File name: Pandora272s1_Lauder_20260506_L2Fit_fwvt1c6d20241202p1-8.txt File generation date: 20260704T072844.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c6p1-8 Local principal investigator: Richard Querel Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 272 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora272_OF_v3d20240829.txt Instrument calibration file used: Pandora272s1_CF_v6d20241202.txt Level 1 file used: Pandora272s1_Lauder_20260506_L1_smca1c6d20241202p1-8.txt Full location name: Lauder Atmospheric Research Station Short location name: Lauder Country of location: New Zealand Location latitude [deg]: -45.0380 Location longitude [deg]: 169.6840 Location altitude [m]: 370 Local noon date: 20260506 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1622 1772 Nominal wavelengths inside fitting window [nm]: 492.0719 492.1924 492.3129 492.4333 492.5537 492.6742 492.7946 492.9149 493.0353 493.1557 493.2760 493.3963 493.5166 493.6369 493.7571 493.8774 493.9976 494.1178 494.2380 494.3582 494.4784 494.5985 494.7187 494.8388 494.9589 495.0789 495.1990 495.3190 495.4391 495.5591 495.6791 495.7991 495.9190 496.0390 496.1589 496.2788 496.3987 496.5186 496.6384 496.7583 496.8781 496.9979 497.1177 497.2375 497.3572 497.4770 497.5967 497.7164 497.8361 497.9558 498.0754 498.1950 498.3147 498.4343 498.5539 498.6734 498.7930 498.9125 499.0320 499.1515 499.2710 499.3905 499.5099 499.6294 499.7488 499.8682 499.9876 500.1069 500.2263 500.3456 500.4649 500.5842 500.7035 500.8228 500.9420 501.0613 501.1805 501.2997 501.4188 501.5380 501.6571 501.7763 501.8954 502.0145 502.1335 502.2526 502.3716 502.4907 502.6097 502.7287 502.8476 502.9666 503.0855 503.2044 503.3233 503.4422 503.5611 503.6799 503.7988 503.9176 504.0364 504.1552 504.2739 504.3927 504.5114 504.6301 504.7488 504.8675 504.9862 505.1048 505.2235 505.3421 505.4607 505.5792 505.6978 505.8163 505.9349 506.0534 506.1718 506.2903 506.4088 506.5272 506.6456 506.7640 506.8824 507.0008 507.1191 507.2375 507.3558 507.4741 507.5924 507.7106 507.8289 507.9471 508.0653 508.1835 508.3017 508.4199 508.5380 508.6561 508.7742 508.8923 509.0104 509.1285 509.2465 509.3645 509.4825 509.6005 509.7185 509.8364 509.9544 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20260505T202015.7Z 9621.847404 528 1 6.60 2 84.70 60.33 56.07 263.35 0.00 1 0.00 1 0 15 3.954e-03 3.925e-03 1.181e-04 1.180e-04 4.699423e+03 7.176605e+00 3.414114e+02 -6.000000e+00 2.131232e+02 276.22 -2.00 20.00 -2.00 505.32 0.00e+00 7.321054e-04 3.191739e-06 4.572805e-05 -6.000000e+00 1.087629e-04 276.22 -2.00 20.00 -2.00 500.69 0.00e+00 6.812350e-01 2.288692e-03 3.569705e-02 -6.000000e+00 7.769728e-02 222.70 -2.00 3.69 -2.00 502.25 0.00e+00 9.426 0.010 489.00 513.00 1 7.9094e-01 1.7499e-04 1.3312e-02 -6.0000e+00 5.9476e-03 -2.2988e-03 4.4687e-05 1.1175e-03 -6.0000e+00 1.5400e-03 2.3140e-01 1.0742e-03 1.1422e-05 4.8947e-05 -6.0000e+00 3.9784e-04 7.0915e-03 4.2243e-05 11 8 0 10 0 0 29.51 25.13 1.37 0.00709 0.01454 520 54 2 2 0 12.690 20.00 25.13 19.26 35.00 34.00 1.0 961.27 -874 -609 -169 -93 273 627 721 605 500 481 380 19 -378 -309 -351 -399 -128 64 53 55 256 195 159 383 386 466 515 94 -549 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-375 -156 -73 -22 258 384 500 665 842 744 484 437 264 87 143 353 161 187 349 307 279 442 112 -167 -90 -328 -606 -240 -38 -134 20 252 173 176 359 397 371 246 -62 -414 -511 -543 -502 SQ 20260505T202022.5Z 9621.847483 528 2 6.60 2 84.69 60.31 56.09 263.33 0.00 1 0.00 1 0 22 3.914e-03 3.884e-03 1.231e-04 1.230e-04 4.685215e+03 7.469434e+00 3.404997e+02 -6.000000e+00 2.109245e+02 276.22 -2.00 20.00 -2.00 505.32 0.00e+00 