File name: Pandora183s1_LondonderryNH_20210617_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20251125T164646.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora183_OF_v1d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20210617_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20210617 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210617T095014.2Z 7838.409886 84 1 29.74 2 83.89 63.56 127.42 350.13 0.00 1 0.00 1 0 33 5.359e-01 3.858e-02 4.804e-01 3.116e-02 1.050914e+00 1.829406e-02 1.173937e-02 -6.000000e+00 3.180018e-01 232.92 -2.00 3.55 -2.00 322.54 0.00e+00 -1.759951e-02 9.326065e-03 1.062938e-03 -6.000000e+00 1.421312e-02 285.19 -2.00 20.00 -2.00 322.06 0.00e+00 8.406 0.011 302.00 328.00 3 2.0631e-01 7.3435e-02 1.0269e-01 -6.0000e+00 8.0320e-01 1.7834e+00 8.9823e-02 6.3621e-02 -6.0000e+00 8.7438e-01 -2.3494e+00 5.4183e-02 2.8575e-02 -6.0000e+00 5.1467e-01 9.1480e-01 2.8440e-02 1.3379e-02 -6.0000e+00 2.1334e-01 3.6127e-05 -1.2261e-03 8.1594e-04 1.7939e-04 -6.0000e+00 1.4495e-02 5.0729e-03 -6.2120e-05 12 8 8 10 0 0 27.64 23.15 0.65 0.00507 -0.00414 25 25 1 5 0 1189.260 26.83 19.99 23.15 14.61 5.4 909.19 18443 68424 53954 47721 -26679 17840 32853 -92968 -6768 -42571 15290 900000 -3469 106806 19287 90928 6548 -8996 167000 12083 202440 -12086 28143 37290 109503 -2573 72835 -29209 209382 64310 -64561 -30331 10808 900000 900000 900000 69518 -15714 101392 -32810 -3702 38079 -9739 900000 42522 900000 62891 54707 -39601 -9401 42739 34485 246358 115380 81104 34639 44160 34244 -11022 49552 108055 111756 154768 57543 1645 44730 3309 50749 61830 19534 23151 33993 -1494 -4786 -3086 26887 6234 -8270 -18179 47319 2572 825 5723 14606 -8841 615 6116 6815 24072 -11138 6994 -3631 18495 -19692 -4472 21895 -732 7486 -8613 -1611 -2661 -10824 -2268 2398 2951 -8462 3051 -4753 7921 -575 131 -3174 -200 1103 -967 -3664 -7094 4503 -2528 4464 4160 5199 4225 -937 441 -5596 3931 1922 2580 831 6 -2113 -2381 203 -8 -233 1025 1416 2801 1132 -410 -3427 -2840 1206 2716 2268 1783 -1620 583 997 -9986 -332 -3082 607 900000 -193 3242 1025 2760 431 -683 5069 672 6145 -703 1068 1415 3324 -163 2211 -1921 6356 1952 -5226 -1995 519 900000 900000 900000 2110 -1041 3078 -3712 -347 2417 -968 900000 2112 900000 2256 2114 -4044 -752 2241 2189 7478 3821 4029 2868 3412 2835 -1308 2872 3280 3392 4698 3811 204 3580 402 4061 4948 2749 3450 4690 -285 -859 -477 2938 776 -1230 -3421 5602 570 218 1616 4035 -3274 219 2135 2400 7015 -4395 2144 -1179 4828 -8189 -1874 8441 -420 4636 -6981 -1237 -1939 -7590 -1301 1296 1702 -5805 1982 -3651 6107 -569 150 -4162 -266 1456 -1271 -4838 -9863 5864 -3729 6274 5658 6581 5169 -1178 533 -6999 4403 2392 3798 1471 11 -4824 -5904 534 -22 -701 3087 4276 8206 3164 -1064 -8374 -6620 SS 20210617T100144.9Z 7838.417881 87 1 30.05 2 81.99 65.40 127.75 353.54 0.00 1 0.00 1 0 17 6.091e-01 1.762e-02 3.015e-01 7.494e-03 9.298550e-01 4.255264e-03 1.065237e-02 -6.000000e+00 3.545778e-01 232.92 -2.00 3.55 -2.00 322.21 0.00e+00 6.640634e-03 2.694355e-03 7.175807e-03 -6.000000e+00 1.542198e-02 285.19 -2.00 20.00 -2.00 321.75 0.00e+00 6.702 0.006 302.00 328.00 3 1.5036e-01 1.7866e-02 9.0539e-02 -6.0000e+00 8.9316e-01 7.8067e-01 2.6279e-02 6.5258e-02 -6.0000e+00 9.6872e-01 -1.0292e+00 2.5730e-02 3.4077e-02 -6.0000e+00 5.7511e-01 3.9707e-01 1.1441e-02 1.0457e-02 -6.0000e+00 2.3925e-01 2.2674e-04 -8.4564e-04 1.9348e-04 2.3252e-04 -6.0000e+00 1.6105e-02 3.5796e-03 -4.2818e-05 12 8 8 10 0 0 -6.07 23.13 0.51 0.00358 -0.00277 67 67 1 5 0 448.260 26.73 20.00 23.13 15.71 5.4 917.14 -170759 -147010 -221104 -155446 -41226 -246383 -190887 -190093 -109318 -227631 -191228 -163703 -148311 -114347 -77862 900000 -106603 900000 -64315 -33011 6687 -11600 34276 -13710 -14713 -89882 -33161 -22843 -44761 -96962 -10581 -61394 -16851 -35149 -53881 7476 -32076 30036 -27907 13672 18999 23645 38900 21634 23490 2251 42335 5206 11880 36333 11751 26960 30871 43224 21845 45896 34252 7377 29514 11885 19244 15213 22010 18949 17003 13668 14863 20607 17909 16193 9743 16174 13274 11757 4342 5019 1818 -4499 7566 -3582 4993 2887 1460 1714 -3634 1052 1140 1505 1871 2200 1211 -1992 -4106 -4510 -3548 -2331 -567 -1361 -318 -1309 -2446 -2118 -5065 -1879 -4269 -2896 -3330 -1532 -539 334 444 -425 -380 -564 -797 -400 27 172 711 813 1393 2245 1813 917 1290 529 277 1129 515 -107 787 201 -682 -185 -174 -215 154 1335 -5 -156 -360 -874 -1265 -1767 -1432 -4846 -1703 -301 -5250 -2324 -2430 -799 -4712 -2794 -1993 -1986 -1462 -901 900000 -2336 900000 -1196 -460 62 -123 250 -155 -176 -2328 -485 -288 -684 -2705 -155 -1876 -392 -1074 -1897 134 -895 519 -1038 400 593 754 1111 747 796 96 1361 255 581 1513 704 1576 1917 2589 1724 2951 2527 701 2135 981 1490 1345 2106 2173 2174 1817 1965 2710 2695 2875 2043 3308 2735 2276 809 821 288 -792 1371 -890 1368 943 540 674 -1601 469 531 717 883 995 516 -829 -1722 -2030 -1840 -1432 -408 -1157 -298 -1256 -2223 -1700 -3737 -1326 -3306 -2344 -2873 -1414 -555 397 604 -636 -585 -860 -1174 -570 39 261 1137 1331 2200 3321 2578 1276 1731 694 357 1556 839 -204 1527 428 -1566 -456 -461 -598 435 3762 -14 -416 -889 -2005 -2811 SS 20210617T101932.4Z 7838.430236 93 1 29.91 2 78.99 68.21 128.02 358.85 0.00 1 0.00 1 0 17 6.457e-01 9.654e-03 9.065e-02 1.956e-03 7.484881e-01 1.060593e-03 8.843056e-03 -6.000000e+00 3.726992e-01 232.92 -2.00 3.55 -2.00 321.45 0.00e+00 3.630415e-03 5.542726e-04 5.254870e-03 -6.000000e+00 1.631706e-02 285.19 -2.00 20.00 -2.00 320.87 0.00e+00 5.046 0.002 302.00 328.00 3 -4.2299e-02 3.7639e-03 6.8942e-02 -6.0000e+00 9.3704e-01 1.4348e-01 5.4499e-03 5.1866e-02 -6.0000e+00 1.0142e+00 -1.8264e-01 5.6791e-03 2.6280e-02 -6.0000e+00 6.0258e-01 5.9894e-02 2.6321e-03 7.1442e-03 -6.0000e+00 2.5265e-01 1.6843e-03 -4.7386e-04 5.2328e-05 1.2310e-04 -6.0000e+00 1.7060e-02 3.0381e-03 -4.4060e-05 12 8 8 10 0 0 5.31 23.13 0.31 0.00304 -0.00052 199 199 1 5 0 150.230 26.73 19.98 23.13 18.12 5.4 935.40 -217829 -226272 -189387 -198920 -174474 -211036 -225634 -195650 -225734 -160856 -182384 -161985 -129214 -117030 -95057 -97186 -69180 -90879 -29024 -69340 -39598 -56008 -43894 -33217 -43844 -47242 -50395 -43424 -61022 -31213 -35588 -20920 -6109 -17750 -11108 -24919 -11512 -14143 -2092 3102 2200 11527 454 6943 2963 6725 3702 4443 3186 -942 5694 5549 6191 4246 7228 4186 5822 1542 2450 3783 1447 4898 3315 6416 4386 3689 1656 639 3854 2185 3218 2532 2439 1573 -258 10 -3649 -3264 -3199 -1409 -866 -49 -1545 -1684 -317 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