File name: Pandora183s1_LondonderryNH_20210803_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20251125T165809.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora183_OF_v1d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20210803_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20210803 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210803T102100.0Z 7885.431250 219 1 29.74 2 83.71 72.08 35.88 113.68 0.00 1 0.00 1 0 25 4.960e-01 2.885e-02 4.353e-01 2.301e-02 9.324668e-01 1.321857e-02 1.020520e-02 -6.000000e+00 2.904189e-01 232.34 -2.00 3.55 -2.00 322.40 0.00e+00 -7.012453e-03 6.989290e-03 3.002490e-03 -6.000000e+00 1.273979e-02 288.20 -2.00 20.00 -2.00 321.89 0.00e+00 8.204 0.010 302.00 328.00 3 1.3777e-01 5.2895e-02 9.8280e-02 -6.0000e+00 7.3124e-01 1.4922e+00 6.6576e-02 5.9647e-02 -6.0000e+00 7.9432e-01 -1.9104e+00 4.4982e-02 2.6040e-02 -6.0000e+00 4.7027e-01 7.3083e-01 2.2274e-02 8.8694e-03 -6.0000e+00 1.9565e-01 5.2905e-05 -1.0758e-03 6.2017e-04 9.6732e-05 -6.0000e+00 1.3357e-02 3.6562e-03 -4.9928e-05 12 8 8 10 0 0 13.95 23.31 0.58 0.00366 -0.00443 29 29 1 5 0 1025.310 26.94 20.00 23.31 18.88 7.8 935.96 183095 78614 -20349 240093 23048 50828 -20907 79046 -25280 32322 -88354 15092 -8451 11843 -9250 67217 141332 -17982 900000 -79564 132061 -46532 36503 30358 -8006 36896 -57628 19650 -21987 900000 85862 -8710 37696 10616 900000 41018 71609 32854 45727 44607 50651 149658 -11980 80621 51151 108152 21856 57808 56157 1788 172088 -2610 150032 68963 52692 53336 55147 26334 29730 21480 -13447 41420 14494 28970 19776 10586 2467 5426 24239 24101 37557 23355 6649 1298 -3321 11301 -26679 -15048 12000 -632 8215 23261 13465 13287 764 -1979 1164 -6345 2690 991 11186 -2515 -6133 -7377 -9078 2130 1520 -1745 -2858 -4871 311 -8349 3478 -7662 -4047 -291 -3154 2445 -2152 -201 -337 -488 104 -2362 187 461 588 -2708 -104 -373 3036 3007 2821 2983 1383 3735 -3467 3716 -1022 2068 -2652 7 -264 1322 -334 -349 1054 801 882 -973 -380 -862 -1667 4106 1763 -1088 5384 557 1140 -649 1773 -916 725 -6439 395 -316 420 -467 1759 3169 -1176 900000 -9218 2961 -3304 1091 1021 -419 1241 -4738 661 -986 900000 1925 -479 1460 563 900000 1338 1752 1340 1958 2273 2685 3356 -1221 3123 2503 2866 1337 2475 2519 146 3859 -271 3670 4077 3867 4023 4160 2577 2606 1883 -1617 3040 1566 3071 2459 1424 357 796 3261 3734 5589 4142 1355 257 -670 1723 -5504 -2835 1964 -142 2008 5686 4046 4261 295 -830 493 -2959 1134 407 3863 -942 -2352 -3061 -4438 1108 941 -1303 -2397 -4227 240 -6272 2082 -5086 -2786 -205 -2426 1936 -2012 -214 -415 -658 144 -3332 249 595 771 -3868 -154 -568 4350 4087 3688 3793 1737 4455 -4361 4691 -1591 3645 -5525 15 -631 3358 -932 -1025 3107 2393 2606 -2770 -991 -2087 -3921 SS 20210803T103201.1Z 7885.438901 222 1 30.12 2 81.78 73.88 34.07 116.68 0.00 1 0.00 1 0 17 6.070e-01 1.564e-02 2.308e-01 5.873e-03 7.989930e-01 3.238676e-03 9.370667e-03 -6.000000e+00 3.496423e-01 232.34 -2.00 3.55 -2.00 321.97 0.00e+00 4.445105e-03 1.971944e-03 7.163414e-03 -6.000000e+00 1.553486e-02 288.20 -2.00 20.00 -2.00 321.44 0.00e+00 6.552 0.005 302.00 328.00 3 1.4910e-01 1.3120e-02 8.5979e-02 -6.0000e+00 8.7689e-01 4.7158e-01 1.8918e-02 6.3561e-02 -6.0000e+00 9.4900e-01 -6.5891e-01 1.8098e-02 