7.301527e-04 3.327353e-06 4.555924e-05 -6.000000e+00 1.076402e-04 276.22 -2.00 20.00 -2.00 500.69 0.00e+00 6.883731e-01 2.385444e-03 3.552944e-02 -6.000000e+00 7.689274e-02 222.70 -2.00 3.69 -2.00 502.25 0.00e+00 9.402 0.010 489.00 513.00 1 8.7773e-01 1.8237e-04 1.3277e-02 -6.0000e+00 5.8861e-03 -2.5045e-03 4.6596e-05 1.1133e-03 -6.0000e+00 1.5240e-03 2.1273e-01 1.0772e-03 1.1923e-05 4.8918e-05 -6.0000e+00 3.9372e-04 4.8209e-03 5.8921e-05 11 8 0 10 0 0 50.75 25.13 1.37 0.00482 0.01229 520 54 2 2 0 12.690 20.00 25.13 19.26 35.00 34.00 1.0 961.27 -881 -593 -171 -58 241 624 716 600 508 463 413 16 -365 -302 -346 -390 -155 60 48 40 258 202 152 370 411 440 503 113 -549 -340 -434 -629 -321 303 50 57 209 54 -173 -160 -8 -37 191 309 456 398 443 372 131 -376 -615 -777 -915 -680 -389 -218 -67 156 85 206 351 448 405 415 362 207 189 16 -284 -531 -336 -238 -275 -51 -1 -197 -312 -339 -599 -658 -460 -457 -561 -276 -61 -236 -300 -187 -128 -142 53 368 558 393 488 559 221 -199 -553 -710 -870 -732 -419 -30 -107 -145 -149 -378 -372 -149 -88 -30 225 369 462 653 845 713 464 452 261 79 131 392 174 188 355 297 284 447 119 -161 -77 -327 -605 -233 -33 -118 13 229 160 164 345 384 339 243 -77 -418 -511 -543 -466 -831 -568 -166 -57 240 627 724 612 517 465 415 16 -362 -298 -339 -385 -154 61 49 41 264 207 155 378 421 451 514 115 -553 -338 -428 -620 -319 307 51 59 214 56 -175 -163 -8 -37 194 317 467 409 452 379 132 -376 -603 -754 -891 -661 -383 -219 -67 158 87 210 357 453 412 421 364 208 189 16 -281 -519 -328 -234 -271 -50 -1 -195 -308 -329 -582 -636 -446 -443 -549 -271 -60 -234 -298 -185 -126 -141 53 368 559 395 489 556 217 -193 -529 -675 -827 -700 -404 -30 -107 -146 -149 -378 -368 -147 -88 -30 227 373 470 667 859 729 474 461 263 79 131 392 173 189 356 298 285 447 119 -160 -76 -321 -595 -228 -33 -118 13 232 163 168 354 396 351 251 -79 -422 -511 -544 -465 SQ 20260505T202029.2Z 9621.847560 528 3 6.60 2 84.67 60.29 56.11 263.32 0.00 1 0.00 1 0 22 3.881e-03 3.853e-03 1.328e-04 1.327e-04 4.676363e+03 8.073924e+00 3.400946e+02 -6.000000e+00 2.091759e+02 276.22 -2.00 20.00 -2.00 505.32 0.00e+00 7.214975e-04 3.590990e-06 4.513924e-05 -6.000000e+00 1.067478e-04 276.22 -2.00 20.00 -2.00 500.69 0.00e+00 6.860652e-01 2.574231e-03 3.546078e-02 -6.000000e+00 7.625542e-02 222.70 -2.00 3.69 -2.00 502.25 0.00e+00 9.379 0.010 489.00 513.00 1 1.0331e+00 1.9680e-04 1.3243e-02 -6.0000e+00 5.8373e-03 -2.6518e-03 5.0283e-05 1.1115e-03 -6.0000e+00 1.5113e-03 1.8274e-01 1.1195e-03 1.2868e-05 4.8336e-05 -6.0000e+00 3.9046e-04 6.4964e-03 4.8540e-05 11 8 0 10 0 0 6.77 25.13 1.36 0.00650 0.01426 520 54 2 2 0 12.690 20.00 25.13 19.47 35.00 34.00 1.0 961.27 -871 -571 -157 -43 236 609 706 576 516 488 388 -3 -358 -285 -342 -408 -192 71 53 42 261 199 175 386 394 443 499 90 -573 -347 -425 -625 -321 313 83 58 207 32 -165 -175 -31 -11 198 308 460 386 451 374 139 -379 -639 -794 -898 -682 -376 -194 -57 148 78 203 341 453 423 406 366 182 222 -7 -298 -523 -315 -216 -258 -59 -2 -224 -289 -335 -586 -640 -448 -476 -566 -280 -78 -240 -267 -193 -133 -133 16 365 557 372 470 555 231 -217 -532 -700 -828 -737 -415 -65 -93 -180 -126 -350 -372 -139 -52 -36 259 369 477 653 838 698 449 414 252 77 144 352 152 181 337 298 272 434 122 -147 -96 -337 -599 -248 -20 -141 36 246 182 193 329 370 355 216 -52 -396 -488 -558 -504 -822 -547 -152 -42 235 611 712 586 523 494 389 -3 -353 -281 -337 -402 -190 71 54 43 267 204 179 396 406 453 512 91 -575 -344 -418 -620 -320 315 86 60 212 33 -168 -177 -32 -12 202 315 473 398 462 383 140 -377 -631 -776 -872 -668 -369 -194 -57 150 79 205 344 460 431 413 370 184 221 -7 -293 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