File name: Pandora87s1_LapwaiID_20260506_L2Fit_fout2c3d20240715p1-8.txt File generation date: 20260603T150901.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Julie Simpson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 87 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora87_OF_v4d20240227.txt Instrument calibration file used: Pandora87s1_CF_v3d20240715.txt Level 1 file used: Pandora87s1_LapwaiID_20260506_L1_smca1c3d20240715p1-8.txt Full location name: Nez Perce Tribe cell tower site near Lapwai Idaho Short location name: LapwaiID Country of location: United States Location latitude [deg]: 46.3806 Location longitude [deg]: -116.8064 Location altitude [m]: 564 Local noon date: 20260506 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.1303 305.2709 305.4116 305.5523 305.6929 305.8335 305.9742 306.1148 306.2554 306.3959 306.5365 306.6771 306.8176 306.9582 307.0987 307.2392 307.3798 307.5203 307.6607 307.8012 307.9417 308.0821 308.2226 308.3630 308.5034 308.6438 308.7842 308.9246 309.0650 309.2054 309.3457 309.4861 309.6264 309.7667 309.9070 310.0473 310.1876 310.3279 310.4682 310.6084 310.7487 310.8889 311.0291 311.1693 311.3095 311.4497 311.5899 311.7301 311.8702 312.0104 312.1505 312.2906 312.4307 312.5708 312.7109 312.8510 312.9911 313.1311 313.2712 313.4112 313.5512 313.6912 313.8312 313.9712 314.1112 314.2512 314.3911 314.5311 314.6710 314.8109 314.9508 315.0907 315.2306 315.3705 315.5103 315.6502 315.7900 315.9299 316.0697 316.2095 316.3493 316.4891 316.6288 316.7686 316.9084 317.0481 317.1878 317.3275 317.4673 317.6069 317.7466 317.8863 318.0260 318.1656 318.3053 318.4449 318.5845 318.7241 318.8637 319.0033 319.1428 319.2824 319.4220 319.5615 319.7010 319.8405 319.9800 320.1195 320.2590 320.3985 320.5379 320.6774 320.8168 320.9562 321.0956 321.2350 321.3744 321.5138 321.6532 321.7925 321.9319 322.0712 322.2105 322.3498 322.4891 322.6284 322.7677 322.9070 323.0462 323.1854 323.3247 323.4639 323.6031 323.7423 323.8815 324.0206 324.1598 324.2990 324.4381 324.5772 324.7163 324.8554 324.9945 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Column 100: Humidity inside spectrometer box [%], -9=no humidity signal Column 101: Temperature inside spectrometer box [°C], 999=no temperature signal Column 102: Pressure inside spectrometer box [hPa], -9=no pressure signal Columns 103-245: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 246-388: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260506T131508.9Z 9622.552186 200 1 54.54 2 82.84 73.35 78.37 203.72 0.00 1 0.00 1 0 17 5.625e-01 2.288e-02 2.577e-01 5.856e-03 1.011899e+00 3.238569e-03 1.100928e-02 -6.000000e+00 3.182822e-01 229.77 -2.00 3.63 -2.00 322.06 0.00e+00 -3.044018e-03 1.747698e-03 1.411426e-03 -6.000000e+00 1.375888e-02 276.07 -2.00 20.00 -2.00 321.62 