File name: Pandora87s1_LapwaiID_20260601_L2Fit_fout2c2d20240715p1-8.txt File generation date: 20260602T075331.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Julie Simpson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 87 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora87_OF_v4d20240227.txt Instrument calibration file used: Pandora87s1_CF_v2d20240715.txt Level 1 file used: Pandora87s1_LapwaiID_20260601_L1_smca1c2d20240715p1-8.txt Full location name: Nez Perce Tribe cell tower site near Lapwai Idaho Short location name: LapwaiID Country of location: United States Location latitude [deg]: 46.3806 Location longitude [deg]: -116.8064 Location altitude [m]: 564 Local noon date: 20260601 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0760 305.2167 305.3574 305.4980 305.6386 305.7793 305.9199 306.0605 306.2011 306.3416 306.4822 306.6228 306.7633 306.9039 307.0444 307.1849 307.3254 307.4659 307.6064 307.7468 307.8873 308.0277 308.1682 308.3086 308.4490 308.5894 308.7298 308.8702 309.0105 309.1509 309.2912 309.4316 309.5719 309.7122 309.8525 309.9928 310.1331 310.2734 310.4136 310.5539 310.6941 310.8343 310.9745 311.1147 311.2549 311.3951 311.5353 311.6754 311.8156 311.9557 312.0958 312.2359 312.3760 312.5161 312.6562 312.7963 312.9363 313.0764 313.2164 313.3564 313.4965 313.6365 313.7764 313.9164 314.0564 314.1964 314.3363 314.4762 314.6162 314.7561 314.8960 315.0359 315.1757 315.3156 315.4555 315.5953 315.7351 315.8750 316.0148 316.1546 316.2944 316.4342 316.5739 316.7137 316.8534 316.9932 317.1329 317.2726 317.4123 317.5520 317.6917 317.8313 317.9710 318.1106 318.2503 318.3899 318.5295 318.6691 318.8087 318.9483 319.0878 319.2274 319.3669 319.5065 319.6460 319.7855 319.9250 320.0645 320.2040 320.3435 320.4829 320.6224 320.7618 320.9012 321.0406 321.1800 321.3194 321.4588 321.5982 321.7375 321.8769 322.0162 322.1555 322.2948 322.4341 322.5734 322.7127 322.8520 322.9912 323.1305 323.2697 323.4089 323.5481 323.6873 323.8265 323.9657 324.1048 324.2440 324.3831 324.5223 324.6614 324.8005 324.9396 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Column 100: Humidity inside spectrometer box [%], -9=no humidity signal Column 101: Temperature inside spectrometer box [°C], 999=no temperature signal Column 102: Pressure inside spectrometer box [hPa], -9=no pressure signal Columns 103-245: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 246-388: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260601T131612.9Z 9648.552927 199 1 53.52 2 78.94 69.49 97.84 236.16 0.00 1 0.00 1 0 25 5.072e-01 5.150e-02 1.723e-01 5.341e-03 7.691626e-01 2.974865e-03 9.664244e-03 -6.000000e+00 2.962235e-01 231.83 -2.00 3.63 -2.00 320.93 0.00e+00 -2.211376e-03 1.172343e-03 1.717626e-03 -6.000000e+00 1.268915e-02 279.06 -2.00 20.00 -2.00 