File name: Pandora183s1_LondonderryNH_20220121_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20251125T173323.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20220121_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20220121 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220121T133220.1Z 8056.564122 298 1 50.67 2 78.35 131.60 80.86 276.32 0.00 1 0.00 1 0 17 5.938e-01 1.862e-02 3.639e-01 1.143e-02 7.322378e-01 6.371974e-03 8.283836e-03 -6.000000e+00 3.377648e-01 223.75 -2.00 3.55 -2.00 321.65 0.00e+00 4.626617e-03 3.138625e-03 2.932508e-03 -6.000000e+00 1.570717e-02 273.02 -2.00 20.00 -2.00 321.21 0.00e+00 4.794 0.002 302.00 328.00 3 2.8820e+00 2.1524e-02 6.1673e-02 -6.0000e+00 8.3928e-01 2.5239e-01 3.1764e-02 4.1025e-02 -6.0000e+00 9.1957e-01 -2.9686e-01 3.5396e-02 2.5125e-02 -6.0000e+00 5.4082e-01 1.1071e-01 1.6613e-02 1.0358e-02 -6.0000e+00 2.3263e-01 1.1477e-04 -3.5700e-04 3.2872e-04 1.4222e-04 -6.0000e+00 1.6680e-02 -4.3583e-03 2.1354e-05 12 8 8 10 0 0 98.90 22.80 0.43 -0.00436 -0.00704 22 5 1 5 0 2302.780 26.41 20.01 22.80 -9.72 11.4 779.74 900000 900000 -251006 900000 -240294 -172387 -110125 900000 900000 -276522 900000 -112239 49932 900000 900000 -117193 900000 2999 -104716 127673 -48604 900000 903 87293 -77142 -2291 264236 -15017 -3887 9587 215033 -16378 9244 -13048 -8838 -13258 7110 30501 79471 6992 34838 6815 21800 -6614 13395 4320 23853 -13246 -7786 29970 22720 15255 24150 23486 29039 20025 17949 7385 -1990 14479 16144 -2638 9829 7510 13282 -1852 -976 12040 8407 1380 7370 383 3279 5335 4663 -5741 5698 -6095 -6035 1507 -2136 -3552 -8114 2386 -4580 -401 -2026 1170 586 5789 -1962 1170 2203 -3432 -1945 -1195 198 1277 1484 -1163 -365 -2555 -3489 -1030 -2871 -624 -462 -1174 -669 2390 -294 -937 1009 -171 -1341 -972 -357 144 986 430 1664 3166 1480 -1050 -384 -351 1138 -294 71 -373 525 693 -515 55 -662 -522 266 1341 445 -610 232 -810 -991 900000 900000 -4942 900000 -3908 -1918 -1225 900000 900000 -9231 900000 -1249 556 900000 900000 -2500 900000 33 -2816 1421 -811 900000 10 971 -2003 -30 2940 -243 -55 126 2393 -414 215 -422 -268 -402 187 741 1447 318 1375 386 1125 -468 786 284 1327 -1112 -654 1849 1678 1374 2199 2352 2938 2309 2179 994 -284 1699 1894 -408 1541 1383 2499 -403 -207 2314 1837 374 2095 122 1008 1511 1208 -1469 1325 -1614 -1793 498 -789 -1534 -4063 1256 -2747 -246 -1203 762 383 3460 -1181 638 1145 -1952 -1230 -877 168 1234 1575 -1278 -373 -2380 -2950 -842 -2565 -577 -449 -1235 -772 3032 -429 -1472 1571 -262 -1965 -1359 -499 210 1503 682 2561 4580 2088 -1468 -514 -451 1397 -385 105 -636 981 1383 -1097 124 -1608 -1327 684 3449 1147 -1515 532 -1752 -2077 SS 20220121T134248.8Z 8056.571398 304 1 49.62 2 76.93 133.66 82.73 277.98 0.00 1 0.00 1 0 33 4.283e-01 1.046e-02 3.151e-01 6.175e-03 6.707335e-01 3.327175e-03 7.926514e-03 -6.000000e+00 2.404513e-01 223.75 -2.00 3.55 -2.00 321.38 0.00e+00 6.369660e-03 1.546025e-03 3.309370e-03 -6.000000e+00 1.056685e-02 273.02 -2.00 20.00 -2.00 320.92 0.00e+00 4.311 0.001 302.00 328.00 3 2.5384e+00 1.0803e-02 5.5979e-02 -6.0000e+00 5.9463e-01 1.4855e-01 1.5507e-02 3.7800e-02 -6.0000e+00 6.5015e-01 -1.5498e-01 1.7509e-02 2.5431e-02 -6.0000e+00 3.8615e-01 5.0428e-02 