File name: Pandora272s1_Lauder_20260111_L2Fit_fwvt1c2d20241202p1-8.txt File generation date: 20260111T125641.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Richard Querel Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 272 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora272_OF_v3d20240829.txt Instrument calibration file used: Pandora272s1_CF_v2d20241202.txt Level 1 file used: Pandora272s1_Lauder_20260111_L1_smca1c2d20241202p1-8.txt Full location name: Lauder Atmospheric Research Station Short location name: Lauder Country of location: New Zealand Location latitude [deg]: -45.0380 Location longitude [deg]: 169.6840 Location altitude [m]: 370 Local noon date: 20260111 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB based on session 1 First and last pixel inside fitting window: 1622 1772 Nominal wavelengths inside fitting window [nm]: 492.0513 492.1717 492.2922 492.4126 492.5331 492.6535 492.7739 492.8943 493.0146 493.1350 493.2553 493.3756 493.4959 493.6162 493.7364 493.8567 493.9769 494.0971 494.2173 494.3375 494.4576 494.5777 494.6979 494.8180 494.9381 495.0581 495.1782 495.2982 495.4183 495.5383 495.6583 495.7782 495.8982 496.0181 496.1380 496.2579 496.3778 496.4977 496.6175 496.7374 496.8572 496.9770 497.0968 497.2166 497.3363 497.4560 497.5758 497.6955 497.8151 497.9348 498.0545 498.1741 498.2937 498.4133 498.5329 498.6524 498.7720 498.8915 499.0110 499.1305 499.2500 499.3695 499.4889 499.6083 499.7278 499.8471 499.9665 500.0859 500.2052 500.3245 500.4439 500.5631 500.6824 500.8017 500.9209 501.0401 501.1593 501.2785 501.3977 501.5169 501.6360 501.7551 501.8742 501.9933 502.1124 502.2314 502.3505 502.4695 502.5885 502.7075 502.8264 502.9454 503.0643 503.1832 503.3021 503.4210 503.5399 503.6587 503.7775 503.8963 504.0151 504.1339 504.2527 504.3714 504.4901 504.6089 504.7275 504.8462 504.9649 505.0835 505.2021 505.3207 505.4393 505.5579 505.6764 505.7950 505.9135 506.0320 506.1505 506.2690 506.3874 506.5058 506.6243 506.7426 506.8610 506.9794 507.0977 507.2161 507.3344 507.4527 507.5709 507.6892 507.8074 507.9257 508.0439 508.1621 508.2802 508.3984 508.5165 508.6347 508.7528 508.8708 508.9889 509.1070 509.2250 509.3430 509.4610 509.5790 509.6970 509.8149 509.9328 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20260110T193338.2Z 9506.815026 591 1 6.21 2 67.01 98.49 35.82 335.56 0.00 1 0.00 1 0 22 3.305e-03 3.289e-03 3.464e-04 3.460e-04 3.175291e+03 2.064758e+01 2.341045e+02 -6.000000e+00 1.802058e+02 278.70 -2.00 20.00 -2.00 505.28 0.00e+00 4.807701e-04 9.380492e-06 3.029050e-05 -6.000000e+00 9.139200e-05 278.70 -2.00 20.00 -2.00 500.52 0.00e+00 1.297988e-01 6.828085e-03 2.340488e-02 -6.000000e+00 6.571004e-02 232.12 -2.00 3.69 -2.00 502.10 0.00e+00 2.540 0.000 489.00 513.00 1 3.6478e+00 5.2216e-04 4.0569e-03 -6.0000e+00 5.0281e-03 -3.8984e-03 1.3472e-04 6.0151e-04 -6.0000e+00 1.3058e-03 3.5436e-02 1.5712e-03 3.3741e-05 3.1999e-05 -6.0000e+00 3.3303e-04 1.5794e-02 1.7900e-05 12 1 1 12 1 1 99.98 25.52 1.77 0.01579 0.02669 77 71 1 2 0 79.510 19.99 25.52 23.96 35.25 34.00 0.8 980.11 -723 -533 -183 -47 174 558 604 453 347 461 396 113 -361 -255 -235 -318 -137 40 88 38 203 183 123 341 293 