File name: Pandora87s1_LapwaiID_20260625_L2Fit_fout2c3d20240715p1-8.txt File generation date: 20260626T080150.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Julie Simpson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 87 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora87_OF_v4d20240227.txt Instrument calibration file used: Pandora87s1_CF_v3d20240715.txt Level 1 file used: Pandora87s1_LapwaiID_20260625_L1_smca1c3d20240715p1-8.txt Full location name: Nez Perce Tribe cell tower site near Lapwai Idaho Short location name: LapwaiID Country of location: United States Location latitude [deg]: 46.3806 Location longitude [deg]: -116.8064 Location altitude [m]: 564 Local noon date: 20260625 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.1303 305.2709 305.4116 305.5523 305.6929 305.8335 305.9742 306.1148 306.2554 306.3959 306.5365 306.6771 306.8176 306.9582 307.0987 307.2392 307.3798 307.5203 307.6607 307.8012 307.9417 308.0821 308.2226 308.3630 308.5034 308.6438 308.7842 308.9246 309.0650 309.2054 309.3457 309.4861 309.6264 309.7667 309.9070 310.0473 310.1876 310.3279 310.4682 310.6084 310.7487 310.8889 311.0291 311.1693 311.3095 311.4497 311.5899 311.7301 311.8702 312.0104 312.1505 312.2906 312.4307 312.5708 312.7109 312.8510 312.9911 313.1311 313.2712 313.4112 313.5512 313.6912 313.8312 313.9712 314.1112 314.2512 314.3911 314.5311 314.6710 314.8109 314.9508 315.0907 315.2306 315.3705 315.5103 315.6502 315.7900 315.9299 316.0697 316.2095 316.3493 316.4891 316.6288 316.7686 316.9084 317.0481 317.1878 317.3275 317.4673 317.6069 317.7466 317.8863 318.0260 318.1656 318.3053 318.4449 318.5845 318.7241 318.8637 319.0033 319.1428 319.2824 319.4220 319.5615 319.7010 319.8405 319.9800 320.1195 320.2590 320.3985 320.5379 320.6774 320.8168 320.9562 321.0956 321.2350 321.3744 321.5138 321.6532 321.7925 321.9319 322.0712 322.2105 322.3498 322.4891 322.6284 322.7677 322.9070 323.0462 323.1854 323.3247 323.4639 323.6031 323.7423 323.8815 324.0206 324.1598 324.2990 324.4381 324.5772 324.7163 324.8554 324.9945 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Column 100: Humidity inside spectrometer box [%], -9=no humidity signal Column 101: Temperature inside spectrometer box [°C], 999=no temperature signal Column 102: Pressure inside spectrometer box [hPa], -9=no pressure signal Columns 103-245: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 246-388: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260625T124809.7Z 9672.533445 95 1 54.97 2 83.19 63.01 131.55 282.73 0.00 1 0.00 1 0 25 5.295e-01 2.883e-02 2.478e-01 7.291e-03 1.041914e+00 4.052005e-03 1.150558e-02 -6.000000e+00 3.018056e-01 232.89 -2.00 3.63 -2.00 322.21 0.00e+00 -6.603913e-03 2.210871e-03 1.213087e-03 -6.000000e+00 1.320560e-02 281.55 -2.00 20.00 -2.00 321.74 