0.00e+00 7.399 0.008 302.00 328.00 3 1.3237e+00 1.1854e-02 9.0136e-02 -6.0000e+00 7.9869e-01 9.6673e-01 1.7051e-02 5.8591e-02 -6.0000e+00 8.7074e-01 -1.4161e+00 1.7056e-02 3.1189e-02 -6.0000e+00 5.1351e-01 5.7850e-01 7.8464e-03 9.6423e-03 -6.0000e+00 2.1460e-01 5.1849e-05 -8.9797e-04 1.3881e-04 1.2348e-04 -6.0000e+00 1.4816e-02 -8.0678e-03 0.0000e+00 12 8 8 10 0 0 24.53 24.60 0.55 -0.00807 -0.01482 52 5 1 5 0 1048.660 33.00 19.99 24.60 17.12 0.0 910.54 16.7 25.52 950.10 -115595 -143100 -155283 221467 45108 -153872 -132384 900000 -177819 -151783 -108110 -186546 -93585 -46 4873 900000 -62446 83881 -84942 -39059 172255 24498 116042 73750 -46328 -43469 -45130 900000 -78296 -36456 64027 -1764 9091 149103 23602 -19078 -18300 43840 88851 -10306 40452 86849 47657 -1220 28772 -6739 18919 -1263 51717 11442 54149 41640 37585 64634 43739 25656 39948 36628 34122 45109 19494 40800 24022 6260 27125 -1343 28772 18428 11858 16196 16203 12597 12404 9992 7850 -252 -571 -1813 4212 9127 4363 -130 -1782 3893 771 4460 2633 7135 -94 -2419 4200 -2330 -10014 -5236 -5795 -3611 -861 31 -2371 -298 -3841 -2004 -1988 -616 -2354 -6404 -2228 -3588 -1557 302 875 -713 -120 -1012 -597 -327 -188 188 -1217 118 1778 2481 2710 1698 4180 323 1694 1905 433 353 326 -410 113 238 262 -284 1189 215 312 -239 -1104 -932 -1991 -2039 -3490 -4109 1264 257 -2874 -2129 900000 -5259 -3544 -1683 -7550 -1894 0 56 900000 -1717 566 -3129 -892 983 267 662 574 -1250 -1150 -1147 900000 -2438 -870 767 -48 254 1021 512 -632 -668 1026 1623 -594 1524 2132 1741 -70 1199 -400 885 -76 1978 725 2565 2496 2574 3689 3246 2372 3238 2927 2590 2909 1669 3167 2578 922 3375 -221 3662 2808 2220 3346 3598 2933 2740 2042 1434 -44 -99 -350 926 2344 1399 -51 -775 1693 369 2166 1348 3531 -49 -1221 1846 -1057 -5019 -2800 -3392 -2485 -686 29 -2437 -294 -3616 -1618 -1442 -454 -1907 -5662 -2028 -3660 -1791 369 1223 -1095 -188 -1575 -891 -478 -283 299 -2061 198 2791 3627 3819 2341 5466 427 2177 2741 760 665 693 -889 261 596 660 -748 3108 573 812 -621 -2647 -2046 -4283 SS 20260506T132606.5Z 9622.559798 203 1 54.62 2 81.02 75.26 79.13 205.99 0.00 1 0.00 1 0 17 7.069e-01 1.622e-02 6.916e-02 2.176e-03 8.748703e-01 1.146502e-03 1.027920e-02 -6.000000e+00 3.963726e-01 229.77 -2.00 3.63 -2.00 321.32 0.00e+00 3.618494e-03 5.391003e-04 5.008011e-03 -6.000000e+00 1.703250e-02 276.07 -2.00 20.00 -2.00 320.83 0.00e+00 6.076 0.004 302.00 328.00 3 1.1054e+00 3.7408e-03 7.7119e-02 -6.0000e+00 9.9190e-01 3.3495e-01 5.3626e-03 5.4747e-02 -6.0000e+00 1.0798e+00 -5.2488e-01 5.7982e-03 3.0704e-02 -6.0000e+00 6.3940e-01 2.1538e-01 2.7423e-03 1.0290e-02 -6.0000e+00 2.6877e-01 2.4972e-04 -2.8128e-04 5.1344e-05 1.4566e-04 -6.0000e+00 1.8128e-02 -8.2665e-03 0.0000e+00 12 9 8 11 8 0 13.18 24.60 0.40 -0.00827 -0.01038 131 13 1 5 0 416.940 33.00 19.99 