File name: Pandora183s1_LondonderryNH_20210604_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20251126T070712.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora183_OF_v1d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20210604_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20210604 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210604T112644.5Z 7825.476904 197 1 28.75 2 67.30 79.78 46.77 156.68 0.00 1 0.00 1 0 17 7.773e-02 1.061e-02 7.513e-02 6.395e-03 3.840338e-01 3.261355e-03 4.522790e-03 -6.000000e+00 4.475065e-02 232.22 -2.00 3.55 -2.00 319.36 0.00e+00 1.639269e-03 8.439417e-04 9.720317e-04 -6.000000e+00 1.953391e-03 283.88 -2.00 20.00 -2.00 318.61 0.00e+00 2.570 0.000 302.00 328.00 3 4.6204e+00 9.2508e-03 3.2898e-02 -6.0000e+00 1.1237e-01 4.8902e-02 1.0767e-02 2.0754e-02 -6.0000e+00 1.2170e-01 -8.3917e-03 8.0644e-03 1.0327e-02 -6.0000e+00 7.2298e-02 -4.9477e-03 4.2174e-03 3.0029e-03 -6.0000e+00 3.0324e-02 2.4571e-04 -3.8827e-04 1.8527e-04 3.1455e-05 -6.0000e+00 2.0530e-03 1.9154e-03 -4.7697e-05 12 8 8 10 0 0 98.20 23.26 0.67 0.00192 -0.00100 9 9 1 5 0 3193.130 26.94 20.05 23.26 28.00 4.5 1003.46 -3555 43458 -29019 -32436 -26386 -23753 -13571 -26290 -8443 -21051 8188 289 -2985 -11955 -11217 -9776 13363 9572 -4879 2659 -7169 -471 10725 5762 -2652 12490 1881 -5864 -2252 -7998 -6607 -8179 6598 -4290 -9967 2586 -3471 -4476 -376 -374 -2281 -1910 871 -3315 -1008 -2385 820 -2614 4214 2199 4428 -1587 783 3959 -1227 4003 -665 840 297 678 465 4079 3357 2106 807 1030 1188 -561 -254 798 2982 1287 1134 -211 1855 1570 -1466 -2811 -2615 -2212 -397 -1474 -2511 -2592 -372 -868 -322 -154 843 880 360 530 -2268 753 -1236 -353 1701 117 826 -801 -349 -2419 61 -679 -2014 -654 -1161 320 431 233 1375 22 695 -112 -103 85 -298 98 559 -290 63 1363 378 1004 -108 -723 523 1394 -238 118 -443 -554 -299 -183 -197 -630 1070 1238 -24 -21 117 -1359 -653 -74 715 -1053 -1195 -823 -673 -362 -894 -273 -835 246 10 -118 -624 -693 -687 811 640 -401 213 -654 -40 827 497 -266 1133 193 -625 -218 -898 -795 -1127 876 -680 -1598 350 -535 -812 -79 -94 -656 -581 268 -1087 -324 -785 261 -854 1285 697 1463 -609 315 1644 -561 1785 -318 397 138 309 218 1987 1819 1261 503 604 651 -308 -148 526 2128 980 865 -157 1252 954 -832 -1551 -1525 -1470 -296 -1243 -2310 -2507 -376 -859 -335 -165 897 994 379 510 -2075 656 -1177 -373 1988 142 1064 -1040 -422 -2990 69 -788 -2567 -870 -1478 423 605 354 2214 37 1126 -172 -146 124 -438 137 831 -460 101 2104 571 1590 -164 -1058 721 1939 -367 197 -720 -933 -515 -330 -379 -1278 2185 2574 -51 -43 228 -2563 -1197 SS 20210604T114522.8Z 7825.489847 207 1 14.21 2 63.92 82.72 45.54 162.80 0.00 1 0.00 1 0 17 2.360e-02 7.404e-03 8.255e-03 1.620e-03 3.365826e-01 8.200361e-04 4.012961e-03 -6.000000e+00 1.358767e-02 232.22 -2.00 3.55 -2.00 318.07 0.00e+00 9.521541e-04 1.449650e-04 5.314507e-04 -6.000000e+00 5.931006e-04 283.88 -2.00 20.00 -2.00 317.31 0.00e+00 2.261 0.000 302.00 328.00 3 2.4444e+00 2.2160e-03 2.8765e-02 -6.0000e+00 3.4118e-02 1.4756e-02 2.5079e-03 1.7827e-02 -6.0000e+00 3.6952e-02 -5.7371e-03 1.6012e-03 8.6645e-03 -6.0000e+00 2.1951e-02 -2.5005e-03 8.2019e-04 2.3943e-03 -6.0000e+00 9.2078e-03 3.1763e-03 -3.1578e-04 4.5539e-05 2.4068e-05 -6.0000e+00 