0.00e+00 7.707 0.009 302.00 328.00 3 1.2322e+00 1.5489e-02 9.3450e-02 -6.0000e+00 7.6021e-01 1.3760e+00 1.9674e-02 5.8624e-02 -6.0000e+00 8.2544e-01 -1.9115e+00 1.5342e-02 2.9195e-02 -6.0000e+00 4.8931e-01 7.6123e-01 7.3890e-03 8.7844e-03 -6.0000e+00 2.0494e-01 3.8662e-05 -1.0447e-03 1.7135e-04 1.1300e-04 -6.0000e+00 1.3858e-02 -9.3446e-03 0.0000e+00 12 8 8 10 0 0 -5.68 24.44 0.40 -0.00934 -0.01719 46 5 1 5 0 1194.840 33.00 20.02 24.44 23.30 0.0 938.97 15.8 23.93 947.02 -52975 -70965 -94851 141948 178500 -84408 -56711 66683 -18714 -89904 -78919 -96091 -5693 900000 95583 900000 -31250 141603 -38676 -17663 181342 99216 900000 91086 26919 11879 -30713 900000 -41846 -35047 61728 57236 73749 59626 58739 -28436 21709 7797 289324 15911 46602 54034 31751 1013 34248 33291 19788 24829 15343 18002 58638 83121 42813 128110 66713 36586 78350 17015 64710 54122 6482 34903 36780 7603 51747 -5654 26045 41368 18401 20101 25463 15934 16386 18187 -5885 -2027 -6403 -3156 16109 18038 13641 2837 -2677 8814 -377 4689 9980 11817 3052 -1957 5242 -5757 -21140 -3063 -3851 -5045 -4540 -1391 -3385 1543 -4329 -4222 -1832 -3944 -1145 -8252 -1376 -5069 -2918 -489 1193 -2406 -1388 -2182 509 -791 478 22 -1199 -275 2734 3816 4013 2932 3932 152 1762 1280 755 733 425 188 1062 155 -148 151 735 7 -170 319 -1460 -1442 -1892 -2258 -3621 -5637 1009 1268 -2890 -1539 560 -387 -3775 -2957 -4841 -140 900000 1173 900000 -1554 1281 -2074 -730 1289 1090 900000 1236 713 361 -1309 900000 -1622 -1426 1156 1294 1572 1425 1377 -1556 787 382 2056 1006 2318 2534 1827 75 1728 1656 1125 1394 1003 1254 3083 3780 3164 4369 4409 3379 4788 1814 3908 3384 659 2951 3528 1113 5037 -964 3368 4938 3164 3899 5012 3476 3353 3282 -1175 -344 -1110 -576 2919 3922 3683 994 -1084 3363 -168 2086 4347 5097 1408 -894 2071 -2454 -10755 -1456 -2208 -3197 -3405 -1187 -3199 1365 -3738 -3185 -1332 -2736 -835 -6775 -1132 -4784 -3104 -600 1665 -3468 -2036 -3198 702 -1086 669 33 -1901 -435 3985 5630 5708 4089 5283 207 2322 1902 1246 1412 858 416 2510 400 -386 406 1986 19 -459 852 -3627 -3279 -4178 SS 20260625T125900.4Z 9672.540977 98 1 54.64 2 81.51 64.86 133.31 285.00 0.00 1 0.00 1 0 17 6.576e-01 1.982e-02 8.238e-02 2.779e-03 9.188218e-01 1.493967e-03 1.074741e-02 -6.000000e+00 3.731287e-01 232.89 -2.00 3.63 -2.00 321.58 0.00e+00 2.093422e-03 7.739645e-04 6.337171e-03 -6.000000e+00 1.621138e-02 281.56 -2.00 20.00 -2.00 321.06 0.00e+00 6.380 0.005 302.00 328.00 3 1.1624e+00 5.2396e-03 8.4263e-02 -6.0000e+00 9.3923e-01 5.4142e-01 7.4286e-03 6.3874e-02 -6.0000e+00 1.0189e+00 -8.3209e-01 7.4242e-03 3.1326e-02 -6.0000e+00 6.0368e-01 3.4036e-01 3.4309e-03 8.3369e-03 -6.0000e+00 2.5335e-01 1.6806e-04 -3.4666e-04 6.4820e-05 1.5038e-04 -6.0000e+00 1.6877e-02 -1.0187e-02 0.0000e+00 12 8 8 10 0 0 -5.07 24.44 0.46 -0.01019 -0.01279 