8.3877e-03 1.1896e-02 -6.0000e+00 1.6290e-01 2.7391e-04 -1.7541e-04 1.7627e-04 1.5277e-04 -6.0000e+00 1.1517e-02 -4.0707e-03 2.1092e-05 12 8 8 10 0 0 99.84 22.81 0.39 -0.00407 -0.00539 46 10 1 5 0 1078.520 26.41 20.00 22.81 -9.52 11.4 781.26 -150653 -136554 -117771 -177447 900000 -188140 -90938 -155470 11974 -48885 -192186 -35439 -11770 -5220 -131041 -47993 900000 -8685 26749 -20562 900000 -2864 112553 -28225 -50611 10150 -42361 11755 -31451 -29853 38304 41307 -17290 9733 -28153 -16001 -25857 13446 20037 8001 6104 -7039 19308 9357 -11079 15628 9802 6186 19 -7760 13712 -3678 1438 8363 11761 1054 7296 8145 -2679 -3303 4524 2518 4001 4255 2513 1432 -1891 -2462 2502 933 5947 4289 3636 685 -845 -5538 -1211 -2746 -1817 1017 -71 -2151 -2007 -2224 -300 -589 1236 1190 591 1170 653 -336 -3081 -2572 -2133 -1776 20 1353 611 -402 -900 -943 453 -1438 -1782 -1767 -1022 -265 1 1246 1190 193 411 82 -737 131 -661 12 890 499 387 906 1369 -81 -7 -1165 -37 429 -176 158 -166 -226 -300 -362 -297 -382 27 1106 -67 -121 429 -642 -150 -982 -959 -768 -2136 900000 -2170 -547 -1482 72 -294 -3374 -213 -71 -31 -3023 -602 900000 -96 228 -299 900000 -39 677 -541 -1302 150 -1089 174 -706 -702 545 701 -624 298 -1232 -595 -1132 464 789 429 381 -543 1215 676 -1000 1112 762 518 2 -836 1320 -475 194 1149 1660 172 1150 1270 -451 -548 710 442 792 959 620 388 -518 -694 732 320 2159 1660 1405 257 -294 -1803 -349 -808 -591 383 -32 -1131 -1162 -1367 -192 -404 874 868 433 822 430 -208 -1873 -1594 -1474 -1423 19 1403 700 -468 -985 -924 396 -1275 -1704 -1787 -1080 -298 1 1699 1803 314 668 129 -1102 185 -949 18 1393 814 624 1392 2012 -117 -10 -1566 -48 574 -269 271 -314 -456 -636 -813 -714 -964 69 2839 -174 -300 988 -1401 -316 SS 20220121T140027.2Z 8056.583648 313 1 14.75 2 74.66 137.24 85.87 280.78 0.00 1 0.00 1 0 17 2.632e-01 7.908e-03 7.443e-02 2.294e-03 5.895712e-01 1.162507e-03 6.863908e-03 -6.000000e+00 1.469140e-01 223.75 -2.00 3.55 -2.00 320.46 0.00e+00 3.588430e-03 4.278588e-04 1.827912e-03 -6.000000e+00 6.326678e-03 273.02 -2.00 20.00 -2.00 319.98 0.00e+00 3.712 0.001 302.00 328.00 3 1.2303e+00 3.4458e-03 4.7756e-02 -6.0000e+00 3.6294e-01 5.0088e-02 4.3873e-03 3.1233e-02 -6.0000e+00 3.9616e-01 -4.7510e-02 4.4317e-03 1.8135e-02 -6.0000e+00 2.3543e-01 9.0326e-03 2.2547e-03 7.1445e-03 -6.0000e+00 9.9648e-02 1.9901e-03 -4.5056e-04 6.3024e-05 8.0888e-05 -6.0000e+00 6.9350e-03 -4.4031e-03 -1.9776e-06 12 9 1 12 1 1 97.39 22.77 0.31 -0.00440 -0.00779 50 36 1 5 0 285.680 26.41 20.00 22.77 -8.99 11.4 785.23 -80033 -96650 -78051 -108527 -64411 -88994 -88655 -70438 -103316 -75759 -87865 -35489 -49492 -40802 -36554 -27458 -13823 -20295 -14448 -1886 -1124 -18817 -11878 -11724 -24224 -13665 -16964 -7153 -17992 -20409 -16255 -8056 -5646 -4927 -8162 -11496 -5490 -4941 -1659 1696 -2922 884 -3000 247 -397 1563 -5 3140 3782 317 3114 1764 2099 2137 2510 729 2036 208 -1248 591 372 2542 3178 3548 2341 734 451 -62 1986 1647 1607 1442 1249 1712 205 -675 -2385 -2198 -1320 -1534 -1177 -1067 -2097 -1843 -677 -804 391 367 1429 1308 427 -112 -1179 -673 -1181 -659 330 1092 412 -74 -844 -1486 -928 -626 -1470 -1367 -931 -559 -176 582 851 548 409 -65 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