6.2333e-04 1.8349e-03 -3.3903e-05 12 9 1 12 1 1 99.82 23.34 0.34 0.00183 -0.00054 30 66 1 5 0 452.510 27.05 19.99 23.34 28.62 4.6 1008.10 -9770 -8363 -1664 -2787 -5418 -8453 -7430 -6433 -5522 -7756 -7130 -6884 -5439 -5185 271 -1226 299 -425 5 681 1129 -686 1110 347 269 1238 -329 -126 -2494 -856 1305 -235 1477 -84 -2803 -3556 -3629 -2930 -660 -891 -148 -113 -467 -603 151 674 337 -713 -532 -755 228 1044 1448 1276 693 1261 963 841 81 -97 1369 2284 2897 2869 883 -12 -164 -997 844 910 772 978 493 355 -79 -603 -1128 -2087 -952 -1380 -1143 -1439 -2195 -1361 -633 -433 -236 334 954 542 469 -107 -812 -171 -486 -585 272 786 -73 -483 -633 -1432 -663 -451 -1235 -1152 -661 -811 5 477 846 367 699 216 -198 149 75 95 572 569 439 559 825 681 584 42 213 734 202 -107 -194 -359 -209 102 -133 -147 428 481 -17 -203 -252 -687 -744 -580 -561 -111 -183 -326 -487 -440 -424 -409 -635 -585 -572 -503 -564 33 -172 44 -67 1 117 199 -122 197 66 54 261 -71 -26 -496 -164 262 -53 364 -22 -730 -891 -973 -908 -220 -354 -65 -53 -226 -298 74 331 165 -348 -256 -369 117 576 852 732 416 773 606 531 50 -59 851 1511 2094 2248 665 -9 -118 -705 622 705 663 879 446 310 -64 -482 -818 -1456 -689 -1141 -989 -1393 -2140 -1381 -681 -500 -268 390 1111 656 527 -110 -836 -170 -518 -646 334 1000 -100 -660 -811 -1808 -779 -543 -1519 -1499 -897 -1156 7 718 1351 566 1107 322 -291 206 103 137 824 871 684 854 1221 967 843 59 280 972 291 -158 -301 -577 -343 164 -229 -266 789 853 -30 -375 -445 -1167 -1238 SS 20210604T115102.3Z 7825.493776 210 1 29.72 2 62.89 83.62 45.23 164.71 0.00 1 0.00 1 0 17 2.613e-02 7.142e-03 1.569e-02 2.511e-03 3.237371e-01 1.272631e-03 3.848179e-03 -6.000000e+00 1.504760e-02 232.22 -2.00 3.55 -2.00 318.46 0.00e+00 5.600505e-04 2.486353e-04 5.852241e-04 -6.000000e+00 6.567995e-04 283.88 -2.00 20.00 -2.00 317.68 0.00e+00 2.183 0.000 302.00 328.00 3 3.8115e+00 3.4730e-03 2.7762e-02 -6.0000e+00 3.7784e-02 1.9531e-02 3.9540e-03 1.7273e-02 -6.0000e+00 4.0920e-02 2.8796e-03 2.6131e-03 8.3687e-03 -6.0000e+00 2.4309e-02 -8.4118e-03 1.3503e-03 2.2786e-03 -6.0000e+00 1.0198e-02 8.8728e-04 -4.3784e-05 7.2193e-05 2.3327e-05 -6.0000e+00 6.9019e-04 1.6163e-03 4.7065e-06 11 8 0 10 0 0 99.95 23.33 0.31 0.00162 0.00129 21 21 1 5 0 1414.790 27.05 19.99 23.33 28.93 4.5 1009.93 -6791 -11038 5119 -4102 -8852 -7272 -3938 -9169 -5779 -12295 -5520 -9265 2644 -4894 484 830 -1935 -562 773 758 -887 756 833 1424 -940 1076 -1104 -3018 -1386 -2129 1362 1049 1401 777 -3762 -3580 -3479 -2793 -1197 -159 -725 -671 179 -932 -180 -58 403 -626 171 -733 267 1542 247 1169 1030 1271 1237 254 476 559 1415 2229 1870 2780 -92 207 -440 -399 1144 1074 657 950 943 682 -373 -360 -1575 -1679 -200 -1363 -1508 -1016 -2326 -992 -648 -276 0 427 676 1046 684 -291 -639 -633 -700 -362 -8 561 127 -280 -475 -1533 -773 -392 -1371 -1032 -686 -715 112 459 949 472 390 370 -267 -85 24 -104 634 227 154 909 945 241 400 -319 40 916 263 60 -432 -507 -478 -103 120 -97 349 538 312 -88 -29 -889 -641 -314 -609 254 -217 -439 -330 -180 -496 -343 -843 -356 -692 197 -461 51 98 -252 -76 108 111 -136 114 127 228 -165 194 -207 -551 -232 -351 231 198 290 172 -827 -750 -779 -723 -370 -58 -295 -289 79 -424 -81 -26 180 -277 74 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