108 11 1 5 0 505.860 33.00 20.03 24.44 23.91 0.0 941.82 15.8 23.91 947.09 -213077 -199983 -224190 -177988 -205714 -211220 -209284 -161646 -219733 -191611 -195270 -213208 -138123 -81384 -95350 25727 -107195 -49117 -71723 -78259 -28220 -51298 -33863 2412 -31725 -48193 -67831 19808 -67750 -71168 -18114 11775 -416 11313 -15189 -30956 -2582 13512 27366 97 16941 20303 26162 -732 13019 13372 9378 7986 15847 20338 27282 27145 27083 28980 24569 16358 20164 19317 14746 15559 12268 10398 20026 11285 13975 4852 8440 7278 7305 8081 10099 6248 5716 3097 2128 -586 -2851 -4536 -144 792 -164 510 -1917 503 -256 1187 1121 2532 867 189 1533 -892 -7929 -3978 -3474 -2697 -1326 90 -1308 -841 -2377 -2956 -1936 -1386 -2463 -3422 -1302 -1686 -426 -27 922 -402 296 -599 -441 -493 111 595 346 460 1613 1792 2128 2580 1453 -222 631 1234 408 415 194 -29 -116 -35 126 -273 603 518 138 -360 -705 -976 -1303 -3727 -3399 -4916 -2192 -2990 -3278 -3454 -1832 -4872 -3352 -3752 -6040 -2450 -1169 -1990 188 -3312 -932 -1788 -2121 -451 -1015 -606 33 -636 -1175 -1967 225 -1873 -2430 -461 268 -12 304 -490 -1191 -85 454 986 5 877 1073 1347 -49 766 801 605 556 1099 1499 2159 2413 2657 3055 2856 2150 2596 2424 1834 1868 1596 1561 3197 2254 2821 1062 1853 1736 2005 2547 3060 2003 1759 983 603 -153 -746 -1312 -48 291 -72 257 -1080 293 -161 778 700 1584 593 123 916 -524 -5040 -2682 -2532 -2328 -1233 96 -1530 -958 -2529 -2777 -1768 -1304 -2336 -3432 -1368 -1952 -514 -38 1355 -640 473 -945 -665 -728 168 947 583 784 2594 2716 3105 3876 2138 -322 891 1924 709 778 383 -62 -251 -81 297 -674 1492 1301 341 -880 -1595 -2168 -2828 SS 20260625T131452.6Z 9672.551997 103 1 54.50 2 79.01 67.54 135.85 288.47 0.00 1 0.00 1 0 17 5.595e-01 1.322e-02 2.833e-02 1.158e-03 7.659067e-01 6.039242e-04 9.076938e-03 -6.000000e+00 3.174682e-01 232.89 -2.00 3.63 -2.00 320.68 0.00e+00 2.866922e-03 2.459359e-04 3.535361e-03 -6.000000e+00 1.379369e-02 281.56 -2.00 20.00 -2.00 320.08 0.00e+00 5.057 0.003 302.00 328.00 3 9.9828e-01 1.8746e-03 6.5133e-02 -6.0000e+00 7.9912e-01 1.2296e-01 2.4507e-03 4.5820e-02 -6.0000e+00 8.6693e-01 -2.5304e-01 2.4022e-03 2.3658e-02 -6.0000e+00 5.1364e-01 1.0637e-01 1.1819e-03 7.0191e-03 -6.0000e+00 2.1555e-01 7.7145e-04 -1.9320e-04 2.7961e-05 9.5515e-05 -6.0000e+00 1.4361e-02 -9.7113e-03 0.0000e+00 12 8 8 10 0 0 11.30 24.42 0.33 -0.00971 -0.01116 248 25 1 5 0 219.720 32.75 20.01 24.42 25.17 0.0 947.93 15.8 23.93 947.10 -197367 -177570 -187242 -168212 -192714 -195270 -181834 -158254 -171681 -166914 -157994 -151611 -122959 -83182 -71827 -31579 -62456 -40339 -43888 -46345 -37119 -48368 -35895 -34988 -28794 -34957 -34281 -33562 -42634 -32851 -16265 -13982 -4806 -5691 -10739 -19638 -10765 -4888 4970 -985 2863 4405 4399 2941 3145 4014 3524 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