File name: Pandora272s1_Lauder_20260405_L2Fit_fwvt1c2d20241202p1-8.txt File generation date: 20260405T125501.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Richard Querel Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 272 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora272_OF_v3d20240829.txt Instrument calibration file used: Pandora272s1_CF_v2d20241202.txt Level 1 file used: Pandora272s1_Lauder_20260405_L1_smca1c2d20241202p1-8.txt Full location name: Lauder Atmospheric Research Station Short location name: Lauder Country of location: New Zealand Location latitude [deg]: -45.0380 Location longitude [deg]: 169.6840 Location altitude [m]: 370 Local noon date: 20260405 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB based on session 1 First and last pixel inside fitting window: 1622 1772 Nominal wavelengths inside fitting window [nm]: 492.0513 492.1717 492.2922 492.4126 492.5331 492.6535 492.7739 492.8943 493.0146 493.1350 493.2553 493.3756 493.4959 493.6162 493.7364 493.8567 493.9769 494.0971 494.2173 494.3375 494.4576 494.5777 494.6979 494.8180 494.9381 495.0581 495.1782 495.2982 495.4183 495.5383 495.6583 495.7782 495.8982 496.0181 496.1380 496.2579 496.3778 496.4977 496.6175 496.7374 496.8572 496.9770 497.0968 497.2166 497.3363 497.4560 497.5758 497.6955 497.8151 497.9348 498.0545 498.1741 498.2937 498.4133 498.5329 498.6524 498.7720 498.8915 499.0110 499.1305 499.2500 499.3695 499.4889 499.6083 499.7278 499.8471 499.9665 500.0859 500.2052 500.3245 500.4439 500.5631 500.6824 500.8017 500.9209 501.0401 501.1593 501.2785 501.3977 501.5169 501.6360 501.7551 501.8742 501.9933 502.1124 502.2314 502.3505 502.4695 502.5885 502.7075 502.8264 502.9454 503.0643 503.1832 503.3021 503.4210 503.5399 503.6587 503.7775 503.8963 504.0151 504.1339 504.2527 504.3714 504.4901 504.6089 504.7275 504.8462 504.9649 505.0835 505.2021 505.3207 505.4393 505.5579 505.6764 505.7950 505.9135 506.0320 506.1505 506.2690 506.3874 506.5058 506.6243 506.7426 506.8610 506.9794 507.0977 507.2161 507.3344 507.4527 507.5709 507.6892 507.8074 507.9257 508.0439 508.1621 508.2802 508.3984 508.5165 508.6347 508.7528 508.8708 508.9889 509.1070 509.2250 509.3430 509.4610 509.5790 509.6970 509.8149 509.9328 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20260404T233418.6Z 9590.982160 633 1 2.27 2 53.38 21.82 101.22 224.12 0.00 1 0.00 1 0 15 3.922e-03 3.911e-03 2.785e-03 2.780e-03 2.169704e+03 1.617106e+02 1.624406e+02 -6.000000e+00 2.130087e+02 277.99 -2.00 20.00 -2.00 505.26 0.00e+00 3.707690e-04 7.521509e-05 2.493146e-05 -6.000000e+00 1.083157e-04 277.99 -2.00 20.00 -2.00 500.45 0.00e+00 -4.342378e-02 5.456536e-02 1.626264e-02 -6.000000e+00 7.732226e-02 225.98 -2.00 3.69 -2.00 502.04 0.00e+00 1.672 0.000 489.00 513.00 1 6.2011e+00 4.1775e-03 2.7316e-03 -6.0000e+00 5.9200e-03 1.6093e-02 1.0778e-03 4.1298e-04 -6.0000e+00 1.5337e-03 3.1524e-03 1.4202e-03 2.7157e-04 2.2870e-05 -6.0000e+00 3.9474e-04 2.1438e-02 6.7976e-05 12 9 1 12 1 1 999.00 25.31 1.93 0.02144 0.03129 1 5 1 2 0 1132.690 20.01 25.31 19.54 35.25 33.75 0.9 960.76 -585 -482 144 -73 239 54 984 365 536 447 641 -627 -283 -81 37 -645 -82 -151 261 214 338 166 -182 166 172 501 -149 -85 -257 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-425 -32 77 -132 217 462 318 503 679 625 213 99 406 596 114 61 -32 524 428 -242 -2 346 -10 -162 -70 -419 116 -387 -270 -360 -120 726 100 147 304 279 229 30 -468 -418 -280 -75 150 SQ 20260404T234601.0Z 9590.990289 641 1 54.12 2 52.67 18.28 102.56 221.81 0.00 1 0.00 1 0 15 3.029e-03 3.019e-03 3.896e-04 3.890e-04 1.982682e+03 2.250691e+01 1.483266e+02 -6.000000e+00 1.645139e+02 277.99 -2.00 20.00 -2.00 