24.60 17.60 0.0 912.62 16.6 25.46 950.25 -239313 -222276 -220170 -192389 -238254 -232510 -220010 -203756 -217881 -198330 -213165 -235695 -157353 -107731 -92462 -13042 -88905 -29976 -82373 -68199 -50112 -50493 -38484 -17037 -57325 -58343 -68341 -44898 -73246 -42949 -24277 -17706 -15377 -6901 -19740 -31804 -9507 -12064 10288 -4558 4338 12128 11089 466 901 5269 3442 8045 11035 6514 11060 17886 13707 22675 14820 12989 14162 9366 9942 4490 7182 7755 11948 9474 8780 2121 5170 3904 5413 5447 5468 3746 4271 999 -1621 -2913 -4591 -3339 -2433 -68 -1237 -1306 -1904 -705 -654 1052 656 1803 1353 409 585 -2307 -4056 -3574 -2258 -2087 -953 392 -775 -783 -1880 -1643 -1031 -752 -1920 -2380 -1519 -771 75 715 1036 313 -21 -371 -400 -115 167 448 528 524 683 1519 1773 1246 1138 -621 596 529 473 238 -186 -135 -184 -131 76 -288 524 375 167 -114 -567 -786 -798 -3232 -2873 -2889 -1745 -3126 -2961 -2717 -2398 -3279 -2862 -3845 -6703 -2772 -1532 -1452 -111 -1830 -382 -1888 -1404 -851 -857 -629 -246 -1314 -1412 -1813 -905 -2021 -1057 -634 -526 -522 -220 -666 -1249 -341 -538 454 -277 266 734 708 33 65 378 262 627 902 621 1162 1974 1745 2897 2164 2015 2215 1493 1504 705 1162 1420 2462 2294 2221 568 1392 1038 1633 1902 2061 1464 1590 352 -521 -852 -1340 -1044 -906 -30 -657 -735 -1171 -454 -451 754 491 1356 1008 291 386 -1500 -2696 -2599 -1766 -1938 -959 452 -906 -957 -2134 -1634 -997 -753 -1951 -2543 -1720 -948 96 995 1622 493 -34 -576 -629 -176 263 698 869 873 1086 2406 2708 1844 1631 -877 870 802 798 435 -359 -281 -387 -296 175 -692 1263 918 401 -269 -1246 -1690 -1675 SS 20260506T133828.6Z 9622.568387 208 1 54.69 2 78.95 77.41 80.07 208.53 0.00 1 0.00 1 0 17 5.169e-01 1.340e-02 2.416e-02 1.086e-03 7.478468e-01 5.573671e-04 8.810016e-03 -6.000000e+00 2.898352e-01 229.77 -2.00 3.63 -2.00 320.55 0.00e+00 3.914621e-03 2.116024e-04 2.722129e-03 -6.000000e+00 1.245443e-02 276.07 -2.00 20.00 -2.00 320.01 0.00e+00 5.034 0.002 302.00 328.00 3 9.4509e-01 1.6708e-03 6.2827e-02 -6.0000e+00 7.2530e-01 1.3319e-01 2.1447e-03 4.1878e-02 -6.0000e+00 7.8955e-01 -2.5225e-01 2.1330e-03 2.3167e-02 -6.0000e+00 4.6754e-01 1.0730e-01 1.0679e-03 8.3656e-03 -6.0000e+00 1.9653e-01 8.4582e-04 -1.5064e-04 2.6417e-05 9.8244e-05 -6.0000e+00 1.3255e-02 -8.3337e-03 0.0000e+00 12 8 8 10 0 0 32.16 24.58 0.34 -0.00833 -0.00947 260 26 1 5 0 210.330 33.00 20.04 24.58 18.08 0.0 914.91 16.7 25.55 950.31 -173376 -168534 -180057 -143726 -167884 -187677 -173111 -154164 -161621 -143354 -154760 -138435 -116699 -82119 -56387 -42690 -53022 -35303 -46021 -45500 -34110 -31070 -28564 -23232 -30571 -28540 -35791 -26518 -40562 -26807 -10152 -7352 -7861 -4178 -11846 -21038 -9559 -3785 3819 1785 1194 3415 3666 4664 5463 4761 4186 3629 4801 4443 7339 7466 8212 7330 7031 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