320.44 0.00e+00 5.027 0.002 302.00 328.00 3 2.9202e+00 9.1192e-03 6.4058e-02 -6.0000e+00 7.4564e-01 4.8587e-01 1.1682e-02 4.3428e-02 -6.0000e+00 8.0322e-01 -6.1989e-01 1.0844e-02 2.3799e-02 -6.0000e+00 4.7489e-01 2.5249e-01 5.3970e-03 8.9196e-03 -6.0000e+00 2.0667e-01 9.9791e-05 -8.8939e-03 1.3212e-04 1.0361e-04 -6.0000e+00 1.3162e-02 -1.6869e-01 -2.1664e-04 12 9 8 11 12 0 35.72 24.63 0.26 -0.16869 -0.23552 17 2 1 5 0 3148.180 33.25 19.98 24.63 17.26 0.0 910.22 17.4 25.71 955.25 900000 95460 -154652 -127806 -185664 900000 -52582 -160815 -175510 -7482 -152611 -152552 -148014 -162836 -43981 -17493 -37718 900000 -91055 87304 -55333 -41749 306 -35355 114745 124364 11829 -16644 -58663 140583 -65361 -43983 45041 28438 15755 41761 3966 10304 713 24198 45193 6918 43687 35351 19270 -4485 6483 10809 17990 6797 8669 9656 24897 24213 15120 26878 23580 13069 19633 9350 24013 14705 7309 22425 14298 -1306 15844 -4593 5330 9348 1897 5942 6343 1311 4299 1565 -3961 -3060 -2707 -4659 2977 4538 3771 508 -3039 1732 -2442 -1162 -379 1704 -1815 -3794 3857 -1119 -11349 -3225 -2589 -2706 -98 1068 -1277 1121 -2532 -4133 -1580 -1143 -2352 -5594 -1381 -4554 -837 -287 301 -573 -294 -1015 1405 196 880 540 -97 -667 -617 -303 -738 45536 1008 -2117 65 18 87 333 49 -330 1247 831 866 -437 849 -976 -880 -1009 -3015 900000 497 -4245 -2903 -7469 900000 -448 -4186 -5897 -53 -5128 -5343 -5184 -7860 -893 -337 -1080 900000 -5499 954 -2621 -1760 8 -1362 1075 1165 363 -702 -3634 1098 -3947 -2450 1243 1081 771 1565 200 504 44 1423 2659 699 3320 3055 1996 -581 749 1204 1892 832 1097 1322 3318 3592 2684 4603 4382 2810 4017 2049 4313 2825 1579 4658 3692 -440 4545 -1566 1676 2988 747 2583 2949 592 1983 682 -1621 -1109 -944 -1756 1221 2194 1947 309 -2063 1183 -1866 -926 -311 1387 -1504 -3018 2628 -761 -8449 -2390 -2212 -2704 -102 1255 -1630 1353 -2910 -4266 -1598 -1206 -2485 -6371 -1603 -5912 -1167 -419 485 -976 -496 -1662 2120 291 1331 862 -164 -1163 -1035 -481 -1140 50212 1531 -3195 93 28 145 628 94 -679 2660 1901 1984 -1054 2039 -2422 -2137 -2300 -6981 SS 20260601T132233.2Z 9648.557328 202 1 54.10 2 77.91 70.56 98.72 237.19 0.00 1 0.00 1 0 25 5.094e-01 3.680e-02 1.378e-01 4.326e-03 7.201816e-01 2.375737e-03 9.100271e-03 -6.000000e+00 2.973318e-01 231.83 -2.00 3.63 -2.00 320.65 0.00e+00 -6.819637e-04 8.920282e-04 1.818782e-03 -6.000000e+00 1.251577e-02 279.06 -2.00 20.00 -2.00 320.16 0.00e+00 4.632 0.002 302.00 328.00 3 3.0332e+00 7.1174e-03 5.9726e-02 -6.0000e+00 7.4880e-01 2.6756e-01 9.2011e-03 4.1216e-02 -6.0000e+00 8.0644e-01 -2.7129e-01 9.1106e-03 2.2833e-02 -6.0000e+00 4.7700e-01 9.4878e-02 4.5882e-03 8.3455e-03 -6.0000e+00 2.0747e-01 1.3594e-04 -8.1445e-03 1.0846e-04 9.2630e-05 -6.0000e+00 1.3052e-02 -1.6458e-01 6.3071e-05 12 9 8 11 12 0 75.31 24.62 0.21 -0.16458 -0.22578 19 2 1 5 0 2847.270 33.00 20.00 24.62 17.40 0.0 911.38 17.4 25.62 955.21 900000 -157493 -191863 -141137 -190754 13219 -108695 -196785 -128203 -149976 -155491 -176216 -111235 -168733 -74435 -50963 -27074 900000 -57055 -47535 -85908 -51188 18030 -21357 56008 -7392 -5769 -36118 -41517 65433 -52718 -43804 6617 12061 16958 13095 -3989 -14104 -4792 11150 5291 -4366 12779 15597 1221 -2265 1812 -3484 5697 -2425 7250 32 6600 13009 7466 12024 9685 5422 10407 6118 4792 10419 3232 11097 6309 1109 4442 -6774 1674 5854 2109 3940 6001 586 2230 2426 -2107 -4350 -1503 -4611 726 1571 2275 -169 -2722 1300 -1874 654 649 1613 -588 -1921 1623 -1689 -7551 -2475 -786 -542 939 1436 -205 906 -1486 -1938 -1893 -1679 -1833 -3804 -1959 -2810 113 26 655 -207 -329 -379 743 57 219 -70 -401 -969 -1136 -499 -831 28125 -329 -1792 -847 890 6 -206 -12 -369 344 494 766 -360 443 81 -626 -1019 -2146 900000 -1811 -3825 -1894 -4314 56 -917 -4224 -1573 -2909 -3606 -5350 -1876 -6119 -1350 -924 -480 900000 -1756 -1463 -4130 -1813 319 -567 756 -209 -173 -1538 -1838 938 -2468 -2161 240 488 751 607 -205 -839 -299 724 453 -486 1315 1651 155 -297 230 -475 723 -349 1000 5 1141 2342 1558 2611 2267 1383 2580 1543 1174 2377 834 2971 2032 420 1645 -2714 625 2214 862 1820 2924 307 1106 1110 -901 -1875 -607 -2024 321 824 1377 -119 -2117 1026 -1503 541 558 1394 -512 -1594 1311 -1332 -6201 -2071 -684 -548 1082 1736 -266 1125 -1735 -2181 -1970 -1831 -2160 -4768 -2361 -3686 160 39 1068 -355 -557 -615 1121 91 330 -112 -679 -1684 -1911 -795 -1285 36400 -502 -2668 -1215 1365 9 -383 -22 -741 721 1035 1717 -847 1046 195 -1491 -2290 -4558 SS 20260601T132802.4Z 9648.561139 205 1 53.56 2 77.01 71.48 99.49 238.08 0.00 1 0.00 1 0 25 4.076e-01 2.694e-02 7.827e-02 3.308e-03 6.699373e-01 1.780939e-03 8.388542e-03 -6.000000e+00 2.364950e-01 231.83 -2.00 3.63 -2.00 320.33 0.00e+00 1.623688e-03 6.121275e-04 3.755098e-04 -6.000000e+00 1.000914e-02 279.07 -2.00 20.00 -2.00 319.81 0.00e+00 4.335 0.002 302.00 328.00 3 2.9466e+00 5.1896e-03 5.5435e-02 -6.0000e+00 5.9498e-01 2.1502e-01 6.4757e-03 3.7616e-02 -6.0000e+00 6.4002e-01 -2.4811e-01 6.1104e-03 1.9406e-02 -6.0000e+00 3.7867e-01 9.6631e-02 3.1429e-03 6.3300e-03 -6.0000e+00 1.6554e-01 2.0695e-04 -8.4521e-03 8.2662e-05 6.1564e-05 -6.0000e+00 1.0419e-02 -1.6813e-01 -7.5057e-05 12 9 8 11 12 0 25.77 24.62 0.12 -0.16813 -0.23164 24 2 1 5 0 2231.290 33.00 20.01 24.62 17.62 0.0 912.59 17.4 25.56 955.24 900000 -138545 -152048 -126397 -160752 -71729 -31601 -161363 -107336 -82047 -118575 -145689 -124608 -123911 -73978 -22233 -31814 53097 -47557 -1772 -60287 -34509 2394 -8567 28980 14436 -5663 -26531 -26052 5705 -45219 -16132 -9832 -2647 11290 936 -9763 -5700 -6687 -2705 8400 -2113 6461 12036 5463 -4491 4921 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