File name: Pandora183s1_LondonderryNH_20210809_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20251125T165609.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora183_OF_v1d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20210809_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20210809 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210809T134713.1Z 7891.574457 197 1 28.56 2 47.59 110.40 57.61 98.52 0.00 1 0.00 1 0 17 2.595e-02 1.266e-02 2.253e-02 8.104e-03 2.050391e-01 4.080235e-03 2.434635e-03 -6.000000e+00 1.493981e-02 232.11 -2.00 3.55 -2.00 317.19 0.00e+00 1.018620e-03 5.604011e-04 2.961193e-04 -6.000000e+00 6.645778e-04 288.33 -2.00 20.00 -2.00 316.30 0.00e+00 1.480 0.000 302.00 328.00 3 6.1217e+00 1.0875e-02 1.8202e-02 -6.0000e+00 3.7446e-02 7.0154e-02 1.2242e-02 1.0657e-02 -6.0000e+00 4.0525e-02 6.3331e-04 7.1589e-03 5.1687e-03 -6.0000e+00 2.4141e-02 -5.7699e-03 3.4264e-03 1.4602e-03 -6.0000e+00 1.0176e-02 2.0784e-04 -4.4984e-05 2.3417e-04 1.5299e-05 -6.0000e+00 6.8543e-04 4.2966e-04 -1.6333e-05 12 8 8 10 0 0 98.71 23.27 1.11 0.00043 0.00009 8 8 1 5 0 3569.220 26.94 19.99 23.27 28.95 8.3 1004.59 11286 4583 -4814 -5088 443 4642 324 -3485 -1290 4873 -5340 -12605 -387 -7478 2556 5275 2532 -2243 -4147 2902 -1933 996 5402 37 93 -4902 -291 -4509 -1540 170 1449 -658 793 366 -3097 -1476 -7977 386 1722 940 1605 -715 2568 -879 -573 475 978 48 585 -658 1 133 -1334 3146 949 2890 -277 -117 2946 183 1467 1690 1486 4293 380 -1643 -2601 -1200 1146 290 -1091 803 -340 798 -135 1053 -675 -3033 -722 -3132 -1977 -2436 -1685 -1646 -1185 99 -873 1436 1468 820 -376 131 -371 -1084 707 -1826 401 329 2424 493 -2154 -1467 -810 -885 -2384 -1147 -1422 35 965 1308 2693 749 667 -73 -402 -460 -217 -570 -185 879 921 632 364 211 188 331 702 -1243 13 -658 -410 -1171 -989 307 28 907 464 1524 54 370 -271 -1041 -946 1338 646 -770 -781 57 520 39 -477 -194 732 -876 -2183 -64 -1512 530 1174 604 -573 -1117 751 -539 291 1506 11 30 -1715 -98 -1493 -456 47 409 -203 259 125 -1028 -456 -2791 143 753 486 908 -432 1545 -553 -358 293 588 28 329 -370 1 82 -879 2075 658 1993 -200 -85 2017 128 1034 1268 1209 3609 332 -1349 -1958 -850 828 239 -1003 759 -327 733 -117 813 -521 -2234 -532 -2636 -1676 -2282 -1670 -1701 -1301 116 -1086 1804 1851 1005 -432 135 -384 -1075 719 -1899 451 409 3126 639 -2680 -1665 -952 -1075 -2911 -1463 -1898 48 1369 1957 4160 1187 1012 -104 -571 -611 -286 -787 -273 1253 1348 919 568 315 266 443 885 -1600 18 -951 -617 -1812 -1547 492 48 1608 771 2558 92 617 -483 -1802 -1605 SS 20210809T141111.9Z 7891.591110 212 1 30.21 2 43.56 116.18 53.45 103.09 0.00 1 0.00 1 0 17 9.718e-03 7.573e-03 1.898e-03 1.019e-03 1.851600e-01 5.206247e-04 2.244071e-03 -6.000000e+00 5.597379e-03 232.11 -2.00 3.55 -2.00 315.90 0.00e+00 4.466017e-04 5.446858e-05 1.454462e-04 -6.000000e+00 2.489738e-04 288.33 -2.00 20.00 -2.00 315.15 0.00e+00 1.378 0.000 302.00 328.00 3 3.3425e+00 1.3590e-03 1.6812e-02 -6.0000e+00 1.4030e-02 3.4798e-02 1.5121e-03 9.7149e-03 -6.0000e+00 1.5181e-02 2.7192e-03 8.6602e-04 4.6937e-03 -6.0000e+00 9.0436e-03 -6.7589e-03 3.9494e-04 1.2784e-03 -6.0000e+00 3.8137e-03 3.9128e-03 1.9404e-04 2.8601e-05 1.5574e-05 -6.0000e+00 2.5669e-04 -5.8003e-05 6.9391e-05 11 8 0 10 0 