505.26 0.00e+00 2.976752e-04 1.052400e-05 1.902770e-05 -6.000000e+00 8.365846e-05 277.99 -2.00 20.00 -2.00 500.45 0.00e+00 2.529912e-02 7.644564e-03 1.488412e-02 -6.000000e+00 5.972760e-02 225.98 -2.00 3.69 -2.00 502.04 0.00e+00 1.645 0.000 489.00 513.00 1 6.1357e+00 5.8518e-04 2.6161e-03 -6.0000e+00 4.5728e-03 1.3582e-02 1.5119e-04 3.8137e-04 -6.0000e+00 1.1849e-03 3.3652e-03 1.3799e-03 3.7997e-05 2.0407e-05 -6.0000e+00 3.0491e-04 2.2760e-02 4.8322e-05 10 0 0 10 0 0 99.97 25.31 1.94 0.02276 0.03233 65 7 1 2 0 832.590 20.00 25.31 20.01 35.25 33.75 0.9 963.19 -634 -543 -57 -158 161 470 560 360 398 409 377 -26 -250 -235 -242 -305 -70 23 46 -19 249 163 109 241 254 370 405 78 -540 -260 -348 -551 -223 369 -8 -45 123 16 -110 46 -13 -38 35 287 271 321 354 422 249 -367 -513 -649 -793 -466 -294 -306 -96 14 -25 109 253 329 378 274 273 222 195 13 -158 -385 -214 -100 -147 57 72 -73 -149 -316 -469 -431 -397 -285 -387 -103 -82 -258 -203 -82 -93 -133 -26 256 457 260 452 377 247 -316 -398 -385 -556 -570 -251 18 8 -192 -163 -231 -322 -149 -29 -114 148 279 154 514 661 546 339 297 369 -12 70 205 152 67 300 134 198 310 89 -107 11 -278 -531 -253 77 -208 -55 176 93 179 261 337 311 154 -14 -302 -393 -348 -316 -627 -536 -57 -160 168 489 592 377 422 427 389 -27 -255 -236 -243 -309 -72 24 48 -20 262 172 115 255 268 391 425 81 -556 -263 -349 -557 -225 382 -9 -47 129 16 -112 48 -13 -39 36 298 280 332 369 434 256 -369 -509 -641 -778 -459 -291 -307 -97 14 -25 111 256 335 385 279 276 225 195 13 -156 -377 -208 -97 -145 56 70 -72 -147 -307 -451 -412 -381 -275 -377 -101 -80 -255 -201 -81 -92 -132 -26 254 458 262 452 371 243 -304 -380 -367 -528 -540 -243 18 8 -189 -162 -226 -313 -145 -28 -113 147 280 155 520 660 546 343 297 363 -12 68 200 150 66 295 132 194 302 86 -102 11 -265 -504 -241 74 -202 -54 173 92 178 257 332 307 151 -14 -291 -378 -331 -302 SQ 20260405T000225.8Z 9591.001687 653 1 9.35 2 51.89 13.22 104.33 218.50 0.00 1 0.00 1 0 15 3.768e-03 3.767e-03 1.520e-03 1.517e-03 1.983403e+03 8.775349e+01 1.520360e+02 -6.000000e+00 2.046467e+02 277.99 -2.00 20.00 -2.00 505.26 0.00e+00 2.812928e-04 4.103711e-05 1.971498e-05 -6.000000e+00 1.040672e-04 277.99 -2.00 20.00 -2.00 500.46 0.00e+00 2.374571e-02 2.976792e-02 1.409462e-02 -6.000000e+00 7.429891e-02 225.98 -2.00 3.69 -2.00 502.05 0.00e+00 1.616 0.000 489.00 513.00 1 6.8593e+00 2.2789e-03 2.5579e-03 -6.0000e+00 5.6884e-03 9.4665e-03 5.8836e-04 3.7168e-04 -6.0000e+00 1.4740e-03 1.6391e-03 1.5705e-03 1.4834e-04 2.1002e-05 -6.0000e+00 3.7930e-04 1.9619e-02 6.6579e-05 12 1 1 12 33 1 99.27 25.31 1.92 0.01962 0.03051 4 3 1 2 0 1869.250 20.00 25.31 21.18 35.00 33.75 0.9 969.05 -689 -614 321 -150 154 214 878 362 506 336 121 131 -405 -320 -456 -428 -280 2 56 -135 97 280 140 612 469 175 306 52 -740 -236 -659 -659 -136 161 285 -33 193 8 -33 474 54 -110 -2 436 530 343 740 473 35 -374 -537 -392 -979 -565 -569 -500 -331 -97 175 76 70 655 320 359 64 191 277 -145 -198 -311 -157 83 -55 211 -216 238 -198 -283 -494 -437 -151 -196 -603 151 -48 -320 -321 -73 -79 -258 -216 378 571 38 831 549 325 -517 -505 -408 -578 -428 -235 -154 -88 -172 -158 -51 -157 -125 -1 -264 35 366 500 686 685 394 350 195 63 -313 73 390 167 -166 52 -118 366 534 32 30 196 -553 -569 -613 12 -303 -187 344 364 320 507 351 441 218 15 -454 -270 -499 -522 -677 -600 321 -153 158 223 924 378 535 351 125 134 -416 -325 -462 -437 -284 2 59 -142 102 294 147 642 494 185 321 54 -765 -240 -667 -671 -137 164 298 -35 202 8 -34 488 55 -113 -2 453 555 359 768 485 36 -378 -537 -382 -952 -552 -558 -505 -335 -98 178 77 71 664 327 365 65 191 277 -144 -194 -306 -154 81 -53 207 -214 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