_L1_smca1c14d20220908p1-8.txt Full location name: University Of Houston Trailer Short location name: LaPorteTX Country of location: United States Location latitude [deg]: 29.6721 Location longitude [deg]: -95.0647 Location altitude [m]: 22 Local noon date: 20220913 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1555 1703 Nominal wavelengths inside fitting window [nm]: 492.1184 492.2403 492.3622 492.4841 492.6059 492.7278 492.8496 492.9714 493.0932 493.2150 493.3367 493.4585 493.5802 493.7019 493.8236 493.9453 494.0669 494.1886 494.3102 494.4318 494.5534 494.6750 494.7965 494.9181 495.0396 495.1611 495.2826 495.4041 495.5255 495.6470 495.7684 495.8898 496.0112 496.1326 496.2539 496.3753 496.4966 496.6179 496.7392 496.8605 496.9817 497.1030 497.2242 497.3454 497.4666 497.5878 497.7089 497.8301 497.9512 498.0723 498.1934 498.3145 498.4355 498.5566 498.6776 498.7986 498.9196 499.0406 499.1615 499.2825 499.4034 499.5243 499.6452 499.7661 499.8869 500.0078 500.1286 500.2494 500.3702 500.4909 500.6117 500.7324 500.8532 500.9739 501.0945 501.2152 501.3359 501.4565 501.5771 501.6977 501.8183 501.9389 502.0594 502.1800 502.3005 502.4210 502.5415 502.6619 502.7824 502.9028 503.0233 503.1437 503.2640 503.3844 503.5047 503.6251 503.7454 503.8657 503.9860 504.1062 504.2265 504.3467 504.4669 504.5871 504.7073 504.8275 504.9476 505.0677 505.1879 505.3080 505.4280 505.5481 505.6681 505.7882 505.9082 506.0282 506.1481 506.2681 506.3880 506.5080 506.6279 506.7478 506.8676 506.9875 507.1073 507.2271 507.3469 507.4667 507.5865 507.7063 507.8260 507.9457 508.0654 508.1851 508.3048 508.4244 508.5440 508.6637 508.7833 508.9028 509.0224 509.1420 509.2615 509.3810 509.5005 509.6200 509.7394 509.8589 509.9783 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-249: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 250-398: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20220913T121721.5Z 8291.512054 38 1 32.74 2 87.93 86.94 53.67 260.20 0.00 1 0.00 1 0 29 1.173e-02 1.154e-02 4.869e-04 4.837e-04 1.992106e+04 3.609934e+01 1.267815e+03 -6.000000e+00 6.771138e+02 293.63 -2.00 20.00 -2.00 505.48 0.00e+00 4.549509e-03 1.379044e-05 2.481794e-04 -6.000000e+00 3.384447e-04 293.63 -2.00 20.00 -2.00 501.21 0.00e+00 1.284574e+00 9.163302e-03 1.203519e-01 -6.000000e+00 2.307061e-01 228.57 -2.00 3.24 -2.00 502.69 0.00e+00 15.740 0.046 489.00 513.00 1 3.0878e+00 7.0305e-04 2.6269e-02 -6.0000e+00 1.7761e-02 -6.6222e-02 1.7529e-04 3.1831e-03 -6.0000e+00 4.5907e-03 7.8876e-03 2.3747e-03 4.1658e-05 1.2655e-04 -6.0000e+00 1.1400e-03 -2.7519e-03 -3.7878e-05 12 8 8 10 0 0 27.54 17.23 2.48 -0.00275 0.01372 85 19 1 4 0 385.090 20.46 14.98 17.23 28.76 12.6 972.73 -3074 -1845 -859 -15 952 1740 1736 1481 1131 448 -172 -859 -1194 -1525 -1752 -1136 -284 514 771 903 782 840 1208 1406 1272 1137 742 -361 -1426 -2039 -2023 -1115 203 733 558 346 40 -368 -614 -227 -101 516 1168 1413 1555 1406 1049 480 -368 -1245 -1903 -2206 -1486 -430 373 782 1171 1112 1032 955 1142 1074 1174 889 314 -99 -442 -988 -1353 -1386 -1309 -845 -307 -272 -763 -1204 -1601 -1726 -1621 -1464 -1341 -1031 -684 -412 -643 -378 -372 -54 397 1076 1621 1943 1991 1372 964 163 -633 -1689 -2633 -2652 -1746 -819 114 30 -338 -735 -949 -852 -566 -321 309 854 1250 1832 2452 2393 1855 981 416 46 200 704 1072 954 933 654 443 549 162 -419 -810 -1250 -1602 -1244 -712 -239 264 584 619 659 699 771 1048 758 196 -664 -1596 -1853 -1549 -2697 -1652 -742 -14 858 1591 1611 1384 1054 414 -157 -784 -1081 -1375 -1584 -1034 -263 486 741 871 757 816 1178 1382 1260 1127 734 -354 -1375 -1929 -1910 -1069 200 698 540 334 39 -351 -586 -217 -98 503 1151 1409 1560 1412 1047 474 -359 -1195 -1797 -2067 -1397 -413 368 789 1190 1134 1055 981 1180 1118 1222 922 323 -100 -446 -992 -1351 -1375 -1300 -846 -311 -277 -775 -1205 -1580 -1690 -1579 -1425 -1310 -1014 -680 -414 -651 -382 -373 -54 392 1065 1620 1950 1973 1324 896 147 -598 -1586 -2470 -2502 -1586 -777 113 31 -355 -771 -993 -893 -599 -326 316 874 1277 1873 2528 2514 1987 1059 444 48 206 719 1099 990 974 687 467 580 172 -441 -843 -1297 -1676 -1321 -768 -261 293 658 707 722 772 855 1158 836 215 -724 -1730 -2006 -1691 SO 20220913T121928.7Z 8291.513526 41 1 32.53 2 87.47 87.20 54.11 260.51 0.00 1 0.00 1 0 29 1.013e-02 9.942e-03 3.612e-04 3.590e-04 1.928246e+04 2.680213e+01 1.223446e+03 -6.000000e+00 5.846777e+02 293.63 -2.00 20.00 -2.00 505.49 0.00e+00 4.127223e-03 1.025583e-05 2.281029e-04 -6.000000e+00 2.922480e-04 293.63 -2.00 20.00 -2.00 501.18 0.00e+00 1.285709e+00 6.823401e-03 1.178575e-01 -6.000000e+00 1.991834e-01 228.57 -2.00 3.24 -2.00 502.67 0.00e+00 14.573 0.037 489.00 513.00 1 2.7007e+00 5.2447e-04 2.4305e-02 -6.0000e+00 1.5334e-02 -6.1407e-02 1.2981e-04 3.0843e-03 -6.0000e+00 3.9630e-03 1.3796e-02 1.6979e-03 3.0985e-05 1.3016e-04 -6.0000e+00 9.8417e-04 1.8103e-02 -1.5573e-04 12 8 8 10 0 0 -4.04 17.23 1.79 0.01810 0.02988 135 30 1 4 0 240.920 20.46 15.00 17.23 28.80 12.6 972.89 -2540 -1552 -546 53 919 1541 1494 1390 968 412 -210 -778 -999 -1338 -1421 -1093 -162 460 567 707 716 768 984 1232 1099 1024 532 -325 -1303 -1707 -1836 -943 281 614 452 282 31 -369 -448 -203 -48 471 848 1179 1327 1283 956 381 -364 -1040 -1664 -1836 -1210 -263 234 676 899 896 876 884 942 905 1014 696 206 -120 -393 -760 -1144 -1207 -1116 -719 -231 -228 -635 -1111 -1418 -1491 -1424 -1303 -1214 -840 -575 -405 -477 -323 -272 74 388 921 1504 1740 1419 1326 894 194 -495 -1547 -2388 -2265 -1646 -747 -85 -113 -341 -738 -906 -718 -474 -278 206 664 1023 1519 2083 2046 1554 929 428 122 137 762 906 836 765 562 388 464 177 -446 -668 -1132 -1486 -1020 -602 -369 141 529 573 629 647 684 882 800 265 -606 -1321 -1544 -1348 -2210 -1381 -499 50 828 1411 1389 1300 903 381 -192 -708 -902 -1203 -1278 -994 -149 434 545 683 692 745 960 1209 1086 1013 524 -318 -1249 -1603 -1721 -898 274 618 462 288 31 -372 -450 -204 -49 456 833 1171 1324 1280 947 374 -352 -1045 -1644 -1797 -1189 -264 228 675 906 905 885 898 963 931 1043 714 209 -120 -390 -750 -1123 -1177 -1088 -708 -230 -228 -635 -1094 -1376 -1433 -1363 -1246 -1166 -812 -562 -400 -474 -320 -268 73 377 899 1481 1723 1392 1261 867 183 -458 -1424 -2193 -2088 -1556 -696 -84 -115 -352 -760 -929 -737 -491 -292 219 706 1086 1613 2113 2115 1635 982 448 125 146 804 961 849 782 578 400 479 183 -458 -679 -1145 -1516 -1053 -633 -394 153 581 638 710 736 780 1004 907 298 -679 -1468 -1711 -1507 SO 20220913T122135.1Z 8291.514989 44 1 32.56 2 87.01 87.46 54.55 260.83 0.00 1 0.00 1 0 29 9.095e-03 8.930e-03 2.748e-04 2.735e-04 1.844392e+04 2.061647e+01 1.176421e+03 -6.000000e+00 5.248011e+02 293.63 -2.00 20.00 -2.00 505.46 0.00e+00 3.588546e-03 7.873886e-06 2.008874e-04 -6.000000e+00 2.623160e-04 293.63 -2.00 20.00 -2.00 501.08 0.00e+00 1.230463e+00 5.248771e-03 1.081949e-01 -6.000000e+00 1.787788e-01 228.57 -2.00 3.24 -2.00 502.57 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