0 99.95 23.20 0.31 -0.00006 0.00140 60 60 1 5 0 503.250 26.83 20.00 23.20 30.23 8.3 1013.21 220 -142 -390 -1858 -2126 -2722 -924 -208 309 -1030 -1744 -1128 -260 -349 28 236 -180 609 -31 1036 1078 496 1849 1074 1208 1041 424 -449 -564 233 621 1373 1651 -545 -3243 -2124 -3070 -1783 -510 -618 -812 -938 -241 -650 -202 -335 -77 -610 -1341 -287 332 970 708 1273 582 888 846 117 588 408 1336 1245 1974 2292 684 -84 -531 -778 696 796 586 878 465 644 229 -482 -762 -1645 -679 -1096 -1315 -1559 -2421 -1384 -772 -497 -106 305 784 642 436 -249 -750 -307 -274 -356 432 949 36 -380 -558 -1117 -854 -283 -1254 -1095 -741 -762 93 631 970 517 646 247 -204 184 103 124 467 390 70 521 671 420 808 -105 303 902 253 5 -199 -373 -252 49 -216 -17 297 563 18 -9 -229 -988 -799 48 -34 -97 -450 -454 -533 -181 -45 74 -268 -450 -283 -69 -105 10 87 -69 236 -12 425 453 207 763 464 548 447 184 -204 -236 92 248 578 742 -260 -1495 -915 -1414 -934 -287 -408 -592 -655 -171 -469 -145 -260 -58 -448 -956 -199 236 731 562 964 456 704 682 95 465 320 1064 1057 1797 2207 669 -76 -437 -666 611 723 588 921 493 662 222 -423 -653 -1320 -550 -991 -1222 -1597 -2664 -1452 -859 -593 -134 396 1018 807 508 -287 -783 -303 -281 -401 492 1184 49 -501 -692 -1281 -1004 -343 -1542 -1424 -1002 -1074 126 897 1436 772 921 352 -265 223 124 157 631 565 98 717 966 581 1052 -131 386 1139 314 7 -276 -527 -360 72 -314 -26 464 898 30 -15 -351 -1473 -1167 SS 20210809T143053.4Z 7891.604785 218 1 30.05 2 40.40 121.47 50.09 107.13 0.00 1 0.00 1 0 17 1.277e-02 8.158e-03 5.366e-03 2.554e-03 1.752966e-01 1.304392e-03 2.111665e-03 -6.000000e+00 7.354052e-03 232.11 -2.00 3.55 -2.00 316.33 0.00e+00 7.041348e-04 1.467627e-04 1.566375e-04 -6.000000e+00 3.270925e-04 288.33 -2.00 20.00 -2.00 315.52 0.00e+00 1.312 0.000 302.00 328.00 3 4.8228e+00 3.4219e-03 1.5957e-02 -6.0000e+00 1.8433e-02 3.9141e-02 3.8169e-03 9.1666e-03 -6.0000e+00 1.9944e-02 5.6476e-03 2.1986e-03 4.4297e-03 -6.0000e+00 1.1881e-02 -7.9354e-03 1.0126e-03 1.2438e-03 -6.0000e+00 5.0114e-03 9.6542e-04 3.6304e-04 7.2654e-05 1.4247e-05 -6.0000e+00 3.3715e-04 -6.0466e-04 1.0375e-04 11 8 0 10 0 0 99.97 23.18 0.35 -0.00060 0.00212 27 27 1 5 0 1112.660 26.83 20.00 23.18 32.04 8.2 1023.33 -604 -2192 -222 -3767 -2815 -4640 -1318 2641 -1198 378 -4510 -1114 -2738 244 1962 -279 1523 1488 1080 1003 2056 -319 1336 788 318 552 482 136 -1405 608 509 -50 2460 -454 -3895 -2492 -2172 -2253 -1310 9 350 -211 -745 47 -620 -629 -156 -228 -370 -877 707 191 1370 1383 528 1101 1510 -486 606 9 966 1627 1091 2809 685 261 -649 -1220 793 376 499 295 1134 375 96 57 -1223 -2386 -731 -1640 -1364 -1741 -2222 -1444 -137 -555 41 222 1214 791 292 -183 -1007 -524 -729 -623 61 1082 298 -500 -614 -1374 -617 -935 -1024 -1055 -677 -425 179 1003 647 694 352 313 -274 112 -66 -434 863 489 353 201 803 566 711 -519 238 1106 2 -43 -388 -504 -152 -129 -231 -110 826 354 234 -25 -139 -929 -949 -113 -459 -47 -788 -512 -783 -218 465 -246 81 -1001 -256 -685 66 538 -86 476 473 355 373 776 -122 501 308 131 235 206 55 -531 214 182 -19 977 -193 -1608 -957 -880 -1050 -723 6 222 -141 -513 32 -428 -433 -105 -162 -253 -590 482 140 1039 996 394 827 1147 -376 501 8 807 1306 950 2549 634 222 -555 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