2.9518e-02 -6.0000e+00 5.6516e-01 2.5720e-01 8.1623e-03 7.1143e-03 -6.0000e+00 2.3796e-01 3.2223e-04 -8.8615e-04 1.5855e-04 1.4330e-04 -6.0000e+00 1.6036e-02 3.1696e-03 -4.1893e-05 12 8 8 10 0 0 -13.99 23.29 0.46 0.00317 -0.00349 78 78 1 5 0 386.040 26.94 20.00 23.29 20.31 7.8 945.80 -190337 -98206 -211233 -173823 -246470 -215201 -198991 -197075 -139500 -161616 20533 -217091 -118201 -114945 -86130 -91567 -91197 -58728 -37359 29231 -79314 -65091 -81285 -30501 -12762 -38292 -42776 -65831 -62004 -55765 -21409 2517 -41153 -4962 -6464 -7023 10517 12233 -14593 -7436 13998 1455 28881 26069 20458 9950 24644 12274 17921 18486 12396 28945 20122 32468 11787 19215 10563 13510 14867 13183 14255 10979 19739 10377 12955 9415 7079 9480 6938 13104 8257 7851 6202 1457 2437 -879 44 -1437 1432 -4248 969 -2814 -2185 694 -762 2627 957 1573 847 2204 -650 -2187 -3412 -4478 -3064 -3064 -277 0 -1790 -520 -1238 -1617 -3406 -1788 -2555 -2823 -1974 -1961 52 185 1161 433 587 -603 -1051 -182 -814 230 607 1215 972 1410 1766 887 1121 39 434 539 402 -149 131 155 -12 -409 -351 11 631 805 -255 -121 -494 -812 -607 -2089 -562 -3730 -2074 -5411 -3184 -2564 -2728 -1198 -1851 118 -4870 -1241 -1536 -1211 -1669 -1899 -979 -545 228 -1858 -1288 -1905 -461 -173 -698 -824 -1542 -1356 -1219 -401 46 -1371 -127 -162 -168 225 299 -570 -325 561 71 1128 1180 984 541 1186 696 1016 1122 895 2006 1683 2622 1249 1970 1216 1501 1567 1367 1486 1295 2453 1629 2144 1607 1228 1672 1391 2867 2109 2109 1673 386 579 -192 9 -302 333 -1265 326 -1141 -978 322 -383 1360 530 892 483 1197 -340 -1091 -1677 -2334 -1800 -2129 -220 0 -1860 -539 -1214 -1422 -2757 -1420 -2202 -2590 -1903 -2045 59 241 1691 622 858 -871 -1458 -266 -1215 357 908 1870 1471 2232 2677 1315 1601 55 589 777 670 -262 254 326 -26 -982 -906 30 1732 2237 -713 -321 -1226 -1886 -1363 SS 20210803T104746.9Z 7885.449848 227 1 29.82 2 78.99 76.44 31.57 121.38 0.00 1 0.00 1 0 17 4.765e-01 8.836e-03 9.091e-02 2.307e-03 6.542642e-01 1.224875e-03 7.630859e-03 -6.000000e+00 2.745423e-01 232.34 -2.00 3.55 -2.00 321.20 0.00e+00 2.572590e-03 6.027087e-04 3.722826e-03 -6.000000e+00 1.219765e-02 288.20 -2.00 20.00 -2.00 320.55 0.00e+00 5.044 0.002 302.00 328.00 3 3.8077e-01 4.2619e-03 6.3488e-02 -6.0000e+00 6.8854e-01 9.1898e-02 5.8638e-03 4.2155e-02 -6.0000e+00 7.4513e-01 -1.2653e-01 5.7380e-03 2.0750e-02 -6.0000e+00 4.4375e-01 3.9952e-02 2.7226e-03 5.4873e-03 -6.0000e+00 1.8687e-01 1.2521e-03 -5.2760e-04 6.3542e-05 8.9173e-05 -6.0000e+00 1.2590e-02 2.6787e-03 -2.5177e-05 11 8 0 10 0 0 99.07 23.36 0.33 0.00268 -0.00129 136 136 1 5 0 219.200 27.05 19.99 23.36 22.58 7.9 961.65 -172923 -142814 -132126 -133602 -162710 -146569 -194435 -168398 -135762 -127679 -114107 -128063 -100785 -92768 -76824 -76374 413 -45529 -20339 -36358 -25141 -7784 -39189 -31163 -27756 -23843 -32705 -4565 -44343 -26218 -32618 -16564 -7872 -7129 -7766 -10812 -17150 -5451 -8127 1089 -1433 4299 -178 2154 12 5362 702 -626 1656 -775 3785 1731 3451 3869 4467 3207 3626 2474 1403 3938 1385 3759 4882 5818 3369 1481 1609 -195 2542 2605 2502 3082 1633 2313 -1031 -1366 -1840 -3153 -1588 -2254 -323 -1290 -1592 -1822 -434 -497 841 500 1608 535 616 -185 -1902 -1565 -1285 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