File name: Pandora272s1_Lauder_20251209_L2Fit_fout2c6d20241202p1-8.txt File generation date: 20260704T063614.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Richard Querel Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 272 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora272_OF_v3d20240829.txt Instrument calibration file used: Pandora272s1_CF_v6d20241202.txt Level 1 file used: Pandora272s1_Lauder_20251209_L1_smca1c6d20241202p1-8.txt Full location name: Lauder Atmospheric Research Station Short location name: Lauder Country of location: New Zealand Location latitude [deg]: -45.0380 Location longitude [deg]: 169.6840 Location altitude [m]: 370 Local noon date: 20251209 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0455 305.1861 305.3267 305.4672 305.6077 305.7483 305.8888 306.0293 306.1697 306.3102 306.4507 306.5911 306.7315 306.8720 307.0124 307.1528 307.2931 307.4335 307.5739 307.7142 307.8545 307.9949 308.1352 308.2755 308.4158 308.5560 308.6963 308.8365 308.9768 309.1170 309.2572 309.3974 309.5376 309.6778 309.8179 309.9581 310.0982 310.2383 310.3784 310.5185 310.6586 310.7987 310.9388 311.0788 311.2189 311.3589 311.4989 311.6389 311.7789 311.9189 312.0589 312.1988 312.3388 312.4787 312.6186 312.7585 312.8984 313.0383 313.1782 313.3180 313.4579 313.5977 313.7375 313.8773 314.0171 314.1569 314.2967 314.4364 314.5762 314.7159 314.8556 314.9954 315.1351 315.2747 315.4144 315.5541 315.6937 315.8334 315.9730 316.1126 316.2522 316.3918 316.5314 316.6710 316.8105 316.9501 317.0896 317.2291 317.3686 317.5081 317.6476 317.7871 317.9265 318.0660 318.2054 318.3448 318.4842 318.6236 318.7630 318.9024 319.0417 319.1811 319.3204 319.4598 319.5991 319.7384 319.8777 320.0169 320.1562 320.2955 320.4347 320.5739 320.7131 320.8523 320.9915 321.1307 321.2699 321.4090 321.5482 321.6873 321.8264 321.9655 322.1046 322.2437 322.3828 322.5219 322.6609 322.7999 322.9390 323.0780 323.2170 323.3560 323.4949 323.6339 323.7729 323.9118 324.0507 324.1896 324.3285 324.4674 324.6063 324.7452 324.8840 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251208T183302.0Z 9473.772940 607 1 55.70 2 74.15 106.60 73.30 327.45 0.00 1 0.00 1 0 17 1.732e-01 1.931e-02 2.951e-02 2.906e-03 4.468739e-01 1.510849e-03 5.429086e-03 -6.000000e+00 1.014062e-01 231.49 -2.00 3.69 -2.00 319.29 0.00e+00 8.385275e-05 3.824650e-04 7.690177e-04 -6.000000e+00 4.373249e-03 277.22 -2.00 20.00 -2.00 318.70 0.00e+00 3.599 0.001 302.00 328.00 3 4.6913e+00 4.2169e-03 4.2307e-02 -6.0000e+00 2.5459e-01 5.3937e-02 4.8876e-03 2.4874e-02 -6.0000e+00 2.7521e-01 -7.0166e-02 3.7175e-03 1.2306e-02 -6.0000e+00 1.6281e-01 3.5563e-02 1.9408e-03 3.5137e-03 -6.0000e+00 6.8971e-02 9.3422e-05 9.4446e-04 8.4122e-05 3.8648e-05 -6.0000e+00 4.8201e-03 4.5578e-03 0.0000e+00 12 8 8 10 0 0 99.84 25.27 0.27 0.00456 0.01165 18 2 1 8 0 3093.850 20.01 25.27 21.45 35.00 33.75 0.9 970.51 -49707 -11538 8966 8410 900000 -44112 -42611 -97179 -37894 -80043 -62375 -41233 12616 -17573 -37014 3892 -34659 37839 -17533 11549 -10898 3583 -12247 -3885 4848 8508 7470 19295 11275 2495 -13534 10866 5047 38877 -26638 33117 -557 -10783 573 10207 -3530 17265 1218 4114 6511 11496 3447 10517 -7023 2832 9770 5806 1512 1331 -750 -331 2962 -3898 -3003 9994 10569 6169 1103 1992 -2207 -1344 8306 -4043 3668 -560 269 1013 -968 2250 -1192 -574 -1054 -1112 -3164 -2784 -2275 255 -2810 -3910 -3294 364 -963 -620 442 -1114 -194 -640 613 -2213 -1703 -1710 -593 2077 -36 2858 15 -1816 -3292 167 1237 -810 188 1216 -605 -130 699 39 -307 1512 391 84 -932 747 -419 752 -153 -154 842 266 2572 433 -790 639 93 397 347 -223 504 -522 -104 -26 -330 394 619 -68 -661 -578 -1076 -1662 -297 198 179 900000 -1400 -1437 -6360 -1546 -5375 -3588 -2056 433 -976 -2968 238 -3388 1919 -1644 847 -1025 291 -1214 -383 467 832 751 1646 984 243 -1726 1219 672 3921 -4936 3312 -86 -2142 123 2383 -963 4466 351 1173 1816 3076 1000 2842 -2286 862 3000 2032 595 564 -342 -155 1383 -1956 -1459 4204 4527 2973 618 1116 -1333 -768 4497 -2472 2203 -366 194 765 -750 1622 -826 -356 -653 -665 -2041 -1878 -1753 216 -2481 -3683 -3297 377 -1066 -708 506 -1259 -202 -619 548 -1986 -1617 -1822 -658 2539 -50 3799 20 -2220 -3747 195 1436 -1021 246 1671 -841 -195 1129 63 -490 2417 591 119 -1316 1071 -646 1217 -256 -253 1334 409 3668 604 -1144 907 134 622 587 -376 874 -951 -188 -49 -655 794 1260 -136 -1266 -1058 -2025 SS 20251208T195150.7Z 9473.827671 755 1 21.87 2 60.48 93.62 81.83 311.39 0.00 1 0.00 1 0 17 2.817e-02 1.166e-02 7.500e-03 3.101e-03 2.606044e-01 1.603724e-03 3.254080e-03 -6.000000e+00 1.648165e-02 231.49 -2.00 3.69 -2.00 316.67 0.00e+00 8.211495e-05 1.906997e-04 1.412592e-04 -6.000000e+00 6.995190e-04 277.22 -2.00 20.00 -2.00 316.06 0.00e+00 2.021 0.000 302.00 328.00 3 5.5885e+00 4.2117e-03 2.3984e-02 -6.0000e+00 4.1400e-02 5.3914e-02 4.6893e-03 1.4182e-02 -6.0000e+00 4.4750e-02 -2.0384e-02 2.7512e-03 6.8995e-03 -6.0000e+00 2.6487e-02 8.9526e-03 1.3096e-03 1.9143e-03 -6.0000e+00 1.1210e-02 2.0873e-04 2.0764e-04 8.8809e-05 2.2103e-05 -6.0000e+00 7.7492e-04 5.3172e-03 0.0000e+00 12 9 9 12 1 1 99.89 25.29 -0.02 0.00532 0.00688 6 2 1 8 0 3123.410 19.99 25.29 24.64 35.00 34.00 0.8 982.37 -2962 -3375 4734 661 11800 -5016 -2158 -14940 -2708 -9227 -8061 -7841 3519 -2609 -4589 2638 -3572 3987 -1325 2152 -150 2326 -3330 1253 3701 3340 2029 2363 135 -164 -1146 2108 947 6162 -7290 1546 -2131 -5348 -663 290 -2256 1909 -329 941 677 2634 422 1176 -3743 409 2753 1229 704 327 -167 57 711 -600 -882 