File name: Pandora183s1_LondonderryNH_20220124_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20251125T173446.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20220124_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20220124 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220124T125518.8Z 8059.538412 284 1 50.04 2 83.27 124.04 64.22 232.26 0.00 1 0.00 1 0 25 5.603e-01 3.194e-02 4.651e-01 2.751e-02 1.016132e+00 1.593279e-02 1.085709e-02 -6.000000e+00 3.150084e-01 223.87 -2.00 3.55 -2.00 322.45 0.00e+00 -1.396569e-02 7.822375e-03 6.660028e-03 -6.000000e+00 1.440539e-02 273.02 -2.00 20.00 -2.00 322.03 0.00e+00 7.789 0.009 302.00 328.00 3 5.5525e-01 5.7868e-02 1.0579e-01 -6.0000e+00 7.7693e-01 1.5816e+00 7.1751e-02 8.8578e-02 -6.0000e+00 8.4860e-01 -1.9996e+00 5.7625e-02 3.2996e-02 -6.0000e+00 5.0332e-01 7.5311e-01 2.9863e-02 1.3374e-02 -6.0000e+00 2.1462e-01 4.8847e-05 -6.0741e-04 7.2885e-04 1.3622e-04 -6.0000e+00 1.5192e-02 -4.8859e-03 -9.6096e-05 12 8 8 10 0 0 33.39 22.81 0.65 -0.00489 -0.00945 41 9 1 5 0 1220.250 26.41 19.99 22.81 -1.11 12.1 850.28 70205 -672 900000 -25929 111889 900000 40072 174542 -68940 147957 -19773 -70461 900000 900000 75075 -4226 45401 -33051 -16672 -13859 227190 900000 -48362 225034 -32424 43453 -30734 -29026 2406 199343 -86202 31589 67189 132463 20006 85444 -4848 900000 70156 88239 900000 111577 64139 -32299 40106 20665 -14792 140421 82089 35702 33017 -20974 -5890 18983 111937 129881 107429 50284 -37018 -28015 -43666 2036 -9834 58482 34986 42253 7366 18494 7849 18708 36120 32855 58426 8647 4221 32890 506 -11441 13608 9414 6209 13372 1206 15301 3175 18999 17730 -3761 -1072 4228 655 -2183 3274 -11739 -8808 -3646 -6076 -2727 2740 -7065 -474 -4041 -556 -2211 -3224 -647 -9646 6329 2168 -1392 887 309 1033 5104 -3411 849 -1589 -1364 991 596 -1096 1681 3795 3233 -138 -3751 -235 3059 -1262 1827 184 513 -2627 -394 485 -417 525 1461 720 -70 -895 -304 -1330 1881 -26 900000 -1069 2998 900000 1074 4677 -3553 3965 -652 -3922 900000 900000 2012 -208 1419 -2288 -968 -743 6088 900000 -3024 6030 -2100 1358 -1922 -1556 81 5342 -7507 988 1800 3550 759 2290 -217 900000 2222 2794 900000 3262 2969 -3698 2052 1208 -1189 3763 2600 1913 2011 -2453 -646 1757 4363 4430 4711 3797 -6132 -3822 -6595 203 -1246 4274 3494 3911 969 2298 1205 2962 5280 5122 6832 1517 679 3445 68 -1784 1890 1651 1346 3160 361 4249 1052 5647 5529 -1475 -402 1432 235 -766 1088 -4907 -4178 -1964 -3973 -2017 2137 -6172 -363 -2837 -334 -1321 -2082 -432 -7470 4562 1853 -1451 1051 408 1412 6702 -4735 1099 -2133 -1916 1431 882 -1590 2225 4698 3925 -168 -4624 -275 3746 -1918 3177 370 1128 -6441 -1023 1349 -1229 1557 4319 2110 -194 -2293 -708 -3004 SS 20220124T130703.5Z 8059.546568 287 1 49.82 2 81.51 126.20 65.95 234.76 0.00 1 0.00 1 0 17 5.633e-01 1.944e-02 3.230e-01 8.371e-03 9.030806e-01 4.760707e-03 9.786692e-03 -6.000000e+00 3.160990e-01 223.87 -2.00 3.55 -2.00 322.25 0.00e+00 6.995141e-03 2.626539e-03 1.665834e-03 -6.000000e+00 1.405286e-02 273.02 -2.00 20.00 -2.00 321.83 0.00e+00 6.381 0.005 302.00 328.00 3 5.2709e-01 1.7693e-02 8.0056e-02 -6.0000e+00 7.8254e-01 8.0250e-01 2.6270e-02 5.2425e-02 -6.0000e+00 8.5460e-01 -1.0429e+00 2.7823e-02 