410 405 127 -495 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-78 -47 187 314 355 487 631 577 373 409 266 -6 17 332 175 112 280 293 256 357 154 -104 -65 -245 -469 -269 42 -146 -15 234 55 99 277 307 320 263 -59 -272 -389 -383 -438 SQ 20260110T194609.2Z 9506.823717 596 1 3.75 2 64.82 96.40 36.76 330.72 0.00 1 0.00 1 0 22 4.577e-03 4.561e-03 2.842e-03 2.838e-03 3.016156e+03 1.695458e+02 2.219021e+02 -6.000000e+00 2.495664e+02 278.70 -2.00 20.00 -2.00 505.28 0.00e+00 3.480322e-04 7.703796e-05 2.415196e-05 -6.000000e+00 1.265591e-04 278.70 -2.00 20.00 -2.00 500.51 0.00e+00 1.224916e-01 5.604832e-02 2.225844e-02 -6.000000e+00 9.097048e-02 232.12 -2.00 3.69 -2.00 502.09 0.00e+00 2.335 0.000 489.00 513.00 1 6.6584e+00 4.2869e-03 3.7459e-03 -6.0000e+00 6.9613e-03 -1.5772e-03 1.1046e-03 5.7081e-04 -6.0000e+00 1.8071e-03 1.7997e-03 1.4501e-03 2.7651e-04 2.9441e-05 -6.0000e+00 4.6111e-04 1.1552e-02 7.1033e-05 12 9 1 12 1 1 999.00 25.52 1.89 0.01155 0.02161 1 3 1 2 0 1872.020 20.00 25.52 24.64 35.25 33.75 0.8 981.56 -551 -643 218 -637 427 249 1032 265 -119 878 97 -14 -139 -398 -799 628 -420 118 635 -367 321 124 212 109 163 212 340 -325 -497 -399 -750 -1379 -199 535 193 139 319 195 45 682 445 -92 457 137 90 717 163 180 172 -537 -748 -617 -470 -155 -227 -244 -270 -93 -210 38 257 450 617 169 363 105 519 469 56 -427 16 -212 -438 -364 -155 652 -1113 -87 -220 -967 -307 -68 -1009 53 -296 -499 -529 -108 114 -63 -244 133 712 735 133 168 947 -434 -354 -242 -283 -1500 -285 -353 34 -69 -578 156 -441 -10 259 -31 385 425 551 407 751 589 809 246 30 81 347 383 79 -554 635 -49 -200 456 289 -70 131 -162 -637 -459 371 -319 -202 -24 -276 329 -143 65 479 -104 565 -745 -244 -133 -29 -537 -625 217 -652 435 259 1064 277 -125 915 101 -15 -140 -404 -798 634 -427 122 657 -381 332 129 220 113 170 222 353 -334 -507 -402 -750 -1394 -202 547 200 145 331 200 46 695 454 -95 466 142 94 744 169 184 176 -540 -745 -599 -460 -152 -224 -244 -276 -94 -214 38 260 456 627 172 366 104 518 462 55 -421 15 -208 -427 -358 -153 638 -1094 -84 -212 -934 -295 -66 -978 51 -290 -496 -528 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0.03010 28 3 1 2 0 1783.520 19.99 25.51 21.67 35.25 33.75 0.9 970.13 -823 -554 337 -200 189 318 670 279 572 689 287 140 -307 -436 -507 -145 -145 164 136 -111 61 330 263 329 159 327 474 -100 -588 -431 -271 -671 -168 212 -17 -48 164 18 -270 331 104 -58 107 251 265 595 515 568 215 -268 -555 -875 -909 -503 -469 -410 -43 -72 -96 149 268 538 335 230 116 151 172 49 -84 -428 -344 -42 -230 205 -241 46 40 -419 -452 -423 -455 -581 -468 89 -57 -348 -214 -170 -343 -161 -19 52 703 252 621 371 511 -428 -345 -343 -685 -869 -267 -178 -55 -102 -228 -126 -470 -9 -93 -107 135 327 285 607 607 594 346 391 624 -110 18 227 364 157 466 94 336 413 -58 -186 -54 -229 -556 -414 196 -178 -293 202 -268 494 295 409 366 324 -10 -416 -477 -267 -411 -798 -545 332 -205 193 331 693 292 594 721 298 144 -310 -435 -505 -145 -148 170 141 -117 64 347 277 347 165 339 498 -104 -599 -435 -270 -673 -170 217 -17 -50 169 18 -278 337 106 -59 111 257 273 614 529 588 220 -268 -551 -851 -875 -486 -464 -408 -43 -74 -99 153 275 551 338 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