File name: Pandora183s1_LondonderryNH_20220125_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20251125T173301.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20220125_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20220125 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220125T150951.7Z 8060.631848 359 1 25.32 2 66.54 152.07 82.37 245.00 0.00 1 0.00 1 0 17 1.133e-01 1.204e-02 9.445e-02 8.743e-03 3.601511e-01 4.322931e-03 4.260032e-03 -6.000000e+00 6.334079e-02 223.91 -2.00 3.55 -2.00 319.52 0.00e+00 2.089431e-03 1.115232e-03 7.379660e-04 -6.000000e+00 2.724816e-03 273.01 -2.00 20.00 -2.00 318.96 0.00e+00 2.493 0.000 302.00 328.00 3 3.6567e+00 1.2056e-02 3.0622e-02 -6.0000e+00 1.5654e-01 5.5866e-02 1.4004e-02 1.8362e-02 -6.0000e+00 1.7079e-01 -1.3139e-02 1.0905e-02 9.7684e-03 -6.0000e+00 1.0149e-01 -4.3005e-03 5.7889e-03 3.5958e-03 -6.0000e+00 4.2984e-02 7.3126e-04 1.2549e-04 2.5696e-04 3.7395e-05 -6.0000e+00 2.9858e-03 -8.5042e-03 8.6488e-05 12 9 9 12 1 1 99.99 22.79 0.43 -0.00850 -0.00756 13 6 2 5 0 1795.960 26.41 20.00 22.79 10.10 12.6 937.81 -52387 32107 2915 -19355 -48900 6042 -41501 41967 992 -19266 -1981 -49519 -14608 -938 13814 22905 -2463 20186 -4187 19878 11080 -12117 1018 -2773 33783 -4526 17006 -8168 11191 9632 1163 -11229 11637 6138 -7152 -10048 -8907 1231 1090 2720 1681 -493 -1427 -2681 4457 -2291 1432 -1323 -1050 801 -1737 6279 1723 2254 355 -2196 784 -3756 2307 -1460 2056 1015 2242 4209 -174 1435 -2618 967 953 2964 782 939 -1622 194 519 654 1586 -3035 133 -3635 -717 -1044 -2679 -1941 -1182 -711 -320 1577 2958 1622 726 -1054 -1462 -908 -1467 -630 87 -147 1978 -771 -1333 583 -485 336 -1979 -1109 -936 -446 525 384 1653 503 380 127 -1076 -317 1238 -33 367 515 195 345 79 521 526 -356 770 -143 -809 -320 -646 -508 -675 -67 -158 161 102 1551 349 -165 -376 -1615 676 -2062 684 89 -729 -2224 146 -1651 805 32 -835 -73 -2991 -706 -47 717 1253 -189 1305 -366 1426 898 -1231 91 -297 2671 -551 1700 -1013 1076 926 131 -1602 1470 880 -1125 -1542 -1429 206 220 645 452 -144 -438 -852 1323 -733 441 -414 -326 247 -581 2112 650 900 151 -980 348 -1744 985 -637 884 473 1140 2290 -102 784 -1386 481 500 1735 519 654 -1163 131 326 406 880 -1679 75 -2411 -527 -784 -2209 -1667 -1073 -689 -327 1633 3034 1632 753 -1019 -1307 -785 -1356 -645 99 -171 2433 -971 -1742 681 -531 371 -2422 -1428 -1258 -627 775 614 2539 804 593 205 -1623 -446 1703 -48 567 843 325 565 126 793 761 -496 1010 -191 -1180 -506 -1091 -886 -1209 -124 -312 333 216 3316 757 -350 -764 -3171 1267 SS 20220125T151515.8Z 8060.635599 362 1 49.74 2 66.09 153.37 83.26 245.93 0.00 1 0.00 1 0 17 8.344e-02 1.075e-02 6.946e-02 7.419e-03 3.600525e-01 3.697810e-03 4.349270e-03 -6.000000e+00 4.661343e-02 223.91 -2.00 3.55 -2.00 319.45 0.00e+00 1.005215e-03 9.162106e-04 9.890957e-04 -6.000000e+00 2.005758e-03 273.01 -2.00 20.00 -2.00 318.87 0.00e+00 2.450 0.000 302.00 328.00 3 4.6992e+00 1.0295e-02 3.0539e-02 -6.0000e+00 1.1520e-01 7.5389e-02 1.1953e-02 1.9024e-02 -6.0000e+00 1.2571e-01 -6.2851e-03 9.1066e-03 9.7089e-03 -6.0000e+00 7.4697e-02 -1.0522e-02 4.7939e-03 2.8984e-03 -6.0000e+00 3.1622e-02 2.6650e-04 -5.7879e-04 2.2370e-04 3.5022e-05 -6.0000e+00 2.1983e-03 -7.6002e-03 -5.9274e-06 12 8 8 10 0 0 99.90 22.80 0.84 -0.00760 -0.01195 41 9 1 5 0 1212.780 26.41 20.00 22.80 10.38 12.6 939.73 -30057 -4611 -18038 -16408 -23911 -51073 -29196 -6048 8695 -7365 4959 -39289 -17557 -10841 -5232 17350 9362 13067 -7769 3045 -10265 -3615 -1648 2928 4474 -13474 8211 -6714 -4388 339 -1879 10341 47 4595 1497 -829 -12706 -7791 -2995 2601 -669 -3932 5804 1106 3431 -4171 -714 2147 2392 3636 656 4449 1026 1578 245 2965 -766 1047 690 177 1707 -50 4178 3906 236 -1121 -2989 -418 1356 1549 -249 1689 2370 373 62 -1329 -1057 -2182 -891 -1971 -276 -758 -2400 -1118 -819 -520 -1090 -233 6 1049 1890 31 -1085 -1829 -121 -1573 -364 1811 -246 -351 -68 -1090 -1864 119 -2407 -1735 -139 -1170 651 1662 1295 94 486 618 -756 31 -360 296 -263 1229 -185 269 1354 169 756 -62 469 -95 -321 -168 327 -892 -1121 568 -349 383 101 944 -99 -48 -367 -359 -543 -1004 -139 -663 -584 -825 -2132 -1008 -201 283 -306 185 -2322 -942 -647 -350 1067 677 961 -745 274 -1089 -357 -161 290 467 -1771 886 -810 -484 35 -212 1154 7 648 209 -123 -2240 -1512 -670 657 -196 -1267 1764 359 1090 -1438 -237 684 755 1146 225 1601 410 667 110 1324 -364 489 316 80 774 -25 2179 2228 144 -656 -1658 -220 739 958 -174 1218 1702 263 41 -797 -570 -1131 -476 -1210 -190 -586 -2041 -985 -766 -520 -1157 -253 6 1096 1818 28 -905 -1491 -103 -1516 -390 2122 -317 -451 -81 -1204 -1926 135 -2748 -2088 -172 -1538 890 2430 2033 154 771 920 -1157 44 -511 434 -414 2027 -314 447 2155 262 1106 -88 624 -128 -470 -267 551 -1577 -2035 1058 -696 799 216 2045 -217 -103 -750 -701 -1036 SS 20220125T153404.4Z 8060.648662 370 1 40.24 2 64.67 158.01 86.39 249.11 0.00 1 0.00 1 0 17 4.297e-02 8.042e-03 3.414e-02 4.210e-03 3.423733e-01 2.071400e-03 4.104562e-03 -6.000000e+00 2.403355e-02 223.91 -2.00 3.55 -2.00 319.04 0.00e+00 8.042024e-04 4.764355e-04 5.783285e-04 -6.000000e+00 1.035607e-03 273.01 -2.00 20.00 -2.00 318.48 0.00e+00 2.322 0.000 302.00 328.00 3 4.2087e+00 5.6661e-03 2.8825e-02 -6.0000e+00 5.9398e-02 4.6930e-02 6.5238e-03 1.7630e-02 -6.0000e+00 6.4826e-02 -3.1177e-04 4.8358e-03 8.9863e-03 -6.0000e+00 3.8495e-02 -8.6098e-03 2.5637e-03 2.7527e-03 -6.0000e+00 1.6426e-02 5.1349e-04 5.6191e-04 1.2266e-04 2.9817e-05 -6.0000e+00 1.1420e-03 -9.9471e-03 1.9609e-04 12 9 1 12 1 1 99.98 22.77 0.35 -0.00995 -0.00572 26 7 1 5 0 1483.600 26.41 20.00 22.77 10.83 12.6 941.32 900000 -4438 -3464 -5817 -29006 -11734 -16950 1872 -16189 -3124 -15987 -6571 6982 -654 3281 -1264 -6913 -7361 2041 -1193 -531 8178 -3869 515 -4601 -1386 -3190 -1589 -803 -5726 3035 4660 6148 -2113 -4951 -755 -5253 -900 26 2253 -2442 910 -1245 57 2649 -436 2447 -1979 -741 438 -4 -1210 -1226 2603 -171 1703 -815 404 442 -180 -1158 2198 3515 2667 2440 75 -933 -2220 31 1545 1787 2005 640 1867 -975 -68 -383 -2169 -1274 -2546 -1075 -1224 -1651 -1539 55 -768 -775 660 228 774 319 364 -807 -654 -1488 -574 472 842 607 -874 306 -1277 -417 -34 -1537 -1203 -299 -182 306 258 967 381 531 -55 -149 -472 -9 -449 140 360 -52 440 894 752 537 -458 -617 1076 98 -128 -105 -403 72 -50 -160 145 532 718 -210 204 -370 -583 -531 900000 -161 -133 -225 -1270 -397 -620 63 -748 -150 -889 -336 349 -42 238 -110 -689 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