File name: Pandora183s1_LondonderryNH_20210628_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20251125T164559.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora183_OF_v1d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20210628_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20210628 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210628T102152.2Z 7849.431854 219 1 28.56 2 79.09 68.31 67.81 212.22 0.00 1 0.00 1 0 17 4.852e-01 2.455e-02 3.247e-01 1.709e-02 5.697266e-01 9.255112e-03 8.107424e-03 -6.000000e+00 2.818520e-01 232.96 -2.00 3.55 -2.00 321.26 0.00e+00 6.839656e-03 4.286079e-03 8.260498e-03 -6.000000e+00 1.249083e-02 286.20 -2.00 20.00 -2.00 320.61 0.00e+00 5.086 0.002 302.00 328.00 3 3.2673e+00 3.1727e-02 7.0212e-02 -6.0000e+00 7.0937e-01 3.1763e-01 4.0687e-02 5.7997e-02 -6.0000e+00 7.6802e-01 -4.2623e-01 3.3765e-02 2.5471e-02 -6.0000e+00 4.5503e-01 1.6678e-01 1.6151e-02 5.2222e-03 -6.0000e+00 1.9066e-01 7.0847e-05 -3.3695e-04 5.0796e-04 1.4991e-04 -6.0000e+00 1.3161e-02 3.4913e-03 -7.3869e-05 12 8 8 10 0 0 37.90 23.21 0.87 0.00349 0.00096 10 10 1 5 0 2855.030 26.83 20.00 23.21 30.40 5.8 1015.70 -175824 10742 -97688 900000 -112615 -90964 -130654 900000 120473 -148908 -118868 -63970 149669 -97496 -65192 -36233 -41021 -61170 6936 -26311 12419 199536 -4600 23999 -67709 250873 -25844 22630 64944 -22972 -32508 58672 35406 38926 17063 45149 46976 49756 8564 19301 24586 28935 13970 29054 1231 22243 32995 2144 21655 1865 1700 25069 16820 30031 34654 4825 16466 7596 11025 8473 -5375 3471 16192 -773 11231 -4133 1525 11751 10157 9153 7878 6897 1319 -2070 -3830 6657 -12932 -4797 -4817 1931 -120 -5732 -2648 -3035 -2763 -87 883 -570 -2759 3923 625 -1413 -2941 -6645 -1667 -870 1745 -774 457 -1465 -2347 -2248 -3660 144 -4990 -1357 -48 -1978 4191 -1820 1656 86 -814 -157 -141 136 792 -1398 -325 2168 2906 1307 4235 1144 463 1436 -476 -1958 1194 -167 -30 -691 -13 -1199 -69 281 899 1436 -542 25 -474 -1725 -504 -7437 179 -2577 900000 -2971 -1768 -3810 900000 2007 -6410 -3796 -1244 2494 -4061 -2444 -1208 -1595 -3143 193 -1060 345 3325 -160 654 -4821 4180 -1253 651 1181 -1044 -1871 1600 1394 1592 827 1573 1708 2035 636 1520 2048 2455 1439 2641 149 2224 2999 270 2296 251 250 3228 2548 4276 4935 950 2943 1473 2004 1553 -1164 752 3483 -220 2977 -1233 455 3192 3046 3188 3072 2839 569 -876 -1513 2119 -4611 -1567 -1734 766 -56 -3247 -1589 -1932 -1874 -61 652 -441 -2184 2804 430 -921 -1842 -4385 -1161 -693 1561 -811 515 -1682 -2546 -2198 -3348 129 -5089 -1416 -52 -2340 5077 -2605 2514 139 -1318 -242 -203 188 1097 -2085 -512 3493 4640 2054 6252 1682 657 1941 -632 -2756 1827 -290 -57 -1378 -27 -2664 -163 692 2251 3641 -1399 60 -1110 -3872 -1092 SS 20210628T102743.0Z 7849.435914 222 1 29.40 2 78.09 69.23 68.36 213.55 0.00 1 0.00 1 0 17 3.552e-01 1.104e-02 1.980e-01 5.498e-03 5.630368e-01 2.950105e-03 6.710679e-03 -6.000000e+00 2.051040e-01 232.96 -2.00 3.55 -2.00 321.04 0.00e+00 3.275938e-03 1.330871e-03 3.412458e-03 -6.000000e+00 9.047276e-03 286.20 -2.00 20.00 -2.00 320.37 0.00e+00 4.693 0.002 302.00 328.00 3 2.2366e+00 9.9100e-03 5.7521e-02 -6.0000e+00 5.1553e-01 5.8014e-02 1.2936e-02 3.6364e-02 -6.0000e+00 5.5813e-01 -1.1961e-01 1.2001e-02 1.8036e-02 -6.0000e+00 3.3157e-01 4.3470e-02 5.8184e-03 4.9091e-03 -6.0000e+00 1.3997e-01 3.0655e-04 -4.4089e-04 1.6139e-04 7.8735e-05 -6.0000e+00 9.4674e-03 3.4340e-03 -3.6938e-05 12 8 8 10 0 0 75.00 23.20 0.38 0.00343 0.00012 30 30 1 5 0 979.900 26.83 19.99 23.20 30.52 5.8 1016.70 900000 29905 39191 -172886 -10704 -177249 -180740 -105237 -124850 -66856 -87457 -102656 -108150 -7922 -74070 -23442 208 -16907 -13007 -34145 -956 -21538 10844 -9724 3969 -8479 -22734 9798 -34068 -1158 -25076 3689 -6922 8559 8863 -16636 10780 -19682 4452 -616 12654 7373 2727 2139 -4354 10356 804 3787 4416 10704 3631 2581 7831 583 571 3991 3817 -1666 4388 669 2084 4119 1788 6756 2676 4949 701 -1526 3637 1298 2958 -355 3102 -389 1256 -910 -2594 -3741 -3375 -1029 -1555 -1948 -2023 -1709 644 612 553 782 1748 1482 837 -1385 -400 -2677 -2087 -1716 -499 912 -640 -116 -901 -2168 -676 -1285 -1882 -1291 -178 -703 869 258 694 910 51 133 -460 14 395 430 -63 784 471 623 918 111 124 -27 235 645 -349 238 -197 332 -554 -23 -10 -562 246 834 42 -128 -207 -818 -70 900000 160 210 -3862 -57 -3563 -3956 -1333 -2190 -717 -1193 -1751 -2372 -81 -1841 -423 3 -354 -285 -982 -21 -567 211 -251 97 -248 -787 239 -1245 -32 -1002 131 -317 404 404 -945 503 -1467 320 -56 1146 759 310 252 -555 1166 101 473 566 1354 541 434 1368 119 123 867 857 -396 960 150 473 1000 502 2024 881 1544 220 -496 1226 518 1291 -168 1418 -176 514 -341 -912 -1320 -1302 -457 -809 -1159 -1320 -1178 464 473 452 660 1464 1204 638 -1002 -272 -1882 -1615 -1521 -502 939 -729 -132 -964 -2336 -662 -1286 -2052 -1484 -213 -822 1086 360 1059 1451 81 203 -663 19 543 621 -98 1265 760 973 1384 163 174 -41 336 956 -531 402 -363 642 -1128 -49 -23 -1366 608 2086 107 -312 -476 -1794 -148 SS 20210628T103314.2Z 7849.439748 225 1 29.59 2 77.14 70.09 68.90 214.80 0.00 1 0.00 1 0 17 2.314e-01 7.622e-03 8.647e-02 2.664e-03 5.315110e-01 1.392221e-03 6.233800e-03 -6.000000e+00 1.336075e-01 232.96 -2.00 3.55 -2.00 320.68 0.00e+00 1.972933e-03 5.630060e-04 2.470839e-03 -6.000000e+00 5.873393e-03 286.20 -2.00 20.00 -2.00 319.98 0.00e+00 4.372 0.002 302.00 328.00 3 1.4752e+00 4.4025e-03 5.2898e-02 -6.0000e+00 3.3584e-01 3.4992e-03 5.6524e-03 3.2067e-02 -6.0000e+00 3.6340e-01 -4.1053e-02 5.2235e-03 1.5799e-02 -6.0000e+00 2.1604e-01 5.1469e-03 2.5845e-03 4.2580e-03 -6.0000e+00 9.0669e-02 9.2878e-04 -3.9032e-04 7.6706e-05 5.8680e-05 -6.0000e+00 6.1146e-03 2.9126e-03 -3.8408e-05 11 8 0 10 0 0 -1.43 23.20 0.38 0.00291 -0.00002 71 71 1 5 0 416.740 26.83 20.01 23.20 30.75 5.8 1018.83 -86597 -106405 -32894 -83799 -105804 -62034 -56098 -33890 -68451 -54963 -74142 -68882 -42016 -50688 -14260 -19102 -15950 -11901 -19004 -11958 -13482 -11434 -16395 -1912 -15625 -1895 -15023 -15818 -21364 -17274 -1649 -2684 -3647 -8832 2146 -14669 -13065 -6024 -6478 -2958 -3519 3217 -1002 1117 3450 -123 288 353 2958 2320 1513 692 2649 2112 1231 3482 177 786 1465 1334 862 2807 1311 3663 2446 -10 1794 -351 1444 1167 1537 1709 758 1448 -686 -314 -2415 -2494 -1890 -1700 -750 -1725 -1994 -1216 -400 344 491 779 1493 1633 291 748 -1099 -1089 -864 -987 -276 1061 376 -675 -741 -1924 -958 -670 -1679 -1635 -1117 -376 106 737 1017 344 460 -49 -324 85 126 280 552 35 457 676 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