2943 2709 2435 1768 1597 -495 -1344 2229 -2702 1221 -272 758 1251 115 1165 -666 -361 -230 -1841 -2618 -2416 -1960 -576 -1851 -2964 -1945 124 -93 196 313 397 -254 -381 -224 -1624 -1063 -618 675 1488 548 1489 167 -791 -2398 -360 334 -977 212 635 -217 -109 921 432 -5 680 122 104 -840 207 -219 909 93 -88 533 443 1731 529 -359 -133 321 103 268 -301 198 -553 602 -76 -91 389 230 42 -399 -938 -1064 -461 -525 767 105 1485 -713 -315 -2738 -488 -1712 -1614 -1594 710 -579 -1180 697 -1051 1126 -410 665 -48 724 -1120 425 1282 1205 748 819 44 -53 -391 745 365 2350 -2995 562 -871 -2376 -335 172 -1393 1182 -215 615 441 1678 270 727 -2378 248 1712 830 505 248 -123 43 538 -461 -666 2278 1996 1915 1517 1471 -439 -1200 1778 -2188 982 -249 712 1233 116 1125 -614 -321 -184 -1507 -2039 -2086 -1896 -569 -1999 -3175 -2197 148 -111 241 390 480 -305 -419 -241 -1670 -1119 -665 795 1823 731 1965 212 -1003 -2867 -421 419 -1249 280 876 -299 -158 1407 645 -7 983 173 136 -1084 272 -307 1281 138 -130 766 615 2372 698 -455 -174 414 143 391 -434 290 -834 946 -121 -149 650 393 71 -648 -1483 -1630 SS 20251208T195356.9Z 9473.829131 757 1 54.57 2 60.11 93.26 82.10 310.99 0.00 1 0.00 1 0 17 8.795e-02 2.626e-02 1.357e-02 4.406e-03 2.646047e-01 2.265316e-03 3.232748e-03 -6.000000e+00 5.140778e-02 231.49 -2.00 3.69 -2.00 317.28 0.00e+00 -1.187995e-04 3.108146e-04 1.035839e-04 -6.000000e+00 2.184164e-03 277.22 -2.00 20.00 -2.00 316.64 0.00e+00 1.998 0.000 302.00 328.00 3 6.8567e+00 6.0010e-03 2.3896e-02 -6.0000e+00 1.2912e-01 9.4221e-02 6.7061e-03 1.4294e-02 -6.0000e+00 1.3962e-01 -5.8055e-02 3.9974e-03 6.9457e-03 -6.0000e+00 8.2641e-02 3.3937e-02 1.9335e-03 1.9251e-03 -6.0000e+00 3.4933e-02 5.8948e-05 3.7245e-04 1.2825e-04 2.1149e-05 -6.0000e+00 2.4196e-03 1.3097e-02 0.0000e+00 12 9 8 11 8 0 99.98 25.29 0.26 0.01310 0.01590 20 2 1 8 0 2727.940 19.99 25.29 24.66 35.00 34.00 0.8 981.99 -3447 4054 7100 13066 67329 -6231 -4277 -36700 6150 -22347 -16624 -9462 13111 -1754 -11793 5351 -12471 15229 -4966 4168 -298 5054 -4324 435 3236 8968 2425 10135 2009 -348 -6289 2526 -182 23348 -19508 21158 -1852 -7059 -79 4581 -1836 9650 479 1799 2401 7142 1159 4764 -8479 1631 6633 2534 105 -713 -2426 263 2276 -5046 -5313 8106 7539 4694 1599 961 -3611 -2830 7599 -5412 3002 -909 284 1465 -89 2819 -1077 -98 744 -3485 -2726 -2261 -3612 563 -1699 -3872 -3624 1583 531 184 666 -2916 -825 -1476 311 -3685 -3935 -2869 -1565 4266 369 5750 851 -966 -4203 1586 3211 315 929 2332 -92 -778 855 -332 -761 2605 537 -87 -2900 790 -933 1018 -939 -647 1611 -9 4246 762 -2099 -911 -548 -308 272 260 801 -797 35 337 -751 864 853 268 -492 -1176 -985 -458 542 937 1510 3992 -739 -526 -6891 832 -4234 -2936 -1586 1949 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