2.9017e-02 -6.0000e+00 5.0608e-01 4.0160e-01 1.2802e-02 1.2485e-02 -6.0000e+00 2.1501e-01 2.2043e-04 -1.2611e-03 2.3245e-04 1.7297e-04 -6.0000e+00 1.5251e-02 -6.0384e-03 1.2622e-06 12 8 8 10 0 0 84.92 22.78 0.42 -0.00604 -0.01551 96 20 1 5 0 518.790 26.41 20.00 22.78 -0.31 11.9 855.22 -188940 93221 900000 -155362 900000 -193386 -146174 -225219 900000 -186333 -178425 -71987 -192004 -88597 -105742 -4753 78725 34407 -53830 -61082 -9289 -79102 -51354 -60789 881 -37878 -64416 3410 -88370 25303 -49201 92163 154710 22438 2658 -10489 56042 -24211 71554 -13214 51617 29620 42509 10004 31097 56922 8192 29244 31868 72316 22762 6255 37081 6164 52729 21338 34351 19638 29296 31562 22138 13121 17214 27188 13953 42145 12580 13534 5351 8226 18266 5550 23330 10126 14893 848 -2064 -4535 -3838 -1697 2993 5866 1511 1303 3192 -108 486 -451 5559 -1006 2025 -2549 -1913 -3385 -5194 -1860 -2114 982 -2131 -480 -3408 -2478 -1608 -2664 -2197 -4196 -553 -2282 159 -347 39 -543 -619 -334 -2765 446 -1797 -410 993 1009 1648 1833 4116 1694 1754 -612 521 1609 -508 337 -18 444 -466 525 -246 131 378 419 711 33 18 -1893 -1537 -3320 761 900000 -2438 900000 -3399 -1690 -5972 900000 -3674 -3276 -587 -5483 -1205 -2229 -45 642 281 -1135 -1412 -126 -2044 -978 -1323 11 -695 -1533 39 -2464 263 -1314 752 1262 483 67 -280 790 -862 1168 -598 1378 1055 1387 460 1153 1647 395 1193 1347 2199 1266 464 2228 549 3129 1788 2573 1675 2151 2154 1659 1168 1698 2823 1822 4189 1680 1867 881 1519 3387 1218 4205 1930 2661 154 -357 -829 -799 -422 855 1900 572 526 1339 -50 231 -223 2572 -479 872 -1082 -790 -1500 -2704 -1120 -1518 802 -2009 -455 -3126 -1997 -1136 -1852 -1620 -3349 -450 -2049 157 -398 51 -785 -923 -492 -4011 606 -2519 -594 1499 1567 2474 2594 5431 2224 2228 -772 634 2062 -778 598 -37 967 -1095 1314 -667 370 1087 1216 2038 91 46 -4486 -3479 SS 20220124T132309.9Z 8059.557754 292 1 3.84 2 79.17 129.25 68.40 238.07 0.00 1 0.00 1 0 25 4.659e-01 2.562e-02 4.224e-01 1.919e-02 7.652531e-01 1.016807e-02 9.706974e-03 -6.000000e+00 2.611010e-01 223.87 -2.00 3.55 -2.00 321.39 0.00e+00 1.903307e-03 4.621466e-03 8.214715e-03 -6.000000e+00 1.205394e-02 273.02 -2.00 20.00 -2.00 320.92 0.00e+00 5.128 0.002 302.00 328.00 3 1.9010e+00 3.2988e-02 7.4878e-02 -6.0000e+00 6.4551e-01 4.7051e-01 4.4461e-02 6.4235e-02 -6.0000e+00 7.0507e-01 -6.6816e-01 4.4776e-02 3.2066e-02 -6.0000e+00 4.1816e-01 2.7192e-01 2.1658e-02 8.4512e-03 -6.0000e+00 1.7806e-01 2.1789e-04 -1.6098e-05 5.1284e-04 1.8741e-04 -6.0000e+00 1.2337e-02 -7.0166e-03 -3.6373e-05 12 9 9 12 1 1 999.00 22.76 0.62 -0.00702 -0.00714 2 9 1 5 0 1220.920 26.41 20.00 22.76 0.27 11.9 859.74 -110678 900000 -109410 8079 -143285 -98723 28384 -187626 -21616 900000 -173131 -61093 -40633 -60867 202141 -62182 -6304 172825 -60241 21595 -87820 900000 -14770 -400 -540 27910 900000 -105020 -35485 -77371 1953 50142 -35388 28835 -27195 9208 9502 113411 19433 71473 74543 -15419 23357 -21287 26677 -16462 51098 54125 52774 14806 28891 57751 -4445 34234 23473 32665 18990 13541 14759 -16172 29056 14578 17181 292 2054 13098 7776 5765 -2195 10945 4197 7580 -2020 3617 -1171 2372 677 -11915 2297 -3